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Emission of Hydrogen Gas from Metal-Oxide Layered Hydrogen Storage Materials by Microwave Heating

Research Project

Project/Area Number 25630445
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionNagoya Industrial Science Research Institute

Principal Investigator

MORITA Kenji  公益財団法人名古屋産業科学研究所, その他部局等, 研究員 (10023144)

Co-Investigator(Kenkyū-buntansha) TSUCHIYA Bun  名城大学, 理工学部, 准教授 (90302215)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords水素貯蔵材料 / 水素ガス製造技術 / マイクロ波加熱 / 金属・セラミックス複合材料 / イオンビーム分析 / 水素貯蔵複合材料 / 水素製造 / 金属・セラミックス複合材
Outline of Final Research Achievements

Emission of hydrogen gas from water-splitting and hydrogen-absorbing metal-oxide ceramics layered hydrogen storage materials by microwave heating in vacuum has been measured by means of gas-chromatography. In experiments, a Pt/Li2ZrO3/Pt sandwich specimen of 1g in weight was rapidly heated for 3 min in a glass vessel of 1.3 liter in volume evacuated using a microwave heating cooker, 3 times. On 1st heating, just after start of the heating, emission of pink light of discharge of hydrogen gas emitted was observed. On 2nd heating, the light emission was observed. On 3rd heating, the color of light emitted was changed from pink, via re-brown, to orange.
Total amounts of hydrogen gas emitted has been estimated to be 0.66 m%, namely 8.6 cm3. This result indicates the that volume ratio of hydrogen gas emitted to specimen to be about 30 and also that a high pressure of hydrogen gas is able to be produced by selection of volume ratio of specimen to hydrogen containing vacuum vessel.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (10 results)

All 2015 2014 2013

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (4 results)

  • [Journal Article] Dynamic Measurement of Li Depth Profiles in a Li Ion Battery System under Charging Condition2014

    • Author(s)
      B. Tsuchiya, K. Morita,S. Nagata, T. Kato, Y. Iriyama, H. Tsuchida and T. Majima
    • Journal Title

      Surface and Interface Analysis

      Volume: 46, issue 12-13 Issue: 12-13 Pages: 1187-1191

    • DOI

      10.1002/sia.5620

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] A Mechanism for Water Splitting and Hydrogen Absorbing Functions of Metal-Oxide Layered Hydrogen Storage Materials Studied by Means of Ion Beam Analysis Techniques (Review Paper)2014

    • Author(s)
      K. Morita and B. Tsuchiya
    • Journal Title

      Surface and Interface Analysis

      Volume: 46, issue 3 Issue: 3 Pages: 113-127

    • DOI

      10.1002/sia.5359

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Mechanism for Water Splitting and Hydrogen Absorbing Functions of Metal-Oxide Layered Hydrogen Strtage Materials Studied by Means of Ion Beam Analysis (Review Paper)2014

    • Author(s)
      K. Morita and B. Tsuchiya
    • Journal Title

      Surface and Inerface Analysis, online in Wily Online Library

      Volume: 46, issue 3 Pages: 113-127

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dynamic Measurement of Li Depth Profiles in a Li Ion Battery System under Charging Condition2014

    • Author(s)
      B. Tsuchiya, K. Morita, S. Nagata, T. Katoh, Y. Iriyama, H. Tsuchida and T. Majima
    • Journal Title

      Surface and Interface Analysis

      Volume: Special Issue

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] ERD Measurement of Depth Profiles of H and Li in Pt-coated LiCoO2 Thin Films2013

    • Author(s)
      B. Tsuchiya, K. Morita, Y. Iriyama, T. Majima and H. Tsuchida
    • Journal Title

      Nucl. Instru. Meth.

      Volume: B315 Pages: 341-344

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] ERDおよびRBS法を用いた全固体Liイオン電池システム中のLiイオンの移動特性のその場測定2013

    • Author(s)
      森田健治、土屋文、永田晋二、入山恭寿、土田秀次、間嶋拓也
    • Journal Title

      マイクロアナリシス第141委員会

      Volume: 第152回研究会資料 Pages: 35-42

    • Related Report
      2013 Research-status Report
  • [Presentation] ERD-RBS分析によるLiイオン電池の電解質・電極界面の電位勾配と空間電荷電位の決定2015

    • Author(s)
      森田健治、土屋文他
    • Organizer
      日本原子力学会・春の年会
    • Place of Presentation
      茨城大学日立キャンパス
    • Year and Date
      2015-03-20 – 2015-03-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] In-situ ERD Measurements of Dynamic Change in Depth Profile in Li in Electrolyte and Electrode and at Their Interface of All Solid State Battery System (Oral)2014

    • Author(s)
      K. Morita, B. Tsuchiya, S. Nagata, Y. Iriyama, H. Tsuchida and T. Majima
    • Organizer
      20th Int. Worhshop on Ion Surface Collisions (IISC-20)
    • Place of Presentation
      Wirrina Cove Resort, South Australia, Tuesday O5
    • Related Report
      2013 Research-status Report
  • [Presentation] MeVOイオンビームERD法による全固体Liイオン電池システ中のLiイオン濃度分布の動的解析2013

    • Author(s)
      森田健治、土屋文、永田晋二、入山恭寿、土田秀次、間嶋拓也
    • Organizer
      日本原子力学会「2013年秋の大会]八戸工業大学
    • Place of Presentation
      核融合炉材料工学、B28
    • Related Report
      2013 Research-status Report
  • [Presentation] Dynamic Measurements of Li Depth Profiles in a Li Ion Battery System under Charging (Oral)2013

    • Author(s)
      K. Morita, B. Tsuchiya, S. Nagata, Y. Iriyama, H. Tsuchida and T. Majima
    • Organizer
      9th Int. Symp. on Atomic Level Characterizations for New Materials and Devices (ALC-13)
    • Place of Presentation
      Sheraton Kona Resort, Hawaii, USA 05BM05
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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