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Simultaneous photo- and thermal-decomposition of adsorbates by using thermal balance enable to irradiate light

Research Project

Project/Area Number 25630359
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionSojo University

Principal Investigator

KUSAKABE Katsuki  崇城大学, 工学部, 教授 (30153274)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords光分解 / 吸着 / 触媒 / チタニア / 可視光 / 熱天秤 / 金ナノ粒子 / ニトロベンゼン / 還元反応 / 光触媒 / 熱分解 / 熱重量分析 / 紫外線
Outline of Final Research Achievements

The thermal balance enable to irradiate light was built for the analysis of the simultaneous photo- and thermal-decomposition of adsorbates. As a result of the simultaneous decomposition of methylene blue on anatase titania, the ultraviolet irradiation was found to increase the reaction rate effectively. Au-TiO2 composite catalysts were then prepared from HAuCl4 and titanium-iso-propoxide by sol-gel method with and without the addition of reduction agent (ascorbic acid). The absorption of visible light by the addition of Au nanoparticles was confirmed from the result of the diffuse reflectance spectrophotometry. The Au-TiO2 composite was found to be useful as a photocatalyst for the methylene blue degradation and the photochemical reduction of nitrobenzene under visible light irradiation.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (2 results)

All 2014

All Presentation (2 results)

  • [Presentation] Simultaneous Synthesis of Au-Titania Composite for Photocatalytic Reaction2014

    • Author(s)
      Taishi Arai, Masato Ezaki, Mina Sakuragi, Katsuki Kusakabe
    • Organizer
      27th International Symposium on Chemical Engineering
    • Place of Presentation
      Putra World Trade Center (Kuala Lumpur, Malaysia)
    • Year and Date
      2014-12-05 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液-液界面における金ナノ粒子の生成速度2014

    • Author(s)
      荒井泰史、江崎優人、櫻木美菜、草壁克己
    • Organizer
      化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Year and Date
      2014-06-28
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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