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Visualizing adsorption/reaction of gas molecules on catalytic surface by energy-filtering environmental TEM

Research Project

Project/Area Number 25630280
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionNagoya University

Principal Investigator

MUTO Shunsuke  名古屋大学, エコトピア科学研究所, 教授 (20209985)

Research Collaborator ARAI Shigeo  名古屋大学, エコトピア科学研究所, 特任准教授
山本 悠太  名古屋大学, エコトピア科学研究所, 技術職員
樋口 公孝  名古屋大学, エコトピア科学研究所, 技術職員
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords微粒子触媒 / 電子顕微鏡 / 電子分光 / 触媒 / 化学反応可視化 / 統計処理 / 自動車排気ガス浄化 / 可視化 / 金属クラスター
Outline of Final Research Achievements

The purpose of this study is to visulaize gas molecules adsorbed on a ceramics-supporting fine metal particle surface, using the Reaction Science Ultra-High Voltage Scanning Transmission Electron Microscope in Nagoya University and to identify the reaction active site.
We applied an energy-filtering spectral imaging technique to Au-Ni bimetallic fine particles supported by SiO2 and were successful in visualizing NO and CO gas adsorption on their surface. In addition, we applied a multivariate analysis to the obtained data, resolving the spectrum of the gas molecules for identifying which gas specie is actually adsorbed. A research paper reporting the results above is now in preparation.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (7 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (5 results) (of which Invited: 1 results)

  • [Journal Article] Development of an environmental high voltage electron microscope and its application to nano and bio-materials2014

    • Author(s)
      N. Tanaka, J. Usukura, M. Kusunoki, Y. Saito, K. Sasaki, T. Tanji, S. Muto, S. Arai
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 522 Pages: 012008-012008

    • DOI

      10.1088/1742-6596/522/1/012008

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] In situ study of anode reaction in intermediate temperature solid oxide fuel cells2013

    • Author(s)
      A. H. Tavabi, S. Muto, T. Tanji, R. E. Dunin-Borkowski
    • Journal Title

      Microscopy and Microanalysis

      Volume: 19-S2 Issue: S2 Pages: 494-495

    • DOI

      10.1017/s1431927613004467

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] New era (?) of ultra-high voltage analytical S/TEM2015

    • Author(s)
      S. Muto
    • Organizer
      International Symposium on New Movements of Electron Microscopy for the Next Generation
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-03-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ナノスケール触媒観察へのSEMの可能性2014

    • Author(s)
      武藤俊介
    • Organizer
      日本顕微鏡学会「SEMの物理学」分科会合宿討論会
    • Place of Presentation
      ラフォーレ琵琶湖
    • Year and Date
      2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] セラミックス担持 Au-Ni 微粒子触媒の化学状態分析2013

    • Author(s)
      呉健民,武藤俊介,巽一厳,櫻林靖哲,田中展望,平田裕人,白川翔吾
    • Organizer
      日本顕微鏡学会第69回学術講演会
    • Place of Presentation
      ホテル阪急エキスポパーク
    • Related Report
      2013 Research-status Report
  • [Presentation] セラミックス担持Au-Ni微粒子触媒の化学状態分析2013

    • Author(s)
      呉健民,武藤俊介,巽一厳,櫻林靖哲,田中展望,平田裕人,白川翔吾
    • Organizer
      2013年日本金属学会秋期講演大会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Chemical state analysis of ceramics-supported Au-Ni fine particle catalyst2013

    • Author(s)
      C. Wu,S. Muto, K. Tatsumi,Y. Sakurabayashi, H. Tanaka, H. Hirata, S. Shirakawa
    • Organizer
      International Symposium EcoTopia Science, ISETS’13
    • Place of Presentation
      Nagoya University
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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