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Study on mechanism of hydrogen embrittlement through a use of characteristic strength properties of submicron materials

Research Project

Project/Area Number 25709003
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Materials/Mechanics of materials
Research InstitutionKansai University

Principal Investigator

TAKAHASHI Yoshimasa  関西大学, システム理工学部, 准教授 (20611122)

Research Collaborator TANAKA Nobuo  名古屋大学, 未来材料システム研究所, 教授 (40126876)
MUTO Shunsuke  名古屋大学, 未来材料システム研究所, 教授 (20209985)
KONDO Hikaru  関西大学, 大学院理工学研究科, 博士前期課程学生
AIHARA Kazuya  関西大学, 大学院理工学研究科, 博士前期課程学生
ASANO Ryo  関西大学, 大学院理工学研究科, 博士前期課程学生
ASHIDA Itaru  関西大学, 大学院理工学研究科, 博士前期課程学生
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2014: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2013: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywords水素脆性 / 格子脆化説 / サブミクロン材料 / 電子顕微鏡 / 強度評価 / 機械材料・材料力学 / 水素
Outline of Final Research Achievements

The hydrogen-enhanced decohesion (HEDE) theory, which is claimed to be one of the fundamental mechanisms of the so-called hydrogen embrittlement (HE), is experimentally investigated by utilizing the characteristic mechanical properties of submicron-scale materials (e.g. high yield strength, low dislocation density). Submicron specimens are fabricated from (i) a grain boundary (GB) in a polycrystal and (ii) a thin-film layered material. They are fractured either along the GB or interface in a transmission electron microscope (TEM) equipped with an environmental cell. Brittle GB fracture, which is also accompanied by plasticity, is observed only in a hydrogen environment. The strength against interfacial fracture is eminently reduced in a hydrogen environment. These results strongly suggest that the HEDE and its influence on fracture are present regardless of the material scale.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (15 results)

All 2016 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results) Presentation (11 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Interfacial fracture strength of micro-scale Si/Cu components with different free-edge shape2016

    • Author(s)
      Y. Takahashi, H. Kondo, K. Aihara, M. Takuma, K. Saitoh, S. Arai, S. Muto, Y. Yamamoto, K. Higuchi, N. Tanaka
    • Journal Title

      Key Engineering Materials

      Volume: 665 Pages: 169-172

    • DOI

      10.4028/www.scientific.net/kem.665.169

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Direct evaluation of grain boundary hydrogen embrittlement: a micro-mechanical approach2016

    • Author(s)
      Y. Takahashi, H. Kondo, R. Asano, S. Arai, K. Higuchi, Y. Yamamoto, S. Muto, N. Tanaka
    • Journal Title

      Materials Science & Engineering A

      Volume: 661 Pages: 211-216

    • DOI

      10.1016/j.msea.2016.03.035

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Interfacial fracture strength property of micro-scale SiN/Cu components2016

    • Author(s)
      Yoshimasa Takahashi, Kazuya Aihara, Itaru Ashida, Masanori Takuma, Kenichi Saitoh, Tomohiro Sato, Kimitaka Higuchi, Yuta Yamamoto, Shigeo Arai, Shunsuke Muto
    • Journal Title

      Structural Integrity Procedia

      Volume: 未定

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quantitative evaluation of interfacial fracture strength in micro-scale components combined with high-voltage environmental electron microscopy2015

    • Author(s)
      Y. Takahashi, S. Arai, Y. Yamamoto, K. Higuchi, H. Kondo, Y. Kitagawa, S. Muto, N. Tanaka
    • Journal Title

      Experimental Mechanics

      Volume: 未定 Issue: 6 Pages: 1047-1056

    • DOI

      10.1007/s11340-015-0008-2

    • Description
      accepted in printing
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] マイクロ要素界面端からの剥離き裂発生強度評価(界面端形状の影響評価)2016

