Construction of new supramolecular assemblies based on host-guest chemistry in bulk state

• Project/Area Number: 25708022
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Partial Multi-year Fund
• Research Field: Polymer chemistry
• Research Institution: Kanazawa University
• Principal Investigator: Ogoshi Tomoki 金沢大学, 物質化学系, 教授 (00447682)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000); Fiscal Year 2015: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000); Fiscal Year 2013: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
• Keywords: ピラーアレーン / バルク / ホスト－ゲスト化学 / 溶媒 / リング化合物 / 蛍光 / スイッチング / バルク材料 / 液体 / 面性不斉 / ポリロタキサン / ポリエチレン / 疎水性室温環状ホスト液体 / ホスト―ゲスト化学

Outline of Final Research Achievements

In this study, we constructed new supramolecular assemblies based on host-guest chemistry in bulk state. First, we developed switchable luminescence liquid based on bulk state host-guest chemistry. Second, we developed chiral macrocyclic liquid and hydrophobic macrocyclic liquid based on versatile functionality of pillar[n]arenes.

Research Products

• [Journal Article] Porous Carbon Fibers ContainingPores with Sizes Controlled at the AngstromLevel by the Cavity Size of Pillar[6]arene (2015)
  • Author(s): Ogoshi, T. Yoshikoshi, K. Sueto, R. Nishihara, H. Yamagishi, T.
  • Journal Title: Angew Chem Int Ed Volume: 54 Issue: 22 Pages: 6466-6469
  • DOI: 10.1002/anie.201501854
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Host-Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State (2015)
  • Author(s): Ogoshi, T. Sueto, R. Yoshikoshi K. Sakata, Y. Akine, S. Yamagishi, T.
  • Journal Title: Angew Chem Int Ed Volume: 54 Issue: 34 Pages: 9849-9852
  • DOI: 10.1002/anie.201503489
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Reversible and contrasting changes of the cloud point temperature of pillar[5]arenes with one quinone unit and tri(ethylene oxide) chains induced by redox chemistry and host-guest complexation (2015)
  • Author(s): Ogoshi, T.; Akustu, T.; Tamura, Y.; Yamagishi, T.
  • Journal Title: Chem. Commun. Volume: 51 Issue: 33 Pages: 7184-7186
  • DOI: 10.1039/c5cc01630d
  • Peer Reviewed
• [Journal Article] Pillar[5]arene-Based Nonionic Polyrotaxanes and a Topological Gel Prepared from Cyclic Host Liquids (2014)
  • Author(s): Ogoshi, T.; Aoki, T.; Ueda, S.; Tamura, T.; Yamagishi, T.
  • Journal Title: Chem. Commun. Volume: 50 Issue: 50 Pages: 6607-6609
  • DOI: 10.1039/c4cc02833c
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Extension of polyethylene chains by formation of polypseudorotaxane structures with perpentylated pillar[5]arenes (2014)
  • Author(s): Ogoshi, T.; Kayama, H.; Aoki, T.; Yamagishi, T.; Ohashi, R.; Mizuno, M.
  • Journal Title: Polymer Journal Volume: 46 Issue: 1 Pages: 77-81
  • DOI: 10.1038/pj.2013.67
  • NAID: 40019921490
  • Peer Reviewed
• [Journal Article] Pillar[5]- and pillar[6]arene-based supramolecular assemblies built by using their cavity-size-dependent host–guest interactions (2014)
  • Author(s): Ogoshi, T.; Yamagishi, T.
  • Journal Title: Chem. Commun. Volume: 50 Issue: 37 Pages: 4776-4787
  • DOI: 10.1039/c4cc00738g
  • Peer Reviewed
• [Journal Article] Pillararenes, Versatile Synthetic Receptors for Supramolecular Chemistry (2013)
  • Author(s): Ogoshi, T.; Yamagishi, T.
  • Journal Title: Eur. J. Org. Chem. Volume: 15 Issue: 15 Pages: 2961-2975
  • DOI: 10.1002/ejoc.201300079
  • Peer Reviewed
• [Presentation] 柱状環状ホスト分子“Pillar［n］arene”超分子集合体を基にしたカーボンポーラス材料の創製 (2015)
  • Author(s): 生越友樹
