Construction of metal- and semiconductor-based soft matter materials utilizing DNA structural flexibility
| Project/Area Number |
25620183
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | DNAヒドロゲル / 金粒子 / ナノ粒子 / 金属ナノ粒子 / DNAゲル / 貴金属ナノ粒子 / 合金ナノ粒子 / 層状複合金属ナノ粒子 / 低環境負荷材料 / グリーンケミストリー / 金属化DNA / 金属化DNAゲル / 触媒 / 半導体ナノ粒子 / 無機化DNA / ＤＮＡ / 硫化カドミウム / 金 / 無機化ＤＮＡ / 金属化ＤＮＡ |
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| Outline of Final Research Achievements |
Preparation of metal nanoparticle was studied using DNA as a template, and following results were obtained. In a DNA-hydrogel medium, the smallest gold particles of 2.8 ± 1 nm (diameter) ever reported were prepared. A gold small-size coil (100 nm o.d. and 37 nm i.d.) and a small vesicle with a membrane including DNA and gold or silver nanoparticles were prepared. Metal nanoparticles of single metal or complexed metal (alloy or core-shell type), the size of which was smaller than 5 nm, were prepared in a DNA hydrogel matrix. The DNA-hydrogel and metal nanoparticle complex could be used as a catalyst for the conversion of an aromatic nitro compound to an aromatic amine.
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Report
(4 results)
Research Products
(18 results)
