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Widening of optical design freedom of organic thin films for high-performance organic semiconductor devices

Research Project

Project/Area Number 25708038
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Device related chemistry
Research InstitutionYamagata University

Principal Investigator

YOKOYAMA Daisuke  山形大学, 理工学研究科, 准教授 (00518821)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥26,390,000 (Direct Cost: ¥20,300,000、Indirect Cost: ¥6,090,000)
Fiscal Year 2015: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2013: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Keywords有機半導体デバイス / 屈折率 / 複屈折 / エレクトレット / 分子配向 / 有機EL / 光取り出し効率 / 非晶質有機薄膜 / 有機半導体 / 非晶質 / 超低屈折率 / 光学設計自由度 / 光物性 / 半導体物性 / 先端機能デバイス / 化学物理
Outline of Final Research Achievements

In this study, we extended the control range of the refractive index and birefringence of organic semiconductor films and applied their techniques to organic semiconductor devices to improve the device performances. We newly developed conductive super-low-index charge transport layers by mixing amorphous organic semiconductors and low-index electret materials, and also controlled the birefringence of amorphous organic semiconductor films using molecular orientation. We showed that the outcoupling efficiency of organic light-emitting diodes can be enhanced by these controls of refractive index and birefringence. Furthermore, we analyzed the dependence of the refractive index and birefringence on fabrication processes, and clarified the mechanism of film formation related to the birefringence control.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (43 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (30 results) (of which Int'l Joint Research: 7 results,  Invited: 12 results) Remarks (5 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Ghent University(ベルギー)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] University of Wisconsin-Madison(米国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Anisotropic materials in OLEDs for high outcoupling efficiency2015

    • Author(s)
      Michiel Koen Callens, Daisuke Yokoyama, Kristiaan Neyts
    • Journal Title

      Optics Express

      Volume: 23 Issue: 16 Pages: 21128-21148

    • DOI

      10.1364/oe.23.021128

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Advantages and disadvantages of vacuum-deposited and spin-coated amorphous organic semiconductor films for organic light-emitting diodes2015

    • Author(s)
      Maki Shibata, Yoshiya Sakai, Daisuke Yokoyama
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 42 Pages: 11178-11191

    • DOI

      10.1039/c5tc01911g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simple model-free estimation of orientation order parameters of vacuum-deposited and spin-coated amorphous films used in organic light-emitting diodes2015

    • Author(s)
      Yoshiya Sakai, Maki Shibata, Daisuke Yokoyama
    • Journal Title

      Applied Physics Express

      Volume: 8 Issue: 9 Pages: 096601-096601

    • DOI

      10.7567/apex.8.096601

    • NAID

      210000137661

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photopatterning of indomethacin thin films: a solvent-free vapor-deposited photoresist2015

    • Author(s)
      Katherine L. Camera, Jaritza Gomez-Zayas, Daisuke Yokoyama, Mark D. Ediger, Christopher K. Ober
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 7 Issue: 42 Pages: 23398-23401

    • DOI

      10.1021/acsami.5b05361

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 非晶質有機半導体デバイスの光学設計自由度の拡張:分子配向制御と屈折率制御2014

    • Author(s)
      横山大輔
    • Journal Title

      応用物理

      Volume: 83 Pages: 279-283

    • NAID

      130007718504

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Birefringent organic layers in top- and bottom emitting OLEDs2016

    • Author(s)
      Michiel Koen Callens, Daisuke Yokoyama, Kristiaan Neyts
    • Organizer
      SPIE Optics+Photonics 2016
    • Place of Presentation
      San Diego Convention Center, San Diego, US
    • Year and Date
      2016-08-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular orientation in OLEDs: Order in disorder in amorphous organic films2016

    • Author(s)
      Daisuke Yokoyama
    • Organizer
      ISOME2016 (9th International Symposium on Organic Molecular Electronics)
    • Place of Presentation
      TOKIMATE, Niigata University, Niigata, Japan
    • Year and Date
      2016-05-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子配向の直接的簡易評価法の開発と成膜条件依存性の分析2016

    • Author(s)
      酒井義也、福田瑞香、柴田真希、横山大輔
    • Organizer
      2016年春季応用物理学会
    • Place of Presentation
      東京工業大学大岡山キャンパス、東京都目黒区
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Recent Progress on the understanding of molecular states in OLED films: molecular orientation, packing, and mixing2015

    • Author(s)
      Daisuke Yokoyama
    • Organizer
      IDW '15 (The 22nd International Display Workshops)
    • Place of Presentation
      Otsu Prince Hotel, Otsu, Japan
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子配向の直接的簡易評価法の開発と成膜条件依存性の分析2015

