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Development of cellulose derivatives for dispersing single-walled carbon nanotubes and their application for transparent thin-film transistors

Research Project

Project/Area Number 25660278
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental agriculture(including landscape science)
Research InstitutionKyoto University

Principal Investigator

Kamitakahara Hiroshi  京都大学, (連合)農学研究科(研究院), 准教授 (10293911)

Co-Investigator(Renkei-kenkyūsha) SHIRAISHI Masashi  京都大学, 大学院工学研究科, 教授 (30397682)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsセルロース誘導体 / 単層カーボンナノチューブ / ピレン / 電界効果トランジスタ / セルロース / セルロースアセテート / 低炭素社会 / カーボンナノチューブ
Outline of Final Research Achievements

We synthesized six cellulose triacetate (CTA) derivatives having pyrene-functionalized dendrons (generations of dendrons: 1, 2, and 3; number of pyrene groups: 2, 4, and 8, respectively ) at the reducing-end: CTA-C15-N3-b-Dendron-G1Py2, CTA-N3-b-Dendron-G2Py4, CTA-C15-N3-b-Dendron-G2Py4, CTA-N3-b-Dendron-G3Py8, and CTA-C15-N3-b-Dendron-G3Py8. Those cellulose derivatives well dispersed single-walled carbon nanotubes (SWCNTs: a mixture of metallic and semiconducting SWCNTs) to afford SWCNT dispersed solutions in tetrahydrofuran (THF). Single-walled carbon nanotube field effect transistor (SWCNT-FET) was prepared with SWCNTs/CTA-C15-b-Dendron-G3Py8 complex. The field effect mobility of SWCNTs/CTA-C15-b-Dendron-G3Py8-FET was calculated to be 4.96×10-1 (cm2/V sec) as a preliminary result.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (3 results)

All 2015 Other

All Presentation (1 results) (of which Invited: 1 results) Remarks (2 results)

  • [Presentation] Synthetic strategies for cellulosic diblock copolymers2015

    • Author(s)
      Hiroshi Kamitakahara
    • Organizer
      249th ACS national meeting
    • Place of Presentation
      Denver, CO, USA
    • Year and Date
      2015-03-22 – 2015-03-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 京都大学大学院農学研究科森林科学専攻生物材料化学分野

    • URL

      http://www.chembio.kais.kyoto-u.ac.jp/Chembio/Index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 京都大学大学院農学研究科森林科学専攻生物材料化学分野

    • URL

      http://www.chembio.kais.kyoto-u.ac.jp/Chembio/Index.html

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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