Studies on superconducting properties and mechanisms of BiS2-based compounds and exploration of new functionality in related materials
Project/Area Number |
25707031
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Research Category |
Grant-in-Aid for Young Scientists (A)
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Allocation Type | Partial Multi-year Fund |
Research Field |
Condensed matter physics II
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Research Institution | Tokyo Metropolitan University |
Principal Investigator |
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Project Period (FY) |
2013-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
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Budget Amount *help |
¥28,730,000 (Direct Cost: ¥22,100,000、Indirect Cost: ¥6,630,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2013: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
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Keywords | BiCh2系層状化合物 / 元素置換 / 超伝導機構 / 化学圧力 / 新超伝導体探索 / トポロジカル超伝導候補物質 / 新熱電材料 / バンドエンジニアリング / 新超伝導体 / 新物質開発 / BiS2系超伝導体 / 熱電変換材料 / 元素置換効果 / 化学圧力効果 / 基礎物性 / 結晶構造解析 / 新超伝導体の機構解明 / BiS2系層状化合物 / 新熱電変換物質 / 局所構造 / 超伝導特性 / 熱電変換性能 / 新超伝導物質 / BiS2系超伝導体 / 低温物性測定 / 高圧合成 |
Outline of Final Research Achievements |
To clarify the superconducting properties and the mechanisms of superconductivity in the BiCh2-based (Ch: chalcogen) compounds, we have studied the physical properties and crystal structure of RE(O,F)BiCh2-type compounds. We revealed that the enhancement of in-plane chemical pressure should be essential for the induction of superconductivity and the increase of transition temperature (Tc) in the BiCh2-based superconductors. New superconductors with a RE(O,F)BiCh2-type structure, new materials with SbS2-type layers, and a Sn1-xAgxTe superconductor, which may be related to topological superconductivity, were discovered during this project. Furthermore, we have revealed that the Se-substituted LaOBiS2-xSex can be a promising thermoelectric material. The enhancement of in-plane chemical pressure by Se substitution resulted in large electron mobility without degradation of Seebeck coefficient; the highest dimensionless figure-of-merit (ZT) was 0.36 in LaOBiSSe.
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Report
(4 results)
Research Products
(80 results)
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[Journal Article] In-plane chemical pressure essential for superconductivity in BiCh2-based (Ch: S, Se) layered structure2015
Author(s)
Yoshikazu Mizuguchi, Akira Miura, Joe Kajitani, Takafumi Hiroi, Osuke Miura, Kiyoharu Tadanaga, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa
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Journal Title
Scientific Reports
Volume: 2015
Issue: 1
Pages: 14968-14968
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Structural Difference in Superconductive and Nonsuperconductive Bi-S Planes within Bi4O4Bi2S4 Blocks2015
Author(s)
Akira Miura, Yoshikazu Mizuguchi, Tsuyoshi Sugawara, Yongming Wang, Takahiro Takei, Nobuhiro Kumada, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa, Osuke Miura, Kiyoharu Tadanaga
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Journal Title
Inorganic Chemistry
Volume: 54
Issue: 21
Pages: 10462-10467
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] Coexistence of Bulk Superconductivity and Magnetism in CeO1-xFxBiS22015
Author(s)
Satoshi Demura, Keita Deguchi, Yoshikazu Mizuguchi, Kazuki Sato, Ryota Honjyo, Aichi Yamashita, Takuma Yamaki, Hiroshi Hara, Tohru Watanabe, Saleem J. Denholme, Masaya Fujioka, Hiroyuki Okazaki, Toshinori Ozaki, Osuke Miura, Takahide Yamaguchi, Hiroyuki Takeya, Yoshihiko Takano
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Journal Title
J. Phys. Soc. Jpn.
Volume: 84
Issue: 2
Pages: 024709-024709
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] Structure, Superconductivity, and Magnetism of Ce(O,F)BiS2 Single Crystals2015
Author(s)
Akira Miura, Masanori Nagao, Takahiro Takei, Satoshi Watauchi, Yoshikazu Mizuguchi, Yoshihiko Takano, Isao Tanaka, Nobuhiro Kumada
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Journal Title
Cryst. Growth Des.
Volume: 15
Issue: 1
Pages: 39-44
DOI
Related Report
Peer Reviewed
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[Journal Article] Coexistence of ferromagnetism and superconductivity in CeO0.3F0.7BiS22014
Author(s)
J. Lee, S. Demura, M. B. Stone, K. Iida, G. Ehlers, C. R. dela Cruz, M. Matsuda, K. Deguchi, Y. Takano, Y. Mizuguchi, O. Miura, D. Louca, S.-H. Lee
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Journal Title
Phys. Rev. B
Volume: 90
Issue: 22
DOI
Related Report
Peer Reviewed
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[Journal Article] Proximity to Fermi-surface topological change in superconducting LaO0.54F0.46BiS22014
Author(s)
Kensei Terashima, Junki Sonoyama, Takanori Wakita, Masanori Sunagawa, Kanta Ono, Hiroshi Kumigashira, Takayuki Muro, Masanori Nagao, Satoshi Watauchi, Isao Tanaka, Hiroyuki Okazaki, Yoshihiko Takano, Osuke Miura, Yoshikazu Mizuguchi, Hidetomo Usui, Katsuhiro Suzuki, Kazuhiko Kuroki, Yuji Muraoka, Takayoshi Yokoya
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Journal Title
Phys. Rev. B
Volume: 90
Issue: 22
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] Soft x-ray photoemission study of new BiS2-layered superconductor LaO1-xFxBiS22014
Author(s)
Shinsuke Nagira, Junki Sonoyama, Takanori Wakita, Masanori Sunagawa, Yudai Izumi, Takayuki Muro, Hiroshi Kumigashira, Masaharu Oshima, Keita Deguchi, Hiroyuki Okazaki, Yoshihiko Takano, Osuke Miura, Yoshikazu Mizuguchi, Katsuhiro Suzuki, Hidetomo Usui, Kazuhiko Kuroki, Kozo Okada, Yuji Muraoka, Takayoshi Yokoya
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Journal Title
J. Phys. Soc. Jpn.
Volume: 83
Issue: 3
Pages: 033703-033703
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] 3. Observation of an isosceles triangular electronic structure around the excess iron atoms in Fe1+dTe2013
Author(s)
T. Machida, K. Kogure, T. Kato, H. Nakamura, H. Takeya, T. Mochiku, S. Ooi, Y. Mizuguchi, Y. Takano, K. Hirata, H. Sakata
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Journal Title
Physical Review B
Volume: 87
Issue: 21
Pages: 214508-214508
DOI
Related Report
Peer Reviewed
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[Journal Article] s-wave pairing in the optimally-doped LaO0.5F0.5BiS2 superconductor2013
Author(s)
G. Lamura, T. Shiroka, P. Bonfa, S. Sanna, R. De Renzi, C. Baines, H. Luetkens, J. Kajitani, Y. Mizuguchi, O. Miura, K. Deguchi, S. Demura, Y. Takano, M. Putti
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Journal Title
Phys. Rev. B
Volume: 88
Issue: 18
DOI
Related Report
Peer Reviewed
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[Journal Article] Crystal Structure, Lattice Vibrations, and Superconductivity of LaO1-xFxBiS22013
Author(s)
J. Lee, M. B. Stone, A. Huq, T. Yildrim, G. Ehlers, Y. Mizuguchi, O. Miura, Y. Takano, K. Deguchi, S. Demura, S.-H. Lee
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Journal Title
Phys. Rev. B
Volume: 87
Issue: 20
DOI
Related Report
Peer Reviewed
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