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Clarification of growth mechanism of high-quality iron-based superconductor films and construction of growth technique of films exhibiting high performance

Research Project

Project/Area Number 25709058
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

Hiramatsu Hidenori  東京工業大学, 科学技術創成研究院, 准教授 (80598136)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥26,130,000 (Direct Cost: ¥20,100,000、Indirect Cost: ¥6,030,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Keywordsパルスレーザー堆積法 / エピタキシャル成長 / 超伝導 / 磁束ピニング / 臨界電流
Outline of Final Research Achievements

Using pulsed laser deposition (PLD) employing 4 types of pulsed lasers, we explored the growth condition to obtain high quality BaFe2As2:Co thin films, and found that the optimum growth rate is constant to be 0.3nm/sec even if we employ different pulsed lasers for PLD. Further, we applied this optimized process to growth of BaFe2As2:P that we can expect higher critical temperature (~30 K) than that of BaFe2As2:Co (~20 K). Consequently, we succeeded in achieving high-performance critical current density of 7 MA/cm2, which is almost the same as the level of the final target (10 MA/cm2) for this research. Additionally, we fabricated the films on practically applied metal-tape substrates and achieved high performance practical level Jc of 0.1 MA/cm2 at 15 T.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (38 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 9 results,  Open Access: 2 results,  Acknowledgement Compliant: 5 results) Presentation (27 results) (of which Int'l Joint Research: 10 results,  Invited: 9 results)

  • [Int'l Joint Research] ツービンゲン大学(ドイツ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Tubingen(Germany)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] High-field transport properties of a P-doped BaFe2As2 film on technical substrate2017

    • Author(s)
      K. Iida, H. Sato, C. Tarantini, J. Hänisch, J. Jaroszynski, H. Hiramatsu, B. Holzapfel, and H. Hosono
    • Journal Title

      Sci. Rep.

      Volume: 7 Issue: 1

    • DOI

      10.1038/srep39951

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Key Factors for Insulator-Superconductor Transition in FeSe Thin Films by Electric Field2017

    • Author(s)
      K. Hanzawa, H. Sato, H. Hiramatsu, T. Kamiya, and H. Hosono
    • Journal Title

      IEEE Trans. Appl. Supercond.

      Volume: 27 Issue: 4 Pages: 1-5

    • DOI

      10.1109/tasc.2016.2639738

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] BaFe2(As1-xPx)2 (x = 0.22-0.42) thin films grown on practical metal-tape substrates and their critical current densities2017

    • Author(s)
      H. Hiramatsu, H. Sato, T. Kamiya, and H. Hosono
    • Journal Title

      Supercond. Sci. Technol.

      Volume: 30 Issue: 4 Pages: 044003-044003

    • DOI

      10.1088/1361-6668/aa621c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Novel solid-phase epitaxy for multi-component materials with extremely high vapor pressure elements: An application to KFe2As22016

    • Author(s)
      T. Hatakeyama, H. Sato, H. Hiramatsu, T. Kamiya and H. Hosono
    • Journal Title

      Appl. Phys. Express

      Volume: 9 Issue: 5 Pages: 055505-055505

    • DOI

      10.7567/apex.9.055505

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electric field-induced superconducting transition of an insulating FeSe thin film at 31 K2016

    • Author(s)
      K. Hanzawa, H. Sato, H. Hiramatsu, T. Kamiya, and H. Hosono
    • Journal Title

      National Academy of Sciences of the United States of America

      Volume: 113 Issue: 15 Pages: 3986-3990

    • DOI

      10.1073/pnas.1520810113

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced critical-current in P-doped BaFe2As2 thin films on metal substrates arising from poorly aligned grain boundaries2016

    • Author(s)
      H. Sato, H. Hiramatsu, T. Kamiya, and H. Hosono
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1

    • DOI

      10.1038/srep36828

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Vortex pinning property of phosphorous-doped BaFe2As2 epitaxial films: Comparison between (La,Sr)(Al,Ta)O3 and MgO substrates2015

    • Author(s)
      H. Sato, H. Hiramatsu, T. Kamiya, and H. Hosono
    • Journal Title

      IEEE Trans. Appl. Supercond.

