Solvation Structure of Magnesium Ion and Its Electrochemical Reactivity in Ionic Liquids
| Project/Area Number |
25620181
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Yokohama National University |
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Principal Investigator |
DOKKO KAORU 横浜国立大学, 工学研究院, 准教授 (70438117)
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| Co-Investigator(Renkei-kenkyūsha) |
UMEBAYASHI Yasuhiro 新潟大学, 自然科学系, 教授 (90311836)
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| Research Collaborator |
TSUZUKI Seiji 独立行政法人産業技術総合研究所, ナノシステム研究部門, 上級主任研究員 (10357527)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | マグネシウム電池 / 溶媒和構造 / イオン液体 / 電気めっき / 有機電解液 / イオン対 / 電気化学 / 無機工業化学 / 元素戦略 / 電池 / めっき |
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| Outline of Final Research Achievements |
The solvation structure of magnesium ion (Mg2+) in an electrolyte consisting of a magnesium salt Mg(N(SO2CF3)2)2 and tetraglyme (G4) was investigated. In the electrolyte, Mg2+ and G4 form a 1:1 complex cation [Mg(G4)]2+. It was revealed that G4 and Mg(N(SO2CF3)2)2 form a thermally stable complex in the molar ratio of 1:1. The melting point of [Mg(G4)](N(SO2CF3)2)2 is 137 degree Celsius, and the complex decomposes at around 200 degree Celsius. The electrochemical deposition of Mg metal was successfully performed in an electrolyte consisting of [Mg(G4)](N(SO2CF3)2)2 and an ionic liquid N-methyl-N-propyl-pyrrolidinium bis(trifluoromethanesulfonyl)amide.
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Report
(3 results)
Research Products
(7 results)
