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Development of multi-level spin memory with attractive molecular dots

Research Project

Project/Area Number 25630132
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

HAYAKAWA Ryoma  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 独立研究者 (90469768)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords分子 / スピン / 多機能メモリ / 異種分子 / 光機能 / 自己組織化
Outline of Final Research Achievements

We have proposed multi-functional spin memories, where organic molecules are employed as quantum dots in double tunnel junctions on ferromagnetic electrodes. Organic molecules have many advantages as quantum dots, e.g. size uniformity on nanometer scale, photo-responsivity and spin manipulation. If molecules works as quantum dots, we will realize novel spin memories with new functions which is not realized in inorganic quantum dots. In this study, an atomic layer deposition technique made it possible to form Al2O3 thin films with smooth surface on ferromagnetic electrodes and the films showed excellent insulating properties, which enabled the formation of double tunnel junctions with molecular dots. Furthermore, in the sample with C60 molecules, we observed resonant tunneling through molecular orbitals in the current-voltage measurement. The result shows that the tunneling current injected from ferromagnetic electrodes can be manipulated by energy levels of embedded molecular dots.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (9 results)

All 2014 2013

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (6 results) (of which Invited: 1 results)

  • [Journal Article] Multilevel operation of resonant tunneling with binary molecules in a metal-insulator-semiconductor configuration2014

    • Author(s)
      Hoon-Seok Seo、Ryoma Hayakawa、Toyohiro Chikyow、Yutaka Wakayama
    • Journal Title

      J. Phys. Chem. C

      Volume: Vol. 118 Issue: 12 Pages: 6467-6472

    • DOI

      10.1021/jp411386s

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoisomerization -induced manipulation of single-electron tunneling for novel Si-based optical memory2013

    • Author(s)
      Ryoma Hayakawa、Kenji Higashiguchi、Kenji Mtsuda、Toyohiro Chikyow、Yutaka Wakayama
    • Journal Title

      ACS Appl. Matter. Interfaces

      Volume: Vol. 5 Issue: 21 Pages: 11371-11376

    • DOI

      10.1021/am403616m

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Optically- and electrically- driven organic thin film transistors with photochromic diarylethene channel layers2013

    • Author(s)
      Ryoma Hayakawa、Kenji Higashiguchi、Kenji Matsuda、Toyohiro Chikyow、Yutaka Wakayama
    • Journal Title

      ACS Appl. Matter. Interfaces

      Volume: Vol. 5 Issue: 9 Pages: 3625-3630

    • DOI

      10.1021/am400030z

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 分子による単一電子トンネル電流制御 -次世代超低消費電子デバイスの実現に向けて-2014

    • Author(s)
      早川 竜馬
    • Organizer
      第3回JACI/GSCシンポジウム
    • Place of Presentation
      東京国際フォーラム
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Multi-functional single-electron devices with attractive molecular dots2014

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      ICN10
    • Place of Presentation
      National Institute of Standards and Technology, Gaithersburg, Maryland,USA
    • Year and Date
      2014-05-13 – 2014-05-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoisomerization-induced manipulation of single-electron tunneling2014

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      2014 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Moscone West,San Francisco, California, USA
    • Year and Date
      2014-04-21 – 2014-04-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoisomerization-induced manipulation of single-electron tunneling in a silicon-based double tunnel junction2014

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      MANA international symposium 2014
    • Place of Presentation
      つくば国際会議場 (茨城県つくば市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Optically- and electrically-driven organic thin film transistors with diarylethene channel layers2013

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      ECME 2013
    • Place of Presentation
      Imperial College London Great Hall (London,United Kingdom)
    • Related Report
      2013 Research-status Report
  • [Presentation] Integration of molecular functionalities into Si-based devices2013

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      NIMS conference 2013
    • Place of Presentation
      つくば国際会議場 (茨城県つくば市)
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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