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Preparation of multi cationic ionic liquids and its performance for electric double layer electrolyte.

Research Project

Project/Area Number 25630311
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTsuruoka National College of Technology

Principal Investigator

Sato Takaya  鶴岡工業高等専門学校, その他部局等, 教授 (30399258)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordsイオン液体 / アンモニウム塩 / 電気二重層キャパシタ / 電解質 / 多価アンモニウム塩 / エネルギー材料
Outline of Final Research Achievements

Generally, an ionic liquid (IL) is defined as a salt having a melting point lower than 100 oC. They have a very low volatility, are flame retardant, and possess relatively high ionic conductivities. Since very few reports of ionic liquid having a plurality of positive charges in a molecule, we tried to prepare some kinds of salt having a multi ammonium group. We have clarified the physicochemical properties of all of the salt synthesized but, any salts did not form ionic liquid at room temperature. On the other hand, the multi cationic salts showed higher capacitance as an electrolyte for electric double layer capacitor than that of mono charge salt at the same molar concentration.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2016 2015 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (13 results) (of which Invited: 1 results) Remarks (3 results)

  • [Journal Article] Synthesis of Monodisperse Silica Particles Grafted with Concentrated Ionic Liquid-Type Polymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization for Use as a Solid State Polymer Electrolyte2016

    • Author(s)
      Takashi Morinaga, Saika Honma, Takeo Ishizuka, Toshio Kamijo, Takaya Sato,
    • Journal Title

      polymers

      Volume: 8 Issue: 4 Pages: 146-158

    • DOI

      10.3390/polym8040146

    • NAID

      120006305882

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] High voltage electric double layer capacitor using a novel solid-state polymer electrolyte2015

    • Author(s)
      T. Sato, S. Marukane, T. Morinaga, T. Kamijo, H. Arafune, and Y. Tsujii
    • Journal Title

      J. Power Sources,

      Volume: 295 Pages: 108-116

    • DOI

      10.1016/j.jpowsour.2015.06.116

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Investigation of mechanical properties and internal structure of novel ionic double-nework gels and comparison with conventional hydrogels2015

    • Author(s)
      K. Ahmed, Y. Watanabe, T. Higashihara, H. Arafune, T. Kamijo, T. Morinaga, T. Sato, M. Makino, M. Kawakami, and H. Furukawa
    • Journal Title

      Microsyst. Technol

      Volume: 22 Issue: 1 Pages: 17-24

    • DOI

      10.1007/s00542-015-2630-4

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 物質・材料研究機構におけるインターンシップの実施 ―ナノ材料科学環境拠点短期RA 制度の活用―2015

    • Author(s)
      森永 隆志,正村 亮,伊藤 滋啓,佐藤 貴哉
    • Journal Title

      高専教育

      Volume: 38 Pages: 466-471

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 36.Controlled Polymerization of Protic Ionic Liquid Monomer by ARGET-ATRP and TERP2014

    • Author(s)
      Yasuyuki Nakamura, Kouji Nakanishi, Shigeru Yamago*, Yoshinobu Tsujii, Kenichi Takahashi, Takashi Morinaga, Takaya Sato*
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 35 Pages: 642-648

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] リチウムイオン二次電池のガス発生を抑制する電極ポリマーコーティング2015

    • Author(s)
      榊原 圭太, 辻井 敬亘, 正村 亮, 森永 隆志, 佐藤 貴哉, 瓶子 克, 豊川 卓也, 堂前 京介, 田渕 光春, 前田 勝美, 田村 宜之, 村上 朝夫
    • Organizer
      第24回ポリマー材料フォーラム
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] イオン液体型ポリマーブラシ付与微粒子を用いた固体電解質の特徴と機能2015

    • Author(s)
      佐藤 貴哉, 丸金 祥子, 本間 彩香, 森永 隆志, 辻井 敬亘
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] リビングラジカル重合法を用いたイオン液体系 電解質の開発2015

