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Development of a pH sensor based on a nanostructured filter adding pH-sensitive fluorescent dye for detecting acetic acid in photovoltaic modules

Research Project

Project/Area Number 25630438
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

UMEDA Norihiro  東京農工大学, 工学(系)研究科(研究院), 教授 (60111803)

Co-Investigator(Kenkyū-buntansha) IWAMI Kentarou  東京農工大学, 大学院工学研究院, 准教授 (80514710)
Co-Investigator(Renkei-kenkyūsha) MASUDA Atsushi  国立研究開発法人産業技術総合研究所, 太陽光発電研究センター, 副研究センター長 (30283154)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords太陽電池モジュール / 寿命 / 加速試験 / ダンプヒート試験 / エチレンビニールアセテート / 酢酸 / pH感受性蛍光色素 / pH計測 / EVA / pH感受性蛍光色素 / メンブレンフィルター / pH感受性色素 / pH計測
Outline of Final Research Achievements

Acetic acid formed via hydrolysis of ethylene vinyl acetate (EVA) as an encapsulant in photovoltaic (PV) modules causes a decrease in conversion efficiency of modules by grid corrosion. To evaluate the condition of PV modules, a nondestructive and simple optical method is proposed. This method uses a dual wavelength pH-sensitive fluorescent dye to detect acetic acid in PV modules using the change in pH. The change in pH induced by the formation of acetic acid is detected by the change in the ratio of fluorescent intensities of two peaks of a dye. A pH-sensitive fluorescent dye showed sensitivity for small amounts of acetic acid such as that produced from EVA. Furthermore, a membrane filter dyed with pH-sensitive fluorescent dye was confirmed to detect acetic acid included in aged EVA after a damp heat test (85℃, 85%) for 5000 h in PV modules.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (6 results)

All 2015 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Detection of acid moisture in photovoltaic modules using a dual wavelength pH-sensitive fluorescent dye2014

    • Author(s)
      Takashi Asaka, Kentaro Iwami, Atsushi Taguchi, Norihiro Umeda, and Atsushi Masuda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53

    • NAID

      210000143727

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ナノ構造pHセンサーによる太陽電池モジュール内の微量酢酸検出2015

    • Author(s)
      浅香 孝, 板山 知広, 長崎 秀昭, 岩見 健太郎, 山本 千津子, 原 由希子, 増田 淳, 梅田 倫弘
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of a nanostructured pH sensor for detecting acetic acid in photovoltaic modules2014

    • Author(s)
      T. Asaka, T. Itayama, H. Nagasaki, K. Iwami, C. Yamamoto, Y. Hara, A. Masuda and N. Umeda
    • Organizer
      The 6th WCPEC
    • Place of Presentation
      京都国際会議場
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 太陽電池モジュール内の酸性微量水分検出用ナノ構造pHセンサーの開発2014

    • Author(s)
      浅香 孝, 板山 知広, 長崎 秀昭, 岩見 健太郎, 山本 千津子, 原 由希子, 増田 淳, 梅田 倫弘
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of an acid moisture detection method in photovoltaic modules2013

    • Author(s)
      T. Asaka, K. Iwami, A. Taguchi, N. Umeda, A. Masuda
    • Organizer
      SSDM2013
    • Place of Presentation
      ヒルトン福岡シーホーク
    • Related Report
      2013 Research-status Report
  • [Remarks] 東京農工大学工学府機械システム工学専攻梅田研究室

    • URL

      http://www.tuat.ac.jp/~umedalab

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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