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Development of all-solid-state multivalent-ion batteries using quasi-solid-state electrolytes containing room-temperature ionic liquid

Research Project

Project/Area Number 25630437
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionTohoku University

Principal Investigator

Unemoto Atsushi  東北大学, 原子分子材料科学高等研究機構, 講師 (10551525)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsイオン液体 / 疑似固体電解質 / 無機固体電解質 / 錯体水素化物 / 多価イオン電池 / 硫黄正極 / 金属負極 / 高エネルギー密度 / 蓄電池 / 錯体水素化物固体電解質
Outline of Final Research Achievements

In this study, we aimed to develop solid-state electrolytes that ensure safety and are easy to handle compared to the conventional liquid electrolytes for application into all-solid-state multivalent-ion batteries. The solid-state electrolytes developed are (1) quasi-solid-state electrolyte comprised of room-temperature ionic liquid and fumed silica nanoparticles, and (2) complex hydrides. In addition to these, we also have developed a technique for preparation of elemental sulfur and carbon conductive additives. As model systems, we assembled all-solid-state lithium-sulfur batteries, and their performances were evaluated. They had high energy density and allows for repeated operations of charge and discharge. We will further explore the materials that has high magnesium-ion conductivities, and incorporate them into solid-state devices in future studies.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (17 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Invited: 5 results)

  • [Journal Article] Complex hydrides for electrochemical energy storage2014

    • Author(s)
      A. Unemoto, M. Matsuo, S. Orimo
    • Journal Title

      Advanced Functional Materials (Feature Article)

      Volume: 111 Issue: 16 Pages: 1-13

    • DOI

      10.1002/adfm.201303147

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of bulk-type all-solid-state lithium-sulfur battery using LiBH4 electrolyte2014

    • Author(s)
      A. Unemoto, S. Yasaku, G. Nogami, M. Tazawa, M. Taniguchi, M. Matsuo, T. Ikeshoji, S. Orimo
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 8 Pages: 083901-083901

    • DOI

      10.1063/1.4893666

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Development of high capacity all-solid-state lithium battery using quasi-solid-state electrolyte containing tetraglyme-Li-TFSA equimolar complexes2014

    • Author(s)
      Atsushi Unemoto, Yoshiyuki Gambe, Daiki Komatsu, Itaru Honma
    • Journal Title

      Solid State Ionics

      Volume: -

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of lithium-sulfur batteries using room temperature ionic liquid-based quasi-solid-state electrolytes2014

    • Author(s)
      Atsushi Unemoto, Hideyuki Ogawa, Yoshiyuki Gambe, Itaru Honma
    • Journal Title

      Electrochimica Acta

      Volume: 125 Pages: 386-394

    • DOI

      10.1016/j.electacta.2014.01.105

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Complex hydrides as solid-state electrolytes for rechargeable batteries2015

    • Author(s)
      Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      化学工学会第80年会(国際シンポジウム)
    • Place of Presentation
      東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 錯体水素化物固体電解質を利用した次世代型全固体蓄電池の開発2014

    • Author(s)
      宇根本篤,松尾元彰,折茂慎一
    • Organizer
      金属材料研究所第128回講演会
    • Place of Presentation
      仙台
    • Year and Date
      2014-11-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Complex hydrides for all-solid-state energy devices2014

    • Author(s)
      Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      Second International Conference of Young Researchers on Advanced Materials (IUMRS-ICYRAM 2014)
    • Place of Presentation
      Haikou, China
    • Year and Date
      2014-10-24 – 2014-10-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 錯体水素化物固体電解質を利用した次世代全固体リチウム電池の開発2014

    • Author(s)
      宇根本篤,松尾元彰,池庄司民夫,折茂慎一
    • Organizer
      日本金属学会水素化物に関わる次世代学術・応用展開研究会第1回研究会
    • Place of Presentation
      仙台
    • Year and Date
      2014-10-22
    • Related Report
      2014 Research-status Report
  • [Presentation] Complex hydrides for all-solid-state rechargeable battery electrolytes2014

    • Author(s)
      Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      Eleventh International Conference on Flow Dynamics
    • Place of Presentation
      Sendai
    • Year and Date
      2014-10-08 – 2014-10-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 錯体水素化物固体電解質を用いた高エネルギー密度型バルク全固体Li-S電池の開発2014

    • Author(s)
      宇根本篤,矢作駿,野上玄器,田沢勝,谷口貢,松尾元彰,池庄司民夫,折茂慎一
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 錯体水素化物固体電解質を用いた高エネルギー密度型バルク全固体リチウムー硫黄電池の開発2014

    • Author(s)
      宇根本篤,矢作駿,野上玄器,田沢勝,谷口貢,松尾元彰,池庄司民夫,折茂慎一
    • Organizer
      日本金属学会2014年秋期講演大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Complex hydrides for electrochemical energy storage2014

    • Author(s)
      Atsushi Unemoto
    • Organizer
      AIMR Tohoku University–NCTU Joint Workshop on Fusion of Mathematics, Nano-Materials, and Nano-Devices
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2014-09-22 – 2014-09-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Advanced research on complex hydrides for electrochemical energy storage2014

    • Author(s)
      Atsushi Unemoto, Syun Yasaku, Motoaki Matsuo, Genki Nogami, Masaru Tazawa, Mitsugu Taniguchi, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      1st International Symposium on Energy Challenges & Mechanics
    • Place of Presentation
      Aberdeen, UK
    • Year and Date
      2014-07-08 – 2014-07-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Complex hydride electrolytes for all-solid-state rechargeable battery2014

    • Author(s)
      Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      Took University & GREEN Joint Symposium (The 8th GREEN Symposium)
    • Place of Presentation
      Tsukuba
    • Year and Date
      2014-06-02 – 2014-06-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of room temperature ionic liquid based quasi-solid-state electrolyte and its application to all-solid-state lithium rechargeable battery2013

    • Author(s)
      Atsushi Unemoto, Daiki Komatsu, Takahiro Matsuo, Hideyuki Ogawa, Yoshiyuki Gambe, Itaru Honma
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Development of all-solid-state lithium-sulfur battery using room temperature ionic liquid based quasi-solid-state electrolytes2013

    • Author(s)
      Hideyuki Ogawa, Yoshiyuki Gambe, Atsushi Unemoto, Itaru Honma
    • Organizer
      19th International Conference on Solid State Ionics
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Quasi-solid-state glyme-Li-salt equimolar complex electrolyte for battery application2013

    • Author(s)
      Takahiro Matsuo, Atsushi Unemoto, Hideyuki Ogawa, Yoshiyuki Gambe, Itaru Honma
    • Organizer
      19th International Conference on Solid State Ionics
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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