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The study on supercooling and solidification process of Mn-based ferromagnets under high magnetic fields

Research Project

Project/Area Number 25630268
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionKagoshima University

Principal Investigator

Koyama keiichi  鹿児島大学, 理工学域理学系, 教授 (70302205)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords金属物性 / 構造機能性材料 / 磁性 / 構造・機能性材料 / 複合材料・物性 / 物性実験
Outline of Final Research Achievements

For studying in-field process of melting and solidification visually and quantitatively, in-situ observation system with differential thermal analysis (DTA) utilized in high temperature and high magnetic field was developed. Decomposition processes of the bulk sample of ferromagnetic MnBi were directly observed with collecting DTA data under a high field of 10 T for 290-770 K. When the temperature was over decomposition point (MnBi -> paramagnetic Mn1.08Bi + liquid), liquid phase appeared on the sample surface. When the temperature was over peritectic temperature (~ 700 K: Mn1.08Bi -> Mn + liquid), the sample surface was broken and a large quantity of the liquid phase appeared from the sample. The decomposition temperature increased from 620 K for a zero field to 638 K for a magnetic field of 10 T. A magnetic field effect on the suprcooling state of Mn + liquid -> Mn1.08Bi and MnBi was observed. MnBi bulk magnets were synthesized by heat treatment under a high field.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (22 results)

All 2016 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (17 results) (of which Int'l Joint Research: 6 results,  Invited: 5 results) Remarks (2 results)

  • [Journal Article] In-situ observation and differential thermal analysis of MnBi in high magnetic fields2015

    • Author(s)
      Daiki Miyazaki, Yoshifuru Mitsui, Ken-ichi Abematsu,Kohki Takahashi, Kazuo Watanabe, Satoshi Uda, Keiichi Koyama
    • Journal Title

      Physics Procedia

      Volume: 75 Pages: 1324-1331

    • DOI

      10.1016/j.phpro.2015.12.148

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Magnetic field effect on the liquid boundary of Bi-Mn binary system2014

    • Author(s)
      Y. Mitsui, K. Koyama, K. Oikawa, K. Watanabe
    • Journal Title

      AIP Conference Proceedings

      Volume: 1618 Pages: 269-272

    • DOI

      10.1063/1.4897725

    • Related Report
      2014 Research-status Report
  • [Journal Article] Magnetic properties of Mn2Sb1-xZx (Z = Ge, Sn)2013

    • Author(s)
      Keiichi KOYAMA, Daisuke SHIMADA, Hiroki ORIHASHI, Daisuke MITSUNAGA, Masahiko HIROI, Kazuyuki MATSUBAYASHI, Yoshiya UWATOKO, Reisho ONODERA, Shojiro KIMURA, Kohki TAKAHASHI
    • Journal Title

      Reports of the Faculty of Science,Kagoshima University

      Volume: 46 Pages: 37-42

    • Related Report
      2013 Research-status Report
  • [Presentation] Magnetic Field-Induced Synthesis of Ferromagnetic Phase2016

    • Author(s)
      Keiichi Koyama, Yoshifuru Mitsui
    • Organizer
      18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2016-08-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetic Fields Effect on Phase Formation of Ferromagnetic MnBi Synthesized by Reactive Sintering2016

    • Author(s)
      Daiki Miyazaki, Yoshifuru Mitsui, Kohki Takahashi,Keiichi Koyama
    • Organizer
      The 4th International Conference of Asian Union of Magnetics Societies
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2016-08-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic Field-Induced L10-Ferromagnetic MnAl2016

    • Author(s)
      R. Kobayashi, Y. Mitsui, R. Y. Umetsu, K. Takahashi, M. Mizuguchi, K. Koyama
    • Organizer
      The 4th International Conference of Asian Union of Magnetics Societies
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2016-08-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Crystallization in Mn-based Alloys by In-field heat treatment2016

    • Author(s)
      Yoshifuru Mitsui, Ryota Kobayashi, Ken-ichi Abematsu, Rie Y. Umetsu, Kohki Takahashi, Masaki Mizuguchi, Keiichi Koyama
    • Organizer
      7th International Workshop on Materials Analysis and Processing in Magnetic Fields
    • Place of Presentation
      Providence, USA
    • Year and Date
      2016-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-Magnetic-Field Synthesis for Ferromagnetic Mn-Al Alloys2016