      Volume: 25 Issue: 3 Pages: 1-5

    • DOI

      10.1109/tasc.2014.2368073

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Critical factor for epitaxial growth of cobalt-doped BaFe2As2 films by pulsed laser deposition2014

    • Author(s)
      H. Hiramatsu, H. Sato, T. Katase, T. Kamiya and H. Hosono
    • Journal Title

      Applied Physics Letters

      Volume: 104 Issue: 17 Pages: 172602-172602

    • DOI

      10.1063/1.4874609

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High critical-current density with less anisotropy in BaFe2(As,P)2 epitaxial thin films: Effect of intentionally grown c-axis vortex-pinning centers2014

    • Author(s)
      H. Sato, H. Hiramatsu, T. Kamiya and H. Hosono
    • Journal Title

      Applied Physics Letters

      Volume: 104 Issue: 18 Pages: 182603-182603

    • DOI

      10.1063/1.4875956

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ba1-xLaxFe2As2薄膜の結晶構造2017

    • Author(s)
      小林賢介, 中尾朗子, 真木祥千子, 山浦淳一, 片瀬貴義, 佐藤光, 佐賀山基, 熊井玲児, 村上洋一, 平松秀典, 細野秀雄
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 絶縁性FeSe薄膜における電界誘起超伝導に関するチャネル層の影響2017

    • Author(s)
      半沢幸太、平松秀典、神谷利夫、細野秀雄
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属テープ基板上に作製した鉄系超伝導体BaFe2(As,P)2薄膜における臨界電流特性のP濃度依存性2017

    • Author(s)
      平松 秀典,佐藤 光,神谷 利夫,細野 秀雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉄系超伝導体FeSe薄膜中のエピタキシャル歪みと電子構造の関係2017

    • Author(s)
      山口祐太,半沢幸太,小畑由紀子,半那 拓,戸田喜丈,松石 聡,平松秀典,細野秀雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] ZrCuSiAs型構造を有する鉄系超伝導体のヘテロエピタキシャル成長2017

    • Author(s)
      金城 弘幸,ハインドル シルビア,平松 秀典,細野 秀雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] 異なるチャネル成長条件で作製した絶縁性FeSeを用いた電気二重層トランジスタ2017

    • Author(s)
      半沢 幸太,平松 秀典,神谷 利夫,細野 秀雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2017-01-12
    • Related Report
      2016 Annual Research Report
  • [Presentation] Thin-film growth and electric double-layer transistors of iron-based superconductors2016

    • Author(s)
      H. Hiramatsu and H. Hosono
    • Organizer
      1st Asian International Cryogenic Materials Conference and Cryogenics and Superconductivity Society of Japan 50th Anniversary Conference
    • Place of Presentation
      Kanazawa, Japan
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electric filed-induced phase transition of insulating iron-selenides2016

    • Author(s)
      H. Hiramatsu and H. Hosono
    • Organizer
      International Symposium on Revolutionary Atomic-Layer Materials
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2016-10-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Superconductor transition from insulating FeSe thin films induced by electric double-layer transistor2016

    • Author(s)
      H. Hiramatsu, K. Hanzawa, H. Sato, T. Kamiya, and H. Hosono
    • Organizer
      Applied Superconductivity Conference 2016 (ASC2016)
    • Place of Presentation
      Denver, Colorado, USA
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationship Between Surface Degradation and Electric Field-Induced Superconductivity for Insulator-Like FeSe Epitaxial Films2016

    • Author(s)
      Kota Hanzawa, Hikaru Sato, Hidenori Hiramatsu, Toshio Kamiya, and Hideo Hosono
    • Organizer
      The 5th International Symposium on Advanced Microscopy and Theoretical Calculations (AMTC5)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2016-05-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Vortex Pinning Properties of Slightly Over-Doped BaFe2As2:P Epitaxial Films2016

