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Environmental stability of Ag thin films with organic nanolayers

Research Project

Project/Area Number 25630314
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Material processing/Microstructural control engineering
Research InstitutionKitami Institute of Technology

Principal Investigator

KAWAMURA MIDORI  北見工業大学, 工学部, 教授 (70261401)

Co-Investigator(Kenkyū-buntansha) ABE Yoshio  北見工業大学, 工学部, 教授 (20261399)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords銀薄膜 / 有機単分子膜 / 環境試験 / 電気抵抗率 / 表面粗さ / 透過率 / フレキシブル基板 / 表面形態
Outline of Final Research Achievements

To improve environmental stability of Ag thin films, we introduced several kinds of organic molecules, such as 3-mercaptopropyltrimethoxysilane (MPTMS), 1-dodecanethiol (1-DT), as a surface layer or an interface layer with a glass substrate. The environmental test was carried out at 40 °C and 90 RH% for mainly 7 days. The surface roughness, sheet resistance, and optical transmittance of the Ag films with the organic monolayers showed less change than that of single-layer Ag films. As a result, the organic monolayers protect the Ag thin film. The effect as a surface layer was compared among molecules, and it was found that 1-dodecanethiol (1-DT) and 1-octadodecanethiol (1-ODT) were highly effective. To use a flexible substrate, we have reviewed a process to prepare the monolayer, and we have found ethanol solvent is preferable.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (12 results)

All 2015 2014 2013 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Preparation of an indium zinc oxide-silver-indium zinc oxide multilayer film and its application in organic light-emitting diodes2015

    • Author(s)
      Tomoya Chiba, Yoshihisa Kudo, Midori Kawamura, Yoshio Abe, Kyung Ho Kim
    • Journal Title

      Vacuum

      Volume: 121 Pages: 320-322

    • DOI

      10.1016/j.vacuum.2015.07.003

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppression of property changes in Ag thin films by introducing organic monolayers2015

    • Author(s)
      T. Sasaki, M. Kawamura, Y. Abe, K. H. Kim
    • Journal Title

      Vacuum

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Improved stability of Ag thin films due to several organic surface monolayers2015

    • Author(s)
      M. Kawamura, C. Kudo, T. Sasaki, Y. Abe, K.H. Kim, T. Kiba
    • Organizer
      AVS 62nd International Symposium & Exhibition
    • Place of Presentation
      San Jose, California, USA
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] IZO/Ag/IZO積層膜の高湿度条件における特性の変化2015

    • Author(s)
      川森 翔、川村みどり、阿部良夫、木場隆之、金 敬鎬
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異なる有機分子膜によるAg薄膜の特性変化の抑制2015

    • Author(s)
      佐々木達也、川村みどり、工藤千佳、阿部良夫、木場隆之、金 敬鎬
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機単分子膜を表界面に導入した銀薄膜の耐環境性向上2015

    • Author(s)
      川村みどり、工藤千佳、佐々木達也、阿部良夫、金 敬鎬、木場隆之
    • Organizer
      表面技術協会132回講演大会
    • Place of Presentation
      信州大工学部(長野市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 表界面ナノレイヤーを活用した高安定性銀薄膜2015

    • Author(s)
      川村みどり
    • Organizer
      イノベーション・ジャパン2015
    • Place of Presentation
      東京ビッグサイト(東京都)
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ナノ表界面層の導入による銀薄膜の耐久性向上2015

    • Author(s)
      川村みどり
    • Organizer
      2015年度 第1回 光学薄膜研究会
    • Place of Presentation
      機械振興会館(東京都)
    • Year and Date
      2015-04-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Suppression of property changes in Ag thin films by introducing organic monolayers2014

    • Author(s)
      T. Sasaki, M. Kawamura, Y. Abe, K. H. Kim
    • Organizer
      7th Vacuum and Surface Science Conference of Asia and Australia (VASSCAA-7)
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Ag薄膜の特性変化の有機分子膜導入による抑制2014

    • Author(s)
      佐々木達也,川村みどり,阿部良夫,金敬鎬
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Passivation effect of MPTMS monolayer for Ag thin films2013

    • Author(s)
      M. Kawamura, T. Hirose, Y. Abe, K. H. Kim
    • Organizer
      The 60th AVS International Symposium
    • Place of Presentation
      ロングビーチコンベンションセンター(アメリカ、カリフォルニア州)
    • Related Report
      2013 Research-status Report
  • [Remarks] 北見工業大学マテリアル工学科電子材料研究室川村研究紹介

    • URL

      http://www.mtrl.kitami-it.ac.jp/~kawamura/privacy3.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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