Project/Area Number |
25660278
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Environmental agriculture(including landscape science)
|
Research Institution | Kyoto University |
Principal Investigator |
|
Co-Investigator(Renkei-kenkyūsha) |
SHIRAISHI Masashi 京都大学, 大学院工学研究科, 教授 (30397682)
|
Project Period (FY) |
2013-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
|
Keywords | セルロース誘導体 / 単層カーボンナノチューブ / ピレン / 電界効果トランジスタ / セルロース / セルロースアセテート / 低炭素社会 / カーボンナノチューブ |
Outline of Final Research Achievements |
We synthesized six cellulose triacetate (CTA) derivatives having pyrene-functionalized dendrons (generations of dendrons: 1, 2, and 3; number of pyrene groups: 2, 4, and 8, respectively ) at the reducing-end: CTA-C15-N3-b-Dendron-G1Py2, CTA-N3-b-Dendron-G2Py4, CTA-C15-N3-b-Dendron-G2Py4, CTA-N3-b-Dendron-G3Py8, and CTA-C15-N3-b-Dendron-G3Py8. Those cellulose derivatives well dispersed single-walled carbon nanotubes (SWCNTs: a mixture of metallic and semiconducting SWCNTs) to afford SWCNT dispersed solutions in tetrahydrofuran (THF). Single-walled carbon nanotube field effect transistor (SWCNT-FET) was prepared with SWCNTs/CTA-C15-b-Dendron-G3Py8 complex. The field effect mobility of SWCNTs/CTA-C15-b-Dendron-G3Py8-FET was calculated to be 4.96×10-1 (cm2/V sec) as a preliminary result.
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