    • Author(s)
      正村 亮,森永 隆志, Zhang Chaofu,佐藤 貴哉,榊原 圭太, 大野 工司, 辻井 敬亘
    • Organizer
      平成 27 年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-06-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Simple Thin Carbon Layer can Improve Rate Capability of Energy Storage Devices2014

    • Author(s)
      Takaya SATO
    • Organizer
      IGNITE2014, International Conference of global Network for innovative technology,
    • Place of Presentation
      TUT-USM Technology Collaboration Centre, Penang, Malaysia
    • Year and Date
      2014-12-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Preparation and Low Friction Properties of Novel Double Network Ionic Gel (DN-IG)2014

    • Author(s)
      Miki MIURA, Hiroyuki ARAFUNE, Toshio KAMIJO and Takaya SATO
    • Organizer
      The 4th international Symposium on Technology for Sustainability (ISTS2014)
    • Place of Presentation
      National Taipei University of Technology,Taipei, Taiwan
    • Year and Date
      2014-11-20
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体を用いた低摩擦材料の開発2014

    • Author(s)
      佐藤貴哉,上條利夫,森永隆志,荒船博之
    • Organizer
      トライボロジー会議2014秋
    • Place of Presentation
      アイーナいわて県民情報交流センター
    • Year and Date
      2014-11-05
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体型ポリマーブラシを用いたイオン液体系固体電解質の構造設計2014

    • Author(s)
      森永 隆志,正村 亮,本間 彩夏,丸金 祥子,佐藤 貴哉,森 利之,大野 工司,辻井敬亘
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Novel low friction systems using ionic liquids2014

    • Author(s)
      Takaya Sato
    • Organizer
      Swiss-Japanese Tribology Meeting:Energy Savings through Tribology
    • Place of Presentation
      ETH Zurich, Switzerland
    • Year and Date
      2014-09-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] イオン液体/ダブルネットワークゲルの合成とその低摩擦特性2014

    • Author(s)
      三浦美紀,森永隆志,上條利夫,荒船博之,本間彩夏,佐藤貴哉,古川英光,宮瑾,和田真人
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-06-12
    • Related Report
      2014 Research-status Report
  • [Presentation] ARGET-ATRP法によるプロトン性イオン液体型ポリマーの制御重合と燃料電池用電解質への応用2014

    • Author(s)
      丹野駿,本間彩夏,佐藤貴哉,大野工司,辻井敬亘, 森永隆志,森利之
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-06-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 多角度光散乱測定法を用いたイオン液体ポリマーの構造解析2014

    • Author(s)
      長谷川正太、森永隆志、佐藤貴哉
    • Organizer
      第19回高専シンポジウムin久留米
    • Place of Presentation
      久留米工業高等専門学校
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン液体:その特徴と実用化2013

    • Author(s)
      佐藤貴哉
    • Organizer
      文部科学省GRENE事業先進環境材料分野グリーントライボイノベーションネットワーク 夏の学校2013
    • Place of Presentation
      京都大学 化学研究所 共同研究棟 大セミナー室
    • Related Report
      2013 Research-status Report
  • [Presentation] Controlled Synthesis of Protic Ionic Liquid-type,Polymer by ARGET-ATRP2013

    • Author(s)
      Shun Tanno, Saika Honma, Takashi Morinaga and Takaya Sato
    • Organizer
      The 3rd international Symposium on Technology for Sustainability (ISTS2013)
    • Place of Presentation
      Tsing Yi, Hong Kong
    • Related Report
      2013 Research-status Report
  • [Remarks] 鶴岡工業高等専門学校 佐藤研究室

    • URL

      http://ts.tsuruoka-nct.ac.jp/

    • Related Report
      2014 Research-status Report
  • [Remarks] 鶴岡工業高等専門学校 佐藤研究室

    • URL

      http://ts.tsuruoka-nct.ac.jp/

    • Related Report
      2013 Research-status Report
  • [Remarks] 鶴岡工業高等専門学校

    • URL

      http://www.tsuruoka-nct.ac.jp/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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