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Precipitation Control of Sigma Phase in Austenitic Heat-resistant Steels

Research Project

Project/Area Number 25630300
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

TAKEYAMA Masao  東京工業大学, 理工学研究科, 教授 (30251622)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords相平衡 / 粒界析出 / tP30 / 相安定性 / Fe-Ni-Cr-Mo / Fe-Ni-Cr-Mn / 合金設計 / 固溶軟化 / 状態図 / Fe-Ni-Cr / 耐熱鋼 / 格子安定度 / 構造材料 / 社会基盤構造材料 / TTP図
Outline of Final Research Achievements

Phase stability, phase equilibria and the precipitation behavior of σ phase, which has been considered as a detrimental phase, in carbon free Fe-Cr-Ni austenitic heat resistant steels have been examined, in order to seek its new possibilities as a strengthening spices. The stability of the σ phase in Fe-Cr-Ni ternary system increases by the addition of Mo and Mn. Especially, the thermodynamically stable σ phase increase by 300K by Mo addition. Proposed steels designed by newly created database revealed a unique microstructure having 90 % of the grain boundaries of the total grain boundaries are covered by the σ phase after prolonged aging at 1073 K. This result shows a possibility to have a excellent creep rupture strength of the steels by grain-boundary precipitation strengthening. In addition, the σ phase shows solid solution softening by the elements in solution, indicating that alloying can change the nature of σ phase.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (8 results)

All 2015 2014 2013

All Journal Article (1 results) Presentation (7 results) (of which Invited: 1 results)

  • [Journal Article] Fe-Cr-Ni-Mo4元系における1073K 以上におけるγ/σ相間の相平衡2014

    • Author(s)
      広澤 拓, 高田 尚記, 竹山 雅夫
    • Journal Title

      耐熱金属材料123委員会研究報告

      Volume: vol. 55, No. 1 Pages: 1-12

    • Related Report
      2013 Research-status Report
  • [Presentation] Fe-Cr系合金におけるσ相(tP30)の構造解析 -副格子への元素分配挙動-2015

    • Author(s)
      丸山 蒼太,竹山 雅夫
    • Organizer
      日本鉄鋼協会第169回春季講演大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe-Cr-Ni-Mn4元系の高温におけるγ/α/σ相間の相平衡2014

    • Author(s)
      熊谷 祥希,高田 尚記,竹山 雅夫
    • Organizer
      日本鉄鋼協会第168回秋季講演大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe-Cr-Ni-Mo4元系における1073K 以上におけるγ/σ相間の相平衡2014

    • Author(s)
      広澤 拓, 高田 尚記, 竹山 雅夫
    • Organizer
      耐熱金属材料123委員会研究会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Fe-Cr-Niオーステナイト系耐熱鋼におけるσ相の相安定性に及ぼすMn添加の影響2014

    • Author(s)
      熊谷祥希, 高田 尚記, 竹山 雅夫
    • Organizer
      日本鉄鋼協会第167回春季講演大会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Fe-Cr-Ni鋼におけるσ相の相安定性に及ぼすMo 添加の影響2013

    • Author(s)
      広澤 拓,高田尚記,竹山雅夫
    • Organizer
      日本金属学会第153回秋期講演大会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Possibility of σ phase as a Strengthener for Austenitic Heat Resistant Steels2013

    • Author(s)
      T. Hirosawa, N. Takata, M. Takeyama
    • Organizer
      The 2nd International Education Forum on Environment and Energy Science
    • Place of Presentation
      Huntington Beach, CA, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] A Thought on Sigma Phase as Potential Strengthener in Austenitic Heat Resistant Steels2013

    • Author(s)
      Masao Takeyama
    • Organizer
      Intermetallics 2013
    • Place of Presentation
      Kloster Banz, Germany
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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