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Development of direct carbon fuel cell using coal chars

Research Project

Project/Area Number 25630064
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Watanabe Hirotatsu  東京工業大学, 理工学研究科, 助教 (40551825)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords燃料電池
Outline of Final Research Achievements

In this study, direct carbon fuel cells (DCFC) using chars were developed. Mechanisms of power generation was clarified, and findings to enhance power generation were presented. First, it was shown that continuous power generation was successfully achieved when the carbon was well-wetted. The ternary carbonate composition determined the degree of carbon wetting, which, in turn, had a significant impact on the continuous power generation capacity of the DCFC. And, an increase in carbon/carbonate ratio around electrode enhanced partial electrochemical oxidation that produced CO. Moreover, the electrochemical oxidation of carbon in molten carbonates was studied using a single carbon pellet. The difference in carbon surface before and after electrochemical oxidation was presented.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (15 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (3 results)

  • [Journal Article] Impact of Ternary Carbonate Composition on the Morphology of the Carbon/Carbonate Slurry and Continuous Power Generation by Direct Carbon Fuel Cells2016

    • Author(s)
      Hirotatsu Watanabe, Akihiro Kimura, Ken Okazaki
    • Journal Title

      Energy & Fuels

      Volume: 30 Issue: 3 Pages: 1835-1840

    • DOI

      10.1021/acs.energyfuels.5b02224

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Oxidation of Activated Carbon and Coal Chars in a Direct Carbon Fuel Cell Using Carbon/Carbonate Slurry Stirred by Ar Bubbling2016

    • Author(s)
      Hirotatsu Watanabe, Tomoaki Furuyama, Ken Okazaki
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 49 Issue: 3 Pages: 237-242

    • DOI

      10.1252/jcej.14we288

    • NAID

      130005137811

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancing the efficiency of direct carbon fuel cells by bubbling Ar gas in carbon/carbonate slurry2015

    • Author(s)
      Hirotatsu Watanabe, Tomoaki Furuyama, Ken Okazaki
    • Journal Title

      Journal of Power Sources

      Volume: 273 Pages: 340-350

    • DOI

      10.1016/j.jpowsour.2014.09.079

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrochemical oxidation of activated carbon and coal chars in a direct carbon fuel cell using carbon/carbonate slurry stirred by Ar bubbling2015

    • Author(s)
      Hirotatsu Watanabe, Tomoaki Furuyama, Ken Okazaki
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: in press

    • Related Report
      2014 Research-status Report
  • [Presentation] The impact of ternary carbonate composition on the morphology of carbon/carbonate slurry and continuous power generation by direct carbon fuel cells2015

    • Author(s)
      Hirotatsu Watanabe, Akihiro Kimura, Ken Okazaki
    • Organizer
      5th Sino-Australian Symposium on Advanced Coal and Biomass Utilisation Technologies
    • Place of Presentation
      Hilton Wuhan Optics Valley (Wuhan, China)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct carbon fuel cell using carbon/carbonate slurry stirred by inert gas bubbling and effect of carbon content on its performance2015

    • Author(s)
      Hirotatsu Watanabe, Akihiro Kimura, Ken Okazaki
    • Organizer
      International Conference on Coal Science & Technology 2015
    • Place of Presentation
      Melbourne Convention and Exhibition Centre (Melbourne, Australia)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンスラリーを用いたダイレクトカーボン燃料電池の発電特性2015

    • Author(s)
      渡部弘達, 木村明宏, 岡崎健
    • Organizer
      第52回日本伝熱シンポジウム
    • Place of Presentation
      福岡国際会議場(福岡)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 粉末状固体炭素を直接燃料とするダイレクトカーボン燃料電池におけるクーロン効率の向上2014

    • Author(s)
      渡部弘達, 古山知諒, 岡崎健
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館(京都府京都市)
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] ダイレクトカーボン燃料電池のアノードにおける 固体炭素の反応特性2014

    • Author(s)
      渡部 弘達, 古山 知諒, 岡崎 健
    • Organizer
      第51回日本伝熱シンポジウム
    • Place of Presentation
      アクトシティ浜松・コングレスセンター(静岡県浜松市)
    • Year and Date
      2014-05-21 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 石炭チャーを直接燃料とするバブリング型ダイレクトカーボン燃料電池の発電特性とアノードオフガス特性2014

    • Author(s)
      古山 知諒, 渡部 弘達, 岡崎 健
    • Organizer
      第51回日本伝熱シンポジウム
    • Place of Presentation
      アクトシティ浜松・コングレスセンター(静岡県浜松市)
    • Year and Date
      2014-05-21 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 単一カーボン粒子を用いたダイレクトカーボン燃料電池におけるアノード反応挙動の解明2014

    • Author(s)
      渡部弘達, 古山知諒, 岡崎健
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜
    • Related Report
      2013 Research-status Report
  • [Presentation] 微粉炭チャーを直接燃料とするバブリング型ダイレクトカーボン燃料電池の開発2014

    • Author(s)
      古山 知諒, 渡部 弘達, 岡崎 健
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜
    • Related Report
      2013 Research-status Report
  • [Remarks]

    • URL

      http://www.mech.titech.ac.jp/~epl/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京工業大学大学院理工学研究科機械制御システム専攻エネルギー事象分野

    • URL

      http://www.mech.titech.ac.jp/~epl/

    • Related Report
      2014 Research-status Report
  • [Remarks] エネルギー事象分野 岡崎研究室

    • URL

      http://www.mech.titech.ac.jp/~epl/

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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