    • Author(s)
      酒井義也、柴田真希、横山大輔
    • Organizer
      有機EL討論会第21回例会
    • Place of Presentation
      九州大学伊都キャンパス、福岡市
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機ELスピンコート膜中の分子配向の成膜条件依存性とその直接評価2015

    • Author(s)
      酒井義也、柴田真希、横山大輔
    • Organizer
      2015年秋季応用物理学会
    • Place of Presentation
      名古屋国際会議場、名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機半導体材料とエレクトレット材料の混合により作製された超低屈折率電荷輸送層2015

    • Author(s)
      鈴木泰隆、會田航、横山大輔
    • Organizer
      2015年秋季応用物理学会
    • Place of Presentation
      名古屋国際会議場、名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機EL 蒸着膜の蒸着速度による分子配向・膜密度・熱安定性の変化2015

    • Author(s)
      柴田真希、酒井義也、横山大輔
    • Organizer
      2015年秋季応用物理学会
    • Place of Presentation
      名古屋国際会議場、名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Super-low-index hole transport layers and their applications for OLEDs2015

    • Author(s)
      Daisuke Yokoyama, Yasutaka Suzuki, Wataru Aita, Maki Shibata
    • Organizer
      IMID 2015 (The 15th International Meeting on Information Display)
    • Place of Presentation
      EXCO (Daegu, Korea)
    • Year and Date
      2015-08-18 – 2015-08-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Super-low-index hole transport layers and their applications for high outcoupling of OLEDs2015

    • Author(s)
      Daisuke Yokoyama, Yasutaka Suzuki, Wataru Aita
    • Organizer
      IMID2015 (The 15th International Meeting on Information Display)
    • Place of Presentation
      EXCO, Daegu, Republic of Korea
    • Year and Date
      2015-08-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Advantages and disadvantages of vacuum- and solution-processed OLED films: Differences in molecular orientation, thermal stability, and interfacial mixing2015

    • Author(s)
      Daisuke Yokoyama, Maki Shibata, Yoshiya Sakai
    • Organizer
      SPIE Optics+Photonics 2015
    • Place of Presentation
      San Diego Convention Center (San Diego, US)
    • Year and Date
      2015-08-09 – 2015-08-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Advantages and disadvantages of vacuum- and solution-processed OLED films: Differences in molecular orientation, thermal stability, and interfacial mixing2015

    • Author(s)
      Daisuke Yokoyama, Maki Shibata, Yoshiya Sakai
    • Organizer
      SPIE Optics+Photonics 2015
    • Place of Presentation
      San Diego Convention Center, San Diego, US
    • Year and Date
      2015-08-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anisotropy in OLEDs2015

    • Author(s)
      Michiel Koen Callens, Daisuke Yokoyama, Kristiaan Neyts
    • Organizer
      SPIE Optics+Photonics 2015
    • Place of Presentation
      San Diego Convention Center, San Diego, US
    • Year and Date
      2015-08-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超低屈折率正孔輸送層の開発とその有機EL応用2015

    • Author(s)
      鈴木泰隆、會田航、柴田真希、横山大輔
    • Organizer
      有機EL討論会第20回例会
    • Place of Presentation
      千葉大学西千葉キャンパス、千葉市
    • Year and Date
      2015-06-18
    • Related Report
      2015 Annual Research Report
  • [Presentation] Differences in molecular orientation and density of vacuum- and solution-processed OLED films and their effects on light extraction and thermal stability2015

    • Author(s)
      Daisuke Yokoyama, Maki Shibata
    • Organizer
      2015 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Moscone West (San Francisco, US)
    • Year and Date
      2015-04-06 – 2015-04-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Differences in molecular orientation and density of vacuum- and solution-processed OLED films and their effects on light extraction and thermal stability2015

    • Author(s)
      Daisuke Yokoyama, Maki Shibata
    • Organizer
      2015 MRS Spring Meeting
    • Place of Presentation
      Moscone West, San Francisco, US
    • Year and Date
      2015-04-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低分子非晶質有機半導体薄膜の高次構造分析と有機EL・有機太陽電池への応用2015

    • Author(s)
      横山大輔
    • Organizer
      日本化学会第95春季年会(第29回若い世代の特別講演会)
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] スピンコート成膜条件による膜物性への影響2014

    • Author(s)
      柴田真希、横山大輔
    • Organizer
      有機EL討論会第19回例会
    • Place of Presentation
      沖縄県市町村自治会館(沖縄県那覇市)
    • Year and Date
      2014-11-27 – 2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 非晶質有機半導体薄膜の異方性とその有機エレクトロニクスへの応用2014

