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Quantitative Analysis for Crystallinity of Super-cooled Oxide Melt Characterized by Electrical Capacitance Measurement

Research Project

Project/Area Number 25630339
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionKyushu University

Principal Investigator

SAITO Noritaka  九州大学, 工学(系)研究科(研究院), 准教授 (80432855)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords電気容量 / 酸化物融体 / 結晶化 / 結晶化率 / 粘性 / 粘度 / 過冷却 / 結晶化挙動
Outline of Final Research Achievements

A novel- and in situ- quantifying method for the crystallinity of super-cooled silicate melts was proposed by the measurement of their electrical capacitance. It is well known that the electrical capacitance of ionic liquids is generally much higher than that of solids. These differences were exploited as a sensitive indicator of the crystallization of silicate melts in an experimental furnace equipped with an electrical capacitance measuring system. For the calibration of electrode composition employed, a theoretical capacitance model based on the dimensions of electrodes was proposed. For the estimation of crystallinity in super-cooled silicate melts, Nielsen’s equation was employed, which can allow us to calculate the dielectric constant of silicate-based suspension. Consequently, the calculated capacitance values successfully reproduced the experimental values at h.t., which suggests capacitance can provide crystallinity of silicate melt at elevated temperature.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (16 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Invited: 1 results)

  • [Journal Article] Effects of Agitation and Morphology of Primary Crystalline Phase on Crystallization Behavior of CaO–SiO<sub>2</sub>–CaF<sub>2</sub> Supercooled Melts2014

    • Author(s)
      Yusuke HARADA, Kakeru KUSADA, Sohei SUKENAGA, Hideaki YAMAMURA, Yoshiyuki UESHIMA, Toshiaki MIZOGUCHI, Noritaka SAITO, and Kunihiko NAKASHIMA
    • Journal Title

      ISIJ International

      Volume: 54 Issue: 9 Pages: 2071-2076

    • DOI

      10.2355/isijinternational.54.2071

    • NAID

      130004694561

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 電気容量測定による過冷却酸化融体の結晶化挙動の評価および定量化2014

    • Author(s)
      齊藤敬高
    • Journal Title

      金属,特集「次世代を担う若手熱物性研究者の最近の研究」

      Volume: 84 Pages: 124-129

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 電気容量測定による過冷却酸化物融体の結晶化率定量化2015

    • Author(s)
      齊藤敬高,中島邦彦
    • Organizer
      日本学術振興会 製鋼第19委員会 反応プロセス研究会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-01-20 – 2015-01-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] CaO-SiO2-CaF2-Al2O3 系過冷却フラックスの粘性および結晶化挙動同時評価2014

    • Author(s)
      坂口祥也,齊藤敬高,中島邦彦,花尾方史
    • Organizer
      第35回日本熱物性シンポジウム
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-11-22 – 2014-11-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effects of Agitation on Crystallization Behavior of CaO–SiO2–CaF2 Supercooled Melts2014

    • Author(s)
      Noritaka SAITO, Kunihiko NAKASHIMA, Hideaki YAMAMURA, Yoshiyuki UESHIMA, and Toshiaki MIZOGUCHI
    • Organizer
      The 5th Australia-China-Japan Joint Symposium on Iron and Steelmaking
    • Place of Presentation
      Tohoku University
    • Year and Date
      2014-10-20 – 2014-10-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二相共存流体のレオロジー特性評価と推算式の提案2014

    • Author(s)
      齊藤敬高,山下健太,助永壮平,中島邦彦
    • Organizer
      日本鉄鋼協会 第168回秋季講演大会予告セッション「生石灰高速滓化に向けての課題と展望」
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電気容量測定による過冷却酸化物融体の結晶化率定量化2014

    • Author(s)
      齊藤敬高
    • Organizer
      日本実験力学会マテリアル反応工学分科会平成25年度第1回研究講演会「マルチメタラジー研究会」
    • Place of Presentation
      九州大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of agitation on crystallization behavior of CaO-SiO2-R2O (R = Li, Na, or K) system characterized by electrical capacitance measurement2014

    • Author(s)
      齊藤敬高,草田翔,助永壮平,太田能生,中島邦彦
    • Organizer
      日本鉄鋼協会 第167回春季講演大会予告セッション「高温融体の物理化学的性質」
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 過冷却酸化物融体の粘性および結晶化挙動同時評価2014

    • Author(s)
      齊藤敬高,原田祐亮,坂口祥也,中島邦彦,山村英明,上島良之,溝口利明
    • Organizer
      日本鉄鋼協会 第167回春季講演大会予告セッション「高温融体の物理化学的性質」
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 電気容量測定による過冷却酸化物融体の結晶化率定量化2014

    • Author(s)
      原田祐亮,中島邦彦,齊藤敬高
    • Organizer
      日本鉄鋼協会 第167回春季講演大会予告セッション「高温融体の物理化学的性質」
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Agitation on Crystallization Behavior of Molten Calcium Silicates Characterized by Electrical Capacitance Measurement2013

    • Author(s)
      Noritaka SAITO, Sohei SUKENAGA, and Kunihiko NAKASHIMA
    • Organizer
      ISIJ-VDEh-Jernkontoret Joint Symposium (The 14th ISIJ-VDEh Seminar, The 8th Japan-Nordic Countries Joint Symposium on Science and technology of Process Metallurgy)
    • Place of Presentation
      Osaka University
    • Related Report
      2013 Research-status Report
  • [Presentation] CaO-SiO2-CaF2系過冷却融体の結晶化挙動に及ぼす撹拌の影響2013

    • Author(s)
      原田祐亮,助永壮平, 齊藤敬高,中島邦彦
    • Organizer
      資源・素材学会九州支部 平成25年度春季例会
    • Place of Presentation
      熊本大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 電気容量測定による結晶化率の定量化2013

    • Author(s)
      齊藤敬高
    • Organizer
      日本鉄鋼協会高温プロセス部会高温物性値フォーラム 日本熱物性学会研究分科会 平成25年度第1回研究会
    • Place of Presentation
      熱海ニューフジヤホテル
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of agitation on crystallization behavior of super-cooled melts characterized by electrical capacitance measurement2013

    • Author(s)
      Noritaka SAITO, Sohei SUKENAGA, Yoshio OHTA, and Kunihiko NAKASHIMA
    • Organizer
      166th ISIJ Meeting, International Organized Session High Temperature Processes, Innovations in measurement of high temperature property and application to materials production process
    • Place of Presentation
      Kanazawa University
    • Related Report
      2013 Research-status Report
  • [Presentation] Crystallization and Rheological Behavior of Calcium Silicate Melts under Shear Stress2013

    • Author(s)
      Noritaka SAITO, Sohei SUKENAGA, and Kunihiko NAKASHIMA
    • Organizer
      10th Asian Thermophysical Properties Conference (ATPC2013)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] 溶融スラグの静電容量測定による結晶化挙動の評価2013

    • Author(s)
      齊藤敬高
    • Organizer
      平成25年度 第6回材料プロセス談話会 特別講演会
    • Place of Presentation
      新日鐵住金株式会社大分製鉄所
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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