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Syntheses and characterization of highly grain-aligned polycrystalline materials by reactive diffusion between solids and gases

Research Project

Project/Area Number 25630281
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionNagoya Institute of Technology

Principal Investigator

FUKUDA Koichiro  名古屋工業大学, 工学(系)研究科(研究院), 教授 (90189944)

Co-Investigator(Renkei-kenkyūsha) ASAKA Toru  名古屋工業大学, 工学研究科, 准教授 (80525973)
YOSHIDA Hideto  東京大学, 理学研究科, 技術職員 (30376553)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords結晶配向セラミックス / 酸化物イオン伝導 / 反応拡散 / 固体酸化物型燃料電池
Outline of Final Research Achievements

We have prepared the highly c-axis-oriented polycrystalline material of apatite-type La9.33+2xGe6O26+3x by isothermal heating of the randomly grain-oriented ceramics material and gases at high temperatures. In our previous studies, we reported the formation of highly grain-aligned polycrystalline lanthanum silicate oxyapatite (La9.33+2xSi6O26+3x) by the solid-state reactive diffusion. The present study reports, for the first time, the successful preparation of the grain-aligned polycrystalline material, using the same technique, between solid and gases. The authors think that one of the most significant implications of this research is that we successfully extended the reactive diffusion system from solid-solid to those including solid-gases in the preparation of grain-aligned ceramics. The present solid-gas interaction technique could be widely applicable to the other grain-aligned materials.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (24 results)

All 2015 2014 2013 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (20 results) (of which Invited: 3 results) Remarks (2 results)

  • [Journal Article] c軸配向アパタイト型ケイ酸ランタン多結晶体の作製と酸化物イオン伝導2014

    • Author(s)
      福田 功一郎
    • Journal Title

      日本結晶学会誌

      Volume: 56 Pages: 43-48

    • NAID

      130003395584

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structure and Oxide-Ion Conductivity along c-Axis of Si-Deficient Apatite-Type Lanthanum Silicate2013

    • Author(s)
      K. Fukuda, T. Asaka, S. Hara, M. Oyabu, A. Berghout, E. Bechade, O. Masson, I. Julien, and P. Thomas
    • Journal Title

      Chem. Mater.

      Volume: 25 Issue: 10 Pages: 2154-2162

    • DOI

      10.1021/cm400892p

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 回折法と顕微鏡法を用いた新規無機化合物の探索と機能発現2015

    • Author(s)
      福田 功一郎
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学(岡山県岡山市)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ケイ酸ランタンオキシアパタイトの高温単結晶X線回折法と結合原子価の総和(BVS)法による酸化物イオン伝導経路に関する研究2014

    • Author(s)
      原 晋次、浅香 透、石澤 伸夫、福田 功一郎
    • Organizer
      日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Year and Date
      2014-12-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 反応拡散による結晶配向セラミックスの新規作製方法 ― c軸配向アパタイト型ケイ酸ランタン多結晶体の作製 ―2014

    • Author(s)
      福田 功一郎
    • Organizer
      日本セラミックス協会2014年秋季シンポジウム
    • Place of Presentation
      鹿児島大学(鹿児島県鹿児島市)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Reactive Diffusion as A New Facile Texturing Method for Syntheses of Highly Grain-Oriented Oxide-Ion Conductors2014

    • Author(s)
      Koichiro Fukuda
    • Organizer
      JSPS-CNRS Joint Seminar “Material Design and Development of Highly Ionic-Conductive Ceramics Devices”
    • Place of Presentation
      Limoges(France)
    • Year and Date
      2014-06-04 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Crystal Structure and Oxide-Ion Conductivity along c-Axis of Oxygen Hyperstoichiometric Lanthanum Silicate Apatite2014

    • Author(s)
      原 晋次、大藪 雅之、浅香 透、福田 功一郎
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 化学組成と結晶構造の異なるアパタイト型ケイ酸ランタンからなるc軸配向多結晶体の作り分け2014

    • Author(s)
      大藪 雅之、原 晋次、浅香 透、福田 功一郎
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of Highly c-Axis-Oriented Apatite-Type Lanthanum Silicate Polycrystals by Combined Use of Reactive Diffusion and Tape Casting2014

    • Author(s)
      S. Hara, T. Asaka, K. Fukuda, A. Pons, P.-M. Geffroy, E. Bechade, O. Masson, J. Jouin, M. Colas, P. Thomas
    • Organizer
      3rd International Symposium on Ceramics Nanotune Technology
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] Crystal Chemistry of Complex Materials: Apatite-Type Lanthanum Silicates for SOFC Applications and Tellurium Oxide Based Glasses for Non-linear Optics2014

    • Author(s)
      P. Thomas, O. Masson, E. Bechade A. Berghout, M. Colas, J. R. Duclere, I. Julien, J. Jouin, D. Hamani, G. Delaizir, A. Gulenko, A. Bertrand, A. Pons, J. Carreaud, O. Nouguera, P.-M. Geffroy, K. Fukuda, T. Asaka, T. Hhayakawa, M. Nogami
    • Organizer
      3rd International Symposium on Ceramics Nanotune Technology
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 反応拡散法を用いて作製したc軸配向酸化物イオン伝導体の組織構造2013

