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Development of I/I3 Redox Couple Conductive Interface Using Gyroid Minimal Surface

Research Project

Project/Area Number 25708014
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Functional solid state chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

Ichikawa Takahiro  東京農工大学, 工学(系)研究科(研究院), 准教授 (80598798)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥22,490,000 (Direct Cost: ¥17,300,000、Indirect Cost: ¥5,190,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2014: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2013: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywordsイオン液体 / 液晶 / ジャイロイド界面 / 色素増感太陽電池 / 双連続キュービック液晶
Outline of Final Research Achievements

For the improvement of dye-sensitised solar cell, it is important to develop advantageous electrolyte transporting I/I3 redox couples. In the present study, we aim to construct I/I3 redox couple conductive interface by using gyroid minimal surface. As base materials, ionic liquids were employed. We newly designed various ionic liquids having self-assembling ability and examined the relationships between the molecular structure and molecular-assembled structures. Through these investigation, we have succeeded in development of bicontinuous cubic liquid crystalline materials forming ionic gyroid minimal surface and have found out that these surface is effective for ion transportation.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (36 results)

All 2016 2015 2014 2013 Other

All Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 8 results,  Open Access: 1 results) Presentation (22 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Design of ionic liquid-based polyelectrolytes by combining ‘nanostructurisation’ and ‘zwitterionisation’2016

    • Author(s)
      Takuro Matsumoto, Takahiro Ichikawa and Hiroyuki Ohno
    • Journal Title

      Polymer Chemistry

      Volume: 7 Issue: 6 Pages: 1230-1233

    • DOI

      10.1039/c5py01838b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Comprehensive Study on Lyotropic Liquid-Crystalline Behavior of an Amphiphile in 20 Kinds of Amino Acid Ionic Liquids2016

    • Author(s)
      Kanae Fujimura, Takahiro Ichikawa, Masafumi Yoshio, Takashi Kato, Hiroyuki Ohno
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 11 Issue: 4 Pages: 520-526

    • DOI

      10.1002/asia.201501055

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ionic Switch Inducnhed by a Rectangular-Hexagonal Phase Transition in Benzenammonium Columnar Liquid Crystals2015

    • Author(s)
      Bartolome Soberats, Masafumi Yoshio, Takahiro Ichikawa, Xiangbing Zeng, Hiroyuki Ohno, Goran Ungar, Takashi Kato
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 41 Pages: 13212-13215

    • DOI

      10.1021/jacs.5b09076

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 2D Assemblies of Ionic Liquid Crystals Based on Imidazolium Moieties: Formation of Ion-Conductive Layers2015

    • Author(s)
      Junji Sakuda, Masfumi Yoshio, Takahiro Ichikawa, Hiroyuki Ohno, Takashi Kato
    • Journal Title

      New Journal of Chemistry

      Volume: 39 Issue: 6 Pages: 1-7

    • DOI

      10.1039/c5nj00085h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Gyroid Structures through the Design of Self-organizing Ionic Liquids and Their Application2015

    • Author(s)
      一川尚広、大野弘幸、吉尾正史、加藤隆史
    • Journal Title

      Nihon Kessho Gakkaishi

      Volume: 57 Issue: 3 Pages: 184-190

    • DOI

      10.5940/jcrsj.57.184

    • NAID

      130005085902

    • ISSN
      0369-4585, 1884-5576
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Columnar Nanostructured Polymer Films Containing Ionic Liquids in Supramolecular One-Dimensional Nanochannels2015

    • Author(s)
      Akihiro Yamashita, Masafumi Yoshio, Seiya Shimizu, Takahiro Ichikawa, Hiroyuki Ohno, and Takashi Kato
    • Journal Title

      J. Polym. Sci. A Polym. Chem.

      Volume: 53 Issue: 2 Pages: 366-371

    • DOI

      10.1002/pola.27380

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Liquid-Crystalline Electrolytes for Lithium-Ion Batteries: Ordered Assemblies of a Mesogen-Containing Carbonate and a Lithium Salt2015

    • Author(s)
      佐久田淳司、細野英司、吉尾正史、一川尚広、松本拓郎、大野弘幸、周豪慎、加藤隆史
    • Journal Title

      Advanced Functional Materials

      Volume: 25 Issue: 8 Pages: 1206-1212

    • DOI

      10.1002/adfm.201402509

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of Amphiphilic Zwitterions Forming Liquid-Crystalline Phases and Effects of Lithium Salt Addition on Their Phase Behavior2014

