Project/Area Number |
25630411
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Earth system and resources engineering
|
Research Institution | Tohoku University |
Principal Investigator |
KANO JUNYA 東北大学, 多元物質科学研究所, 教授 (40271978)
|
Project Period (FY) |
2013-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
|
Keywords | 水素 / 炭材 / 粉砕 / 水酸化ニッケル / 水酸化カルシウム / 水酸化ナトリウム / メカノケミカル / 再生可能エネルギー |
Outline of Final Research Achievements |
In the production method of hydrogen gas from biomass-derived carbonaceous material as a raw material, 20 atm or more of the high-pressure, 1000 ℃ or more of the high temperature and an expensive catalyst must be needed. Then, the development of a new production method under normal pressure, low temperature, and using inexpensive catalyst is desired. In this work, the mechanochemical method, which can achieve thorough mixing and size reduction of powder materials simultaneously, was applied to the pretreatment for production of hydrogen. The calcium hydroxide and nickel hydroxide mixed with carbonaceous material by the mechanochemical method, and the mixture was heated in a water vapor atmosphere. As a result, producing hydrogen at atmospheric pressure using inexpensive hydroxide as a gasifying agent and a catalyst has succeeded. In addition, the reaction temperature of producing hydrogen is reduced to 600 ℃ from 1000 ℃ or more.
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