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Fast oxide-ion conductor-assisted novel catalytic function

Research Project

Project/Area Number 25630284
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionOkayama University

Principal Investigator

MIYAKE Michihiro  岡山大学, その他の研究科, 教授 (30143960)

Co-Investigator(Kenkyū-buntansha) KAMESIMA Yoshikazu  岡山大学, 大学院環境生命科学研究科, 准教授 (50251616)
NISHIMOTO Shunsuke  岡山大学, 大学院環境生命科学研究科, 助教 (90435826)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords改質触媒 / ニッケル / 触媒担体 / 酸化物イオン伝導体 / ペロブスカイト化合物 / バイオエタノール / バイオガス / 炭素析出抑制 / べロブスカイト化合物 / リフォーミング触媒
Outline of Final Research Achievements

Reforming reactions of bioethanol and biogas to hydrogen and carbon monoxide are industrially important, using Ni catalyst. Side reactions, however, cause carbon deposition and inactivation of the catalyst. In the study, catalyst supports with fast oxide-ion conductivity, which were expected to have resistance to carbon deposition. According to the results, it was found that LaGaO3-, LaAlO3- and BaTiO3-based oxides functioned as inhibitors, depressing carbon deposition. The function was likely due to the mobile oxide ions in the catalyst supports.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (5 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (3 results)

  • [Journal Article] Biogas reforming over BaTi1-xSnxO3-supported Ni-based catalysts recovered from spent Ni-metal-hydride batteries2015

    • Author(s)
      M. Miyake, N. Tomiyama, K. Iwamoto, K. Nagase, S. Nishimoto, Y. Kameshima
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 40 Issue: 26 Pages: 8341-8346

    • DOI

      10.1016/j.ijhydene.2015.04.106

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of nickel nanoparticles with excellent thermal stability in micropores of zeolite2013

    • Author(s)
      H. Inokawa, M. Maeda, S. Nishimoto, Y. Kameshima, M. Miyake, T. Ichikawa, Y. Kojima, H. Miyaoka
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 38 Issue: 31 Pages: 13579-13586

    • DOI

      10.1016/j.ijhydene.2013.08.027

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ランタンアルミネート系ペロブスカイト化合物を用いたバイオガス改質触媒の開発2015

    • Author(s)
      岩本和仁,西本俊介,亀島欣一,三宅通博
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山市
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ランタンガレート系ペロブスカイト化合物を用いたバイオガス改質触媒の開発2014

    • Author(s)
      岩本和仁,西本俊介,亀島欣一,三宅通博
    • Organizer
      日本セラミックス協会第27回秋季シンポジウム
    • Place of Presentation
      鹿児島市
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] バイオガス改質触媒の作製と改質反応への水蒸気の影響2013

    • Author(s)
      岩本和仁
    • Organizer
      第20回ヤングセラミストミーティングin中四国
    • Place of Presentation
      岡山市
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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