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Electrosynthesis of Framework Structures with Polyvalent-cation Conductivities

Research Project

Project/Area Number 25706008
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Nanomaterials engineering
Research InstitutionOsaka Prefecture University

Principal Investigator

YAGI Shunsuke  大阪府立大学, 21世紀科学研究機構, 講師 (60452273)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥25,220,000 (Direct Cost: ¥19,400,000、Indirect Cost: ¥5,820,000)
Fiscal Year 2014: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2013: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Keywords電解合成 / フレームワーク / 多価カチオン電池 / 水晶振動子マイクロバランス / 酸化還元反応 / フレームワーク構造 / EQCM / 電気化学水晶振動子マイクロバランス
Outline of Final Research Achievements

In the present work, framework materials having micropores were synthesized and investigated as conducting materials of polyvalent cations at room temperature for polyvalent-cation batteries. Specifically, it was clarified that divalent magnesium ions can be inserted/extracted using Prussian blue and its analogs. The possibility of the insertion and extraction of counter anions was presented in addition to the co-insertion of solvated molecules. The solvated molecules alleviated the electrostatic interaction and promoted the diffusion of magnesium ions. The above results are important for the battery applications of framework materials.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • Research Products

    (5 results)

All 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (3 results) (of which Invited: 1 results)

  • [Journal Article] EQCM Analysis of Redox Behavior of Prussian Blue in a Lithium Battery Electrolyte2014

    • Author(s)
      S. Yagi, M. Fukuda, R. Makiura, T. Ichitsubo, and E. Matsubara
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 21 Pages: 8041-8047

    • DOI

      10.1039/c4ta00410h

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermodynamic Consideration on Degradation of Humic Acids by Electrolysis2014

    • Author(s)
      S. Yagi, K. Nakatsuji, Y. Satake, A. Nakahira, and M. Anpo
    • Journal Title

      Electrochemistry

      Volume: 82 Issue: 1 Pages: 19-24

    • DOI

      10.5796/electrochemistry.82.19

    • NAID

      130003387728

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Redox Behavior of Prussian Blue in Mg Salt Electrolytes2014

    • Author(s)
      S. Yagi, M. Fukuda, T. Ichitsubo, and E. Matsubara
    • Organizer
      The 226th ECS Meeting
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] EQCM 法によるプルシアンブルーの酸化還元挙動の定量的解析2014

    • Author(s)
      福田 格章, 八木 俊介, 牧浦 理恵, 市坪 哲, 松原 英一郎
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電気化学QCM法による酸化還元に伴うイオンの脱挿入過程の解析2014

    • Author(s)
      八木俊介
    • Organizer
      2014年度第1回関西電気化学研究会
    • Place of Presentation
      i-siteなんば(大阪)
    • Year and Date
      2014-07-12
    • Related Report
      2014 Annual Research Report
    • Invited

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Published: 2013-05-21   Modified: 2019-07-29  

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