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Fast phase change speed induced by surface oxidation of phase change material

Research Project

Project/Area Number 25630289
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionTohoku University

Principal Investigator

SUTOU Yuji  東北大学, 工学(系)研究科(研究院), 准教授 (80375196)

Co-Investigator(Renkei-kenkyūsha) KOIKE Junichi  東北大学, 未来科学技術共同研究センター, 教授 (10261588)
ANDO Daisuke  東北大学, 大学院工学研究科, 助教 (50615820)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords相変化メモリ / 不揮発性メモリ / 表面酸化 / 不均一核生成 / 結晶化 / 相変化材料 / アモルファス
Outline of Final Research Achievements

Phase change random access memory (PCRAM) has attracted much attention as a new class of non-volatile memory because of its low production cost and high scalability. Now, Ge-Sb-Te material is used for PCRAM because of its fast phase change speed and good repeatability. However, the Ge-Sb-Te shows low crystallization temperature (Tc) and consequently insufficient high temperature data retention. Meanwhile, a material with a high Tc shows a slow phase change speed. Therefore, an idea to realize a material with high Tc and fast crystallization speed is desired. In this study, we investigated the effect of preferential surface oxidation on crystallization speed in GeTe-Si phase change material. It was found that the crystallization starting time of the surface-oxidized film by O2 plasma-treatment was about 20% faster than that of a non-oxidized film. This fast crystal nucleation was suggested to be due to the formation of inhomogeneous nucleation sites at the film surface.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (10 results)

All 2014 2013

All Journal Article (3 results) (of which Open Access: 2 results,  Acknowledgement Compliant: 2 results,  Peer Reviewed: 1 results) Presentation (6 results) (of which Invited: 2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] A study on phase change characteristics of (GeTe)1-xSix films2014

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike
    • Journal Title

      Proceedings of the 26th symposium on Phase Change Oriented Science PCOS2014

      Volume: 1 Pages: 53-56

    • Related Report
      2014 Annual Research Report
    • Open Access / Acknowledgement Compliant
  • [Journal Article] Fast crystallization in Si-doped GeTe amorphous film by surface oxidation2014

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike
    • Journal Title

      Proceedings of European Phase Change and Ovonics Symposium E/PCOS 2014

      Volume: 1 Pages: 109-110

    • Related Report
      2014 Annual Research Report
    • Open Access / Acknowledgement Compliant
  • [Journal Article] Investigation of a selective switching device using a phase-change material for a 3-dimensional PCRAM array2013

    • Author(s)
      JM. Lee, YH. Song, Y. Saito, Y. Sutou, J. Koike
    • Journal Title

      J. Kore. Phys. Soc

      Volume: 62 Issue: 9 Pages: 1258-1263

    • DOI

      10.3938/jkps.62.1258

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] A study on phase change characteristics of (GeTe)1-xSix films2014

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike
    • Organizer
      The 26th symposium on Phase Chnage Oriented Science PCOS2014
    • Place of Presentation
      浜松、浜名湖ロイヤルホテル
    • Year and Date
      2014-12-04 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fast crystallization in Si-doped GeTe amorphous film by surface oxidation2014

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike
    • Organizer
      European Phase Change and Ovonics Symposium E/PCOS 2014
    • Place of Presentation
      マルセイユ、フランス
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] PCRAM用Ge-Te系薄膜の相変化挙動2013

    • Author(s)
      須藤祐司
    • Organizer
      第138回結晶工学分科会研究会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Phase Transition Characteristics of GeCu2Te3Film for PCRAM2013

    • Author(s)
      Y. Sutou, Y. Saito, and J. Koike
    • Organizer
      ADMETA2013
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Phase transition characteristics of GeCu2Te3 film2013

    • Author(s)
      Y. Sutou
    • Organizer
      PCOS 2013
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Feasibility study of Ge2Sb2Te5/GeCu2Te3 memory cell with multi-level resistance2013

    • Author(s)
      S. Shindo, Y. Saito, Y. Sutou, J. Koike, J.M. Lee and Y.H. Song
    • Organizer
      PCOS 2013
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 多段相変化材料および多値記録相変化型メモリ素子2014

    • Inventor(s)
      須藤祐司、小池淳一、齋藤雄太
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-124774
    • Filing Date
      2014-06-17
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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