    • Author(s)
      横山大輔
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 成膜法による有機EL材料の膜物性の違い2014

    • Author(s)
      柴田真希、横山大輔
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分光エリプソメトリーによる非晶質有機半導体薄膜の屈折率・密度・分子配向の分析2014

    • Author(s)
      横山大輔
    • Organizer
      第10回偏光計測研究会
    • Place of Presentation
      物質・材料研究機構(茨城県つくば市)
    • Year and Date
      2014-09-01
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Differences between vacuum-deposited and spin-coated amorphous films of OLED materials2014

    • Author(s)
      Daisuke Yokoyama, Maki Shibata
    • Organizer
      SPIE Optics+Photonics 2014
    • Place of Presentation
      San Diego Convention Center (San Diego, US)
    • Year and Date
      2014-08-17 – 2014-08-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 真空蒸着膜とスピンコート膜の密度と分子配向2014

    • Author(s)
      柴田真希、横山大輔
    • Organizer
      有機EL討論会第18回例会
    • Place of Presentation
      千葉大学西千葉キャンパス(千葉県稲毛区)
    • Year and Date
      2014-07-17 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機EL材料の真空蒸着膜とスピンコート膜の絶対密度評価2014

    • Author(s)
      柴田真希、横山大輔
    • Organizer
      第61回応用物理学会春季学術講演会(2014年春季応用物理学会)
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県相模原市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Optical anisotropy and molecular orientation in amorphous organic semiconductor films2013

    • Author(s)
      Daisuke Yokoyama
    • Organizer
      The 6th International Conference on Spectroscopic Ellipsometry (ICSE-VI)
    • Place of Presentation
      京都リサーチパーク(京都市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Fundamental properties of vacuum-deposited amorphous organic semiconductor films: density, molecular orientation, and refractive index2013

    • Author(s)
      Daisuke Yokoyama
    • Organizer
      SPIE Optics+Photonics
    • Place of Presentation
      San Diego Convention Center (San Diego, US)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Molecular states in amorphous organic semiconductor films used in OLEDs2013

    • Author(s)
      Daisuke Yokoyama
    • Organizer
      EuroDisplay2013 (33rd International Display Research Conference)
    • Place of Presentation
      Imperial College London (London, UK)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] X線反射率測定による非晶質有機半導体蒸着膜の質量密度分析と充填係数評価2013

    • Author(s)
      柴田真希、鈴木早紀、村岡宏樹、小川智、横山大輔
    • Organizer
      第74回応用物理学会秋季学術講演会(2013年秋季応用物理学会)
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機EL中の分子配向と膜物性・デバイス特性2013

    • Author(s)
      横山大輔
    • Organizer
      有機EL討論会第17回例会
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 非晶質有機半導体蒸着膜の密度分析と充填係数評価2013

    • Author(s)
      柴田真希、鈴木早紀、村岡 宏樹、小川智、横山大輔
    • Organizer
      有機EL討論会第17回例会
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Related Report
      2013 Annual Research Report
  • [Remarks] 雑誌「化学と工業」2015年8月号 飛翔する若手研究者 横山大輔

    • URL

      http://www.chemistry.or.jp/journal/doc/ci1508.pdf

    • Related Report
      2015 Annual Research Report
  • [Remarks] 第39回(2015年秋季)応用物理学会講演奨励賞 受賞者:酒井義也(指導学生)

    • URL

      https://www.jsap.or.jp/activities/award/lecture/dai39kai.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 有機EL討論会第21回例会(2015年11月) 講演奨励賞 受賞者:酒井義也(指導学生)

    • URL

      http://www.yuki-tohronkai.jp/prize-list.htm

    • Related Report
      2015 Annual Research Report
  • [Remarks] 屈折率制御・光伝搬制御 - 有機半導体デバイスの光学設計自由度の拡張へ

    • URL

      http://dyoko.yz.yamagata-u.ac.jp/res7.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 屈折率制御・光伝搬制御 -有機半導体デバイスの光学設計自由度の拡張へ

    • URL

      http://dyoko.yz.yamagata-u.ac.jp/res7.html

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機電荷輸送層、有機ELデバイス、有機半導体デバイス及び有機光電子デバイス2015

    • Inventor(s)
      横山大輔、鈴木泰隆、會田航
    • Industrial Property Rights Holder
      横山大輔、鈴木泰隆、會田航
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-121641
    • Filing Date
      2015-06-17
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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