Project/Area Number |
25630284
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Inorganic materials/Physical properties
|
Research Institution | Okayama University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
KAMESIMA Yoshikazu 岡山大学, 大学院環境生命科学研究科, 准教授 (50251616)
NISHIMOTO Shunsuke 岡山大学, 大学院環境生命科学研究科, 助教 (90435826)
|
Project Period (FY) |
2013-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
Keywords | 改質触媒 / ニッケル / 触媒担体 / 酸化物イオン伝導体 / ペロブスカイト化合物 / バイオエタノール / バイオガス / 炭素析出抑制 / べロブスカイト化合物 / リフォーミング触媒 |
Outline of Final Research Achievements |
Reforming reactions of bioethanol and biogas to hydrogen and carbon monoxide are industrially important, using Ni catalyst. Side reactions, however, cause carbon deposition and inactivation of the catalyst. In the study, catalyst supports with fast oxide-ion conductivity, which were expected to have resistance to carbon deposition. According to the results, it was found that LaGaO3-, LaAlO3- and BaTiO3-based oxides functioned as inhibitors, depressing carbon deposition. The function was likely due to the mobile oxide ions in the catalyst supports.
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