    • Author(s)
      岡部 桃子、浅香 透、福田 功一郎
    • Organizer
      日本顕微鏡学会学術講演会
    • Place of Presentation
      大阪
    • Related Report
      2013 Research-status Report
  • [Presentation] Oxide-ion conductivity of highly c-axis-oriented apatite-type lanthanum silicate polycrystals2013

    • Author(s)
      K. Fukuda, T. Asaka, A. Berghout, E. Behade, O. Masson, I. Julien and P. Thomas
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Syntheses and characterization of highly c-axis-oriented apatite-type lanthanum silicate polycrystals2013

    • Author(s)
      M. Oyabu, K. Fukuda, T. Asaka, A. Berghout, E. Bechade, O. Masson, I. Julien and P. Thomas
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Local structure in La9.33+x(SiO4)6O2+y studied by X-ray PDF analysis and DFT calculations2013

    • Author(s)
      A. Berghout, O. Masson, P. Thomas, J. Jouin, E. Bechade, G. Leveque, I. Julien, R. Mayet, R. Hamaguchi, T. Asaka and K. Fukuda
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Characterization of highly c-axis-oriented apatite-type lanthanum silicate polycrystals formed by reactive diffusion between L2013

    • Author(s)
      M. Okabe, T. Asaka, K. Fukuda, A. Berghout, E. Bechade, O. Masson, I. Julien and P. Thomas
    • Organizer
      13th International Conference of the European Ceramic Society
    • Place of Presentation
      Limoges(France)
    • Related Report
      2013 Research-status Report
  • [Presentation] Crystal structure and oxide-ion conductivity of apatite-type lanthanum silicate with excess oxide ions2013

    • Author(s)
      S. Hara, K. Fukuda, T. Asaka, A. Berghout, E. Bechade, O. Masson, I. Julien and P. Thomas
    • Organizer
      13th International Conference of the European Ceramic Society
    • Place of Presentation
      Limoges(France)
    • Related Report
      2013 Research-status Report
  • [Presentation] Crystal structures and oxide-ion conductivity along c-axis of apatite-type lanthanum silicates2013

    • Author(s)
      K. Fukuda
    • Organizer
      13th International Conference of the European Ceramic Society
    • Place of Presentation
      Limoges(France)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] New synthesis method and oxide ion conductivity of pure apatite-type La9.33+x(SiO4)6 O2+3x/2 phases2013

    • Author(s)
      G. Leveque, E. Bechade, I. Julien, J. Jouin, O. Masson, P. Thomas, T. Asaka, and K. Fukuda
    • Organizer
      13th International Conference of the European Ceramic Society
    • Place of Presentation
      Limoges(France)
    • Related Report
      2013 Research-status Report
  • [Presentation] Local structure in La9.33+x(SiO4)6O2+y studied by X-ray PDF analysis and DFT calculations2013

    • Author(s)
      O. Masson, J. Jouin, A. Berghout, P. Thomas, G. Leveque, I. Julien, R. Mayet, E. Bechade, K. Fukuda, T. Asaka, R. Hamaguchi
    • Organizer
      13th International Conference of the European Ceramic Society
    • Place of Presentation
      Limoges(France)
    • Related Report
      2013 Research-status Report
  • [Presentation] Si欠損型ケイ酸ランタンアパタイトの結晶構造解析と酸化物イオン伝導2013

    • Author(s)
      福田 功一郎、原 晋次、大藪 雅之、浅香 透
    • Organizer
      日本セラミックス協会2013年秋季シンポジウム
    • Place of Presentation
      長野
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis, structure and ionic conduction mechanisms of apatite-type lanthanum silicate materials for SOFC applications2013

    • Author(s)
      O. Masson, A. Berghout P.Thomas, G. Leveque, I. Julien, R. Mayet, J.Jouin, E.Bechade, K. Fukuda, T. Asaka, R. Hamaguchi
    • Organizer
      2nd International Symposium on Inorganic and Environmental Materials
    • Place of Presentation
      Renne(France)
    • Related Report
      2013 Research-status Report
  • [Presentation] アパタイト型ケイ酸ランタン多結晶体のc軸配向化とGeドーピングによる酸化物イオン伝導度の向上2013

    • Author(s)
      蓑 弘樹,浅香 透,石澤 伸夫,福田 功一郎
    • Organizer
      日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Remarks] 名古屋工業大学 結晶性萌芽材料研究室(福田功一郎・浅香透研究室)

    • URL

      http://crystals.web.nitech.ac.jp

    • Related Report
      2014 Annual Research Report
  • [Remarks] 名古屋工業大学 結晶性萌芽材料研究室(福田功一郎・浅香透研究室)

    • URL

      http://crystals.web.nitech.ac.jp

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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