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Terahertz emission from graphene/semicnductor junctions and its application to gas sensors

Research Project

Project/Area Number 25630149
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electron device/Electronic equipment
Research InstitutionOsaka University

Principal Investigator

TONOUCHI MASAYOSHI  大阪大学, レーザーエネルギー学研究センタ, 教授 (40207593)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsグラフェン / テラヘルツ / 表面反応 / ガスセンサー
Outline of Final Research Achievements

We demonstrate a new approach to visualize the distribution of molecular adsorbates on graphene using terahertz emission spectroscopy and imaging. We found that the waveforms of terahertz radiation from graphene-coated InP sensitively changed with the type of the atmospheric gas, the laser illumination time. The terahertz waveform change is explained through band structure modifications in the InP surface depletion layer due to the presence of localized electric dipoles induced by adsorbed oxygen. These results demonstrate that terahertz emission serves as a local probe for monitoring adsorption and desorption processes on graphene films and devices, suggesting a novel two-dimensional sensor for detecting local chemical reactions.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (15 results)

All 2015 2014 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (11 results) (of which Invited: 1 results)

  • [Journal Article] グラフェン/半導体接合からのテラヘルツ波放射特性とのそのセンサ応用2015

    • Author(s)
      川山巌、斗内政吉
    • Journal Title

      光アライアンス

      Volume: 26 Pages: 15-18

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Imaging molecular adsorption and desorption dynamics on graphene using terahertz emission spectroscopy2014

    • Author(s)
      Y. Sano, I. Kawayama, M. Tabata, K. A. Salek, H. Murakami, M. Wang, R. Vajtai, P. M. Ajayan, J. Kono, and M. Tonouchi
    • Journal Title

      Scientific Reports

      Volume: 4 Issue: 1

    • DOI

      10.1038/srep06046

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Evaluation of Surface Carrier Recombination of Optically Excited Silicon using Terahertz Time-Domain Spectroscopy2014

    • Author(s)
      K. A. Salek, K. Takayama, I. Kawayama*, H. Murakami, M. Tonouchi
    • Journal Title

      Terahertz Science and Technology

      Volume: 7 Pages: 100-107

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Scanning laser terahertz near-field imaging system2012

    • Author(s)
      Kazunori Serita
    • Journal Title

      Optics Express

      Volume: 20 Issue: 12 Pages: 12959-12965

    • DOI

      10.1364/oe.20.012959

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Measuring Photo-oxidation Effect in WS2 Nanosheets using Laser Terahertz Emission Spectroscopy2015

    • Author(s)
      Jofferson Gonzales, F.R. Bagsican, Iwao Kawayama, Hironaru Murakami, A. Winchester, S. Ghosh, S. Talapatra, Masayoshi Tonouchi
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] テラヘルツ時間領域分光法によるグラフェンの光学伝導度の基板及び温度依存性2015

    • Author(s)
      川野慎也, 大城誠, 川山巌, 村上博成, james alled, Minjie Wang, 河野純一郎, Robert Vajtal, Pulickel M. Ajayan, 斗内政吉
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Laser THz Emission Spectroscopy of Gas Adsorption-Desorption Dynamics in Graphene2015

    • Author(s)
      Filchito Renee Bagsican, Iwao Kawayama, Andrew Winchester, Sujoy Ghosh, Minjie Wang, Hironaru Murakami, Robert Vajtai, Pulickel Ajayan, Junichiro Kono, Saikat Talapatra and Masayoshi Tonouchi
    • Organizer
      Optical Terahertz Sciences and Technology conference
    • Place of Presentation
      San Diego
    • Year and Date
      2015-03-08 – 2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Infrared-Induced Photo-Oxidation in WS2 Nanosheets Observed using Laser Terahertz Emission Spectroscopy2015

    • Author(s)
      Filchito Renee Bagsican, Iwao Kawayama, Hironaru Murakami, Andrew Winchester, Sujoy Ghosh, Saikat Talapatra and Masayoshi Tonouchi
    • Organizer
      Optical Terahertz Sciences and Technology conference
    • Place of Presentation
      San Diego
    • Year and Date
      2015-03-08 – 2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Visualizing the distribution of molecular adsorbates on graphene using a laser terahertz emission microscope2014

    • Author(s)
      I. Kawayama, Y. Sano, M. Tabata, K. Salek, M. Murakami, M. Wang, R. Vajtai, J. Kono, P. M. Ajayan and M. Tonouchi
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      松江
    • Year and Date
      2014-11-03 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Terahertz emission from semi-insulating InP surface coated with WS2 nanosheets prepared by liquid phase exfoliation2014

    • Author(s)
      F.R. Bagsican, I. Kawayama, H. Murakami, A. Winchester, S. Ghosh, S. Talapatra, M. Tonouchi
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      松江
    • Year and Date
      2014-11-03 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] THz emission properties from InP wafers covered with graphene excited with fs optical pulses2014

    • Author(s)
      Masayoshi Tonouchi
    • Organizer
      Ultrafast Phenomena at the Nanoscale
    • Place of Presentation
      沖縄
    • Year and Date
      2014-07-11 – 2014-07-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Monitoring of molecular adsorption and desorption dynamics on graphene using terahertz emission2014

    • Author(s)
      I. Kawayama, Y. Sano1, M. Tabata, K. Salek, M. Murakami1, M. Wang, R. Vajtai, J. Kono, P. M. Ajayan and M. Tonouchi
    • Organizer
      4th EOS Topical Meeting on Terahertz Science & Technology
    • Place of Presentation
      Hotel Cenobio dei Dogi, Camogli, Italy
    • Year and Date
      2014-05-11 – 2014-05-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Terahertz time-domain spectroscopy of large-area graphene on various substrates2014

    • Author(s)
      Iwao Kawayama , Makoto Ohshiro , Yuki Sano , Hironaru Murakami , James Allred , Minjie Wang , Junichiro Kono , Robert Vajtai , Pulickel Ajayan , Masayoshi Tonouchi
    • Organizer
      APS March meeting 2014
    • Place of Presentation
      Denver, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Gase sensing using on terahertz emissions from graphene-coated InP surfaces2014

    • Author(s)
      Masayoshi Tonouchi, Iwao Kawayama, Yuki Sano, Khandoker Abu Salek, Hironaru, Murakami, Mika Tabata, Minjie Wang, Robert Vajtai, Junichiro Kono, Pulickel M. Ajayan
    • Organizer
      APS March meeting 2014
    • Place of Presentation
      Denver, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Terahertz Emission From Graphene-Coated InP (100) Surface2013

    • Author(s)
      Iwao Kawayama, Yuki Sano, Khandoker Abu Salek, Masayoshi Tonouchi, Mika Tabata, Minjie Wang, Robert Vajtai, Junichiro Kono, Pulickel M. Ajayan
    • Organizer
      MRS Fall meeting 2013
    • Place of Presentation
      Boston, USA
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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