    • Author(s)
      R. Kobayashi, Y. Mitsui, R. Y. Umetsui, K. Takahashi, M. Mizuguchi, K. Koyama
    • Organizer
      7th International Workshop on Materials Analysis and Processing in Magnetic Fields
    • Place of Presentation
      Providence, USA
    • Year and Date
      2016-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mn-Al合金に対する磁場中熱処理効果2016

    • Author(s)
      小林領太, 三井好古, 梅津理恵, 高橋弘紀, 水口将輝, 高梨弘毅, 小山佳一
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] MnBiの強磁場中合成分解過程2016

    • Author(s)
      小山佳一, 宮崎泰樹, 三井好古, 高橋弘紀, 宇田聡
    • Organizer
      日本物理学会
    • Place of Presentation
      東北学院大学(宮城県仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Bi-Mn合金を用いた合成過程の磁場中その場観察2015

    • Author(s)
      宮崎泰樹, 三井好古, 宇田聡, 渡辺和雄, 小山佳一
    • Organizer
      日本物理学会九州支部会
    • Place of Presentation
      九州工業大学(福岡県北九州市)
    • Year and Date
      2015-12-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] In-situ observation for reaction sintering behavior of Bi-Mn alloy in high magnetic fields2015

    • Author(s)
      D. Miyazaki, Y. Mitsui, K. Abematsu, K.Takahashi, S. Uda, K. Watanabe, K. Koyama
    • Organizer
      International Conference on Magnetism
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi-Mn合金の合成過程における磁場中形態変化観測2015

    • Author(s)
      宮崎泰樹, 三井好古,アベ松賢一,高橋弘紀, 宇田聡, 渡辺和雄, 小山佳一
    • Organizer
      日本金属学会九州支部会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] 強磁場中における熱分析・その場観察装置の開発2014

    • Author(s)
      宮崎泰樹、三井好古、アベ松賢一、高橋弘紀、宇田聡、渡辺和雄、小山佳一
    • Organizer
      応用物理学会
    • Place of Presentation
      北海道大学、北海道、札幌市
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of new in-field analytical system and synthesis of ferromagnetic materials under high magnetic fields2014

    • Author(s)
      K. Koyama
    • Organizer
      日本磁気学会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、神奈川県、横浜市
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Development of composite system of in-situ observation and differential thermal analysis2014

    • Author(s)
      D. Miyazaki, Y. Mitsui, K. Abematsu, K. Takahashi, K. Koyama, S. Uda, K. Watanabe
    • Organizer
      6th International Workshop on Materials Analysis and Processing in Magnetic Fields
    • Place of Presentation
      サザンビーチリゾートホテル沖縄、沖縄県、糸満市
    • Year and Date
      2014-07-08 – 2014-07-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 熱分析・溶解真空炉装置の開発2014

    • Author(s)
      宮﨑泰樹、三井好古、小山佳一、前田健作、高橋弘紀、宇田聡、渡辺和雄
    • Organizer
      日本金属学会九州支部・日本鉄鋼協会九州支部・軽金属学会九州支部平成26年度合同学術講演会
    • Place of Presentation
      九州大学、福岡県、福岡市
    • Year and Date
      2014-06-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic Field Effect on the Equilibrium Diagram of Bi-Mn Binary System2014

    • Author(s)
      K. Koyama, Y. Mitsuib, K. Oikawac and K. Watanabe
    • Organizer
      10th International Conference of Computational Methods in Sciences and Engineering
    • Place of Presentation
      アテネ市、ギリシャ
    • Year and Date
      2014-04-04 – 2014-04-07
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 磁場による強磁性体の相転移制御2014

    • Author(s)
      小山佳一
    • Organizer
      遍歴電子系研究会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 強磁場下における強磁性体MnBiの相変化2013

    • Author(s)
      小山佳一
    • Organizer
      日本学術振興会第161委員会第83回研究会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Remarks] 鹿児島大学大学院理工学研究科 物理宇宙専攻 磁気物理学( 小山、三井研究室)

    • URL

      http://www.sci.kagoshima-u.ac.jp/~koyama/K-Lab/Welcome.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 鹿児島大学大学院理工学研究科物理宇宙専攻 磁気物理学

    • URL

      http://www.sci.kagoshima-u.ac.jp/~koyama/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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