  • Organizer: 5.第42回炭素材料学会年会 次世代の会 第2回定例会
  • Place of Presentation: 関西大学千里山キャンパス
  • Year and Date: 2015-12-04
  • Invited
• [Presentation] Pillar[n]areneを基にした超分子材料の創製－きっかけを交えて (2015)
  • Author(s): 生越友樹
  • Organizer: 第2回π造形若手会
  • Place of Presentation: 不死王閣（大阪府池田市伏尾温泉）
  • Year and Date: 2015-11-21
  • Invited
• [Presentation] Pillar[n]arene の超分子集合体を利用した吸着材料の創製 (2015)
  • Author(s): 生越友樹
  • Organizer: 第25 回吸着シンポジウム 夏の学校
  • Place of Presentation: 京都市左京区 関西セミナーハウス＜修学院きらら山荘＞
  • Year and Date: 2015-08-31
  • Invited
• [Presentation] Pillar[n]arenes: from Simple Molecular Receptors to Bulk Supramolecular Materials (2015)
  • Author(s): Ogoshi, T
  • Organizer: 13th International Conference on Calixarenes (Calix 2015)
  • Place of Presentation: Atahotel Naxos Beach, Giardini Naxos (Sicily), Italy
  • Year and Date: 2015-07-08
  • Int'l Joint Research / Invited
• [Presentation] Extension of Polyethylene Chains by Formation of Polypseudorotaxane Structures with Perpentylated Pillar[5]arenes (2015)
  • Author(s): 生越友樹
  • Organizer: 第64回高分子学会年次大会 PJ-ZEON賞 受賞講演
  • Place of Presentation: 北海道札幌市 札幌コンベンションセンター
  • Year and Date: 2015-05-28
  • Invited
• [Presentation] Supramolecular Assembly Based on Facile and Versatile Macrocycles Pillararenes (2014)
  • Author(s): Ogoshi, T.
  • Organizer: International Polymer Conference 2014
  • Place of Presentation: Epochal Tsukuba, Tsukuba, Japan
  • Year and Date: 2014-12-04
  • Invited
• [Presentation] Pillar[n]arenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry (2014)
  • Author(s): Ogoshi, T.
  • Organizer: IUMRS-ICA2014
  • Place of Presentation: Fukuoka University, Fukuoka
  • Year and Date: 2014-08-25
  • Invited
• [Presentation] Pillar[n]arenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry (2014)
  • Author(s): Ogoshi, T.
  • Organizer: NIMS Conference 2014
  • Place of Presentation: Epochal Tsukuba, Tsukuba, Japan
  • Year and Date: 2014-07-03
  • Invited
• [Presentation] Pillararenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry (2014)
  • Author(s): Ogoshi, T.
  • Organizer: 2014 International Symposium on Frontiers of Molecular Recognition and Function, ICCAS-LMRF
  • Place of Presentation: Chinese Academy of Science, Beijing, China
  • Year and Date: 2014-06-06
  • Invited
• [Presentation] "Pillar[n]arene-based Polymer Materials" (2013)
  • Author(s): Ogoshi, T.
  • Organizer: JAIST International Symposium on Functional Polymer Materials
  • Place of Presentation: 北陸先端科学技術大学院大学
  • Invited
• [Presentation] 柱状環状ホスト分子 Pillar[n]arene の合成と超分子材料への応用 (2013)
  • Author(s): 生越友樹
  • Organizer: 第 6 回 ChemBio ハイブリッドレクチャー
  • Place of Presentation: 東京大学
  • Invited
• [Presentation] Pillararenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry (2013)
  • Author(s): Ogoshi, T.
  • Organizer: China-Japan Joint Symposium on Functional Supramolecular Architectures
  • Place of Presentation: Soochow University、中国
  • Invited
• [Presentation] Pillararenes: Easy-to-Make and Versatile Receptors for Supramolecular Chemistry (2013)
  • Author(s): Ogoshi, T.
  • Organizer: 8th International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: アメリカ・Crystal City、バージニア
  • Invited
• [Book] Pillararenes (2016)
  • Author(s): Ogoshi, T.
  • Total Pages: 320
  • Publisher: Royal Society of Chemistry
• [Book] 超分子材料の設計と応用展開 (2014)
  • Author(s): 生越友樹、山岸忠明
  • Total Pages: 13
  • Publisher: シーエムシ―出版
• [Book] クリックケミストリー－基礎から応用まで－ (2014)
  • Author(s): 生越友樹、山岸忠明
  • Total Pages: 14
  • Publisher: シーエムシ―出版