    • Author(s)
      相原寿哉,高橋可昌,宅間正則,齋藤賢一,佐藤知広
    • Organizer
      日本機械学会関西支部第91期定時総会講演会
    • Place of Presentation
      大阪電気通信大学
    • Year and Date
      2016-03-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] SiN/Cuマイクロ要素界面端からの剥離き裂発生強度評価2016

    • Author(s)
      芦田至,高橋可昌,宅間正則,齋藤賢一,佐藤知宏
    • Organizer
      日本機械学会関西学生会
    • Place of Presentation
      大阪電気通信大学
    • Year and Date
      2016-03-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] 超高圧電子顕微鏡を援用した材料強度メカニズムの解明2015

    • Author(s)
      高橋可昌
    • Organizer
      (公社)日本材料学会 分子動力学部門・マイクロマテリアル部門合同部門委員会
    • Place of Presentation
      日本材料学会、京都市
    • Year and Date
      2015-11-02
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Evaluation of interfacial fracture strength in micro-components with different free-edge shape2015

    • Author(s)
      Yoshimasa Takahashi, Kazuya Aihara, Itaru Ashida, Kimitaka Higuchi, Yuta Yamamoto, Shigeo Arai, Shunsuke Muto, Nobuo Tanaka
    • Organizer
      International Conference on Advanced Technology in Experimental Mechanics
    • Place of Presentation
      LOISIR HOTEL, Toyohashi, Aichi, Japan
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interfacial fracture strength of micro-scale Si/Cu components with different free-edge shape2015

    • Author(s)
      Yoshimasa Takahashi, Hikaru Kondo, Kazuya Aihara, Masanori Takuma, Kenichi Saitoh, Shigeo Arai, Shunsuke Muto, Yuta Yamamoto, Kimitaka Higuchi, Nobuo Tanaka
    • Organizer
      14th International Conference on Fracture and Damage Mechanics
    • Place of Presentation
      Budva, Montenegro
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 環境制御型電子顕微鏡を用いた単一粒界破壊挙動のその場観察試験2015

    • Author(s)
      近藤光,高橋可昌,宅間正則,齋藤賢一
    • Organizer
      日本機械学会関西支部第90期総会・講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-16 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単一粒界試験片を用いた粒界水素脆性の評価2015

    • Author(s)
      浅野瞭,高橋可昌,宅間正則,齋藤賢一
    • Organizer
      日本機械学会関西学生会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 先進電子顕微鏡法を援用した材料強度メカニズムの解析2014

    • Author(s)
      高橋可昌
    • Organizer
      (公社)日本材料学会 理事会主催企画「微小材料強度学研究集会 実験編」
    • Place of Presentation
      日本材料学会(京都府)
    • Year and Date
      2014-12-25 – 2014-12-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] In situ micro-mechanical testing of grain boundaries combined with environmental TEM2014

    • Author(s)
      Yoshimasa Takahashi, Hikaru Kondo, Ryo Asano, Masanori Takuma, Kenichi Saitoh, Sigeo Arai, Shunsuke Muto, Nobuo Tanaka
    • Organizer
      Asian-Pacific Conference on Fracture and Strength (APCFS) /International Conference on Structural Integrity and Failure (SIF)
    • Place of Presentation
      Sydney, Australia
    • Year and Date
      2014-12-09 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] マイクロ要素界面端からの剥離き裂発生強度評価2014

    • Author(s)
      北川優,高橋可昌,宅間正則,齋藤賢一
    • Organizer
      日本機械学会関西支部H25年度学生会
    • Place of Presentation
      大阪府立大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 反応科学超高圧電子顕微鏡を用いたガス環境実験2013

    • Author(s)
      荒井重勇、高橋可昌、武藤俊介、山本悠太、丹司敬義、田中信夫
    • Organizer
      日本顕微鏡学会第69回学術講演会
    • Place of Presentation
      ホテル阪急エキスポパーク
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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