| Project/Area Number |
25620175
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
SAKAKIBARA Keita 京都大学, 化学研究所, 助教 (20618649)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | セルロース / ミクロ相分離 / 準結晶 / ボトルブラシ / キラリティ / リビングラジカル重合 |
|---|
| Outline of Final Research Achievements |
Novel bottlebrushes with semi-flexible and helical cellulose backbones have been synthesized and their self-assembly toward mesoscopic hierarchical structure has been studied. Polyethylene glycol and polystyrene covalently linked to cellulose regioselectively were used to convey periodic nanostructures in solution or film. It should be emphasized that we established a new route for the synthesis of two Janus-type cellulosic bottlebrushes for the first time.
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