    • Author(s)
      Takuro Matsumoto, Takahiro Ichikawa, Junji Sakuda, Takashi Kato and Hiroyuki Ohno
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 87 Issue: 7 Pages: 792-796

    • DOI

      10.1246/bcsj.20140049

    • NAID

      130004059134

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Transparent and colourless room temperature ionic liquids having high refractive index over 1.602014

    • Author(s)
      Yoko Kayama, Takahiro Ichikawa and Hiroyuki Ohno
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 94 Pages: 14790-14792

    • DOI

      10.1039/c4cc06145d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 3D Anhydrous proton-transporting nanochatmels formed by self-assembly of liquid crystals composed of a sulfobetaine and a sulfonic acid2013

    • Author(s)
      B. Soberats, M. Yoshio, T. Ichikawa, S. Taguchi, H. Ohno, T. Kato
    • Journal Title

      Journal of the American Chemical Society

      Volume: 135 Issue: 41 Pages: 15286-15289

    • DOI

      10.1021/ja407883b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design and evaluation of nano-biphasic ionic liquid systems having highly polar and low polar domains2013

    • Author(s)
      S. Taguchi, T Ichikawa, T. Kato, H. Ohno
    • Journal Title

      RSC Advances

      Volume: 3 Issue: 45 Pages: 23222-23227

    • DOI

      10.1039/c3ra43876g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Designer lyotropic liquid-crystalline systems containing amino acid ionic liquids as self-organization media of amphiphiles2013

    • Author(s)
      Takahiro Ichikawa, Kanae Fujimura, Masafumi Yoshio, Takashi Kato and Hiroyuki Ohno
    • Journal Title

      Chemical Communications

      Volume: 49 Issue: 100 Pages: 11746-11748

    • DOI

      10.1039/c3cc45429k

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 液晶分子の自己組織化を利用した機能界面の設計と展開2016

    • Author(s)
      一川尚広
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス (京都府京田辺市)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液晶の自己組織化を利用したジャイロイド界面の設計とその応用2016

    • Author(s)
      一川尚広
    • Organizer
      ソフトマター研究室セミナー
    • Place of Presentation
      近畿大学理工学部 ( 大阪府東大阪市 )
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Design of Functional Bicontinuous Cubic Liquid Crystals and Their Potential Applications2016

    • Author(s)
      Takahiro Ichikawa
    • Organizer
      The 3rd CMS International Symposium
    • Place of Presentation
      九州大学伊都キャンパス (福岡県福岡市)
    • Year and Date
      2016-01-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of bicontinuous cubic liquid-crystalline assemblies using ionic liquids as building block2015

    • Author(s)
      Takahiro Ichikawa, Takuro Matsumoto, Akiyoshi Okafuji, Kanae Fujimura, Masafumi Yoshio, Takashi Kato, and Hiroyuki Ohno
    • Organizer
      THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Hawaii Convention Center, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 双連続キュービック液晶の自己組織化を用いた三次元プロトン伝導パスの構築2015

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館 (神奈川県横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] ~液晶の自己組織化を駆使したジャイロイド構造の創成~2015

    • Author(s)
      一川尚広
    • Organizer
      『不均一性・不規則性・多形性』の研究会
    • Place of Presentation
      お茶の水大学 (東京都文京区)
    • Year and Date
      2015-07-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 3D Continuous Proton Conductive Pathways through the Organization of Amphiphilic Zwitterions Forming Bicontinuous Cubic Phases2015

    • Author(s)
      Takahiro Ichikawa, Takuro Matsumoto, Takashi Kato, Hiroyuki Ohno
    • Organizer
      International Conference on Frontiers in Materials Processing, Applications, Research & Technology (FiMPART 2015)
    • Place of Presentation
      Novotel International Convention Center Hyderabad, India
    • Year and Date
      2015-06-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] "双連続キュービック液晶デザインの難しさ"vs "イオン液体の構造多様性"2015

    • Author(s)
      一川尚広
    • Organizer
      第19回液晶化学研究会シンポジウム
    • Place of Presentation
      名古屋大学ESホール (愛知県名古屋市)
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液晶の自己組織化を利用した ジャイロイド構造の設計とその応用2015

    • Author(s)
      一川尚広, 松本拓郎, 藤村佳苗, 吉尾正史, 加藤隆史, 大野弘幸
    • Organizer
      日本学術振興会第142委員会
    • Place of Presentation
      PORTA(ポルタ)神楽坂7F会議室
    • Year and Date
      2015-03-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] イオン液体のデザイン性を駆使した自己組織化材料の開発2014

    • Author(s)
      一川 尚広
    • Organizer
      第20回 錯体化学若手の会 中部・東海地区勉強会
    • Place of Presentation
      名古屋工業大学 19号館 1階 会議室
    • Year and Date
      2014-10-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Amino Acid Ionic Liquids as Self-organization Media of Amphiphilic Molecules2014

    • Author(s)
      Takahiro Ichikawa, Kanae Fujimura, Masafumi Yoshio, Takashi. Kato, and Hiroyuki Ohno
    • Organizer
      4th Asia-Pacific Conference on Ionic Liquids and Green Processes / 6th Australasian Symposium on Ionic Liquids, 2014
    • Place of Presentation
      オーストラリア, Crowne Hotel Plaza Coogee
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液晶性Zwitterionのデザインとその自己組織化制御を通じた機能展開2014

    • Author(s)
      一川尚広, 松本拓郎, 佐久田淳司, 加藤隆史, 大野弘幸
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸・塩添加による両親媒性Zwitterionの自己組織化制御2014

    • Author(s)
      一川尚広, 松本拓郎, 佐久田淳司, 加藤隆史, 大野弘幸
    • Organizer
      2014年日本液晶学会討論会
    • Place of Presentation
      島根県松江市 くにびきメッセ
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-Organization of Functional Ionic Liquids into Bicontinuous Cubic Liquid-Crystalline Assemblies2013

    • Author(s)
      T. Ichikawa, T. Matsumoto, K. Fujimura, M. Yoshio, T. Kato, and H. Ohno
    • Organizer
      COIL-5
    • Place of Presentation
      ポルトガル アルガルヴェ Vilamouraホテル
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of Lyotropic Liquid Crystals Containing Amino Acid Ionic Liquids as Solvents2013

    • Author(s)
      T. Ichikawa, K. Fujimura, M. Yoshio, T. Kato, and H. Ohno
    • Organizer
      33rd International Conference on Solution Chemistry
    • Place of Presentation
      東京都 AIST Tokyo Waterfront
    • Related Report
      2013 Annual Research Report
  • [Presentation] イオン液体を利用した機能性双連続キュービック液晶の開発2013

    • Author(s)
      一川尚広, 加藤隆史, 大野弘幸
    • Organizer
      第1回 液晶若手勉強会
    • Place of Presentation
      秋田県 田沢湖高原温泉郷 プラザホテル山麓荘
    • Related Report
      2013 Annual Research Report
  • [Presentation] Zwitterionの自己組織化を利用した三次元プロトン伝導性界面の構築2013

    • Author(s)
      一川尚広, 加藤隆史, 大野弘幸
    • Organizer
      2013年日本液晶学会討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] アミノ酸イオン液体を溶媒としたリオトロピック液晶の構築2013

    • Author(s)
      一川尚広, 藤村佳苗, 吉尾 正史, 加藤隆史, 大野弘幸
    • Organizer
      2013年日本液晶学会討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] イオン液体を基幹物質とした機能性双連続キュービック液晶のデザインとその応用展開2013

    • Author(s)
      一川尚広, 松本拓郎, 藤村佳苗、吉尾正史, 加藤隆史, 大野弘幸
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of 3D continuous gyroid minimal surface formed by self-organization of amphiphilic zwitterions and its physicochemical property evaluated from the viewpoint of ion conduction behavior2013

    • Author(s)
      一川尚広, 加藤隆史, 大野弘幸
    • Organizer
      12th European Conference on Liquid Crystals
    • Place of Presentation
      ギリシャ ロドス島 Paradise Mareホテル
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双連続キュービック相を発現する液晶性イオン液体の構築及びその分子集合構造の解析2013

    • Author(s)
      一川尚広, 吉尾正史, 田口; 怜美, Liu Feng, Zeng Xiang-bing, Ungar Goran, 大野弘幸, 加藤隆史
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶応大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Application of Gyroid Minimal Surface for 3D Continuous Proton Conductive Pathway2013

    • Author(s)
      Takahiro Ichikawa, Takashi Kato, Hiroyuki Ohno
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜市 波止場会館
    • Related Report
      2013 Annual Research Report
  • [Book] 化學工業2015

    • Author(s)
      一川尚広
    • Total Pages
      4
    • Publisher
      小峰工業出版
    • Related Report
      2015 Annual Research Report
  • [Remarks] 「燃料電池の発電効率向上に向けて~水素イオンの高速移動経路の創成~」

    • URL

      http://www.tuat.ac.jp/disclosure/pressrelease/2014/20141107160550/index.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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