    • Author(s)
      Hiroyuki Kinjo, Hikaru Sato, Hidenori Hiramatsu, Toshio Kamiya, and Hideo Hosono
    • Organizer
      The 5th International Symposium on Advanced Microscopy and Theoretical Calculations (AMTC5)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2016-05-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Difference in Electronic Structures of Superconducting and Insulator-Like FeSe Epitaxial Films2016

    • Author(s)
      Yuta Yamaguchi, Kota Hanzawa, Taku Hanna, Yoshitake Toda, Satoru Matsuishi, Hidenori Hiramatsu, and Hideo Hosono
    • Organizer
      The 5th International Symposium on Advanced Microscopy and Theoretical Calculations (AMTC5)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2016-05-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属IBADテープ基板上に作製した鉄系超伝導体BaFe2(As,P)2薄膜の臨界電流特性2016

    • Author(s)
      平松 秀典,佐藤 光,神谷 利夫,細野 秀雄
    • Organizer
      第54回セラミックス基礎科学討論会
    • Place of Presentation
      アバンセ,グランデはがくれ(佐賀市)
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electric Double-Layer Transistors Using Iron-Based Layered Compounds2016

    • Author(s)
      H. Hiramatsu and H. Hosono
    • Organizer
      EMN Prague Meeting 2016: Iron and Iridium based Superconductivity
    • Place of Presentation
      Prague, Czech Republic
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Molecular beam epitaxy growth of insulator-like FeSe thin films for direct induction of insulator-superconductor transition by electric field2016

    • Author(s)
      Kota Hanzawa, Hikaru Sato, Hidenori Hiramatsu, Toshio Kamiya, and Hideo Hoson
    • Organizer
      Applied Superconductivity Conference 2016 (ASC2016)
    • Place of Presentation
      Denver, Colorado, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Heteroepitaxial growth of layered pnictides and chalcogenides films2015

    • Author(s)
      H. Hiramatsu and H. Hosono
    • Organizer
      Collaborative Conference on Crystal Growth 2015: Epitaxial Thin Films and Nanostructures
    • Place of Presentation
      Eaton Hotel, Kowloon, Hong Kong
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ba(Fe1-xCox)2As2エピタキシャル薄膜における特異な圧力効果と電子輸送特性2015

    • Author(s)
      平松 秀典, 佐藤 光, 神谷 利夫, 細野 秀雄
    • Organizer
      第157回日本金属学会 秋期講演大会
    • Place of Presentation
      九州大学 伊都キャンパス, 福岡
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] PLD法によるIBAD-MgO 基板上へのP添加BaFe2As2薄膜成長2015

    • Author(s)
      佐藤 光, 平松 秀典, 神谷 利夫, 細野 秀雄
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Progress in Thin Films and Devices of Iron-based Layered Materials2015

    • Author(s)
      H. Hiramatsu, H. Sato, T. Katase, T. Kamiya, and H. Hosono
    • Organizer
      Energy Materials and Nanotechnology Qingdao Meeting 2015: Iron and Iridium based Superconductivity
    • Place of Presentation
      Qingdao, China
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thin Films and Devices of Iron-based Layered Compounds2015

    • Author(s)
      H. Hiramatsu, H. Sato, T. Katase, T. Kamiya, and H. Hosono
    • Organizer
      4th Annual World Congress of Advanced Materials 2015
    • Place of Presentation
      Chongqing, China
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thin Film Growth and Device Fabrication of Iron-Based Layered Materials: High-Performance Superconducting Films and Electric Double-Layer Transistors2014

    • Author(s)
      H. Hiramatsu, H. Sato, T. Katase, T. Kamiya, and H. Hosono
    • Organizer
      The 27th International Symposium on Superconductivity 2014 (ISS 2014)
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-11-25 – 2014-11-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] PLD法による鉄系超伝導体BaFe2As2薄膜の膜質決定要因の解明と等方的な高臨界電流密度の実現2014

    • Author(s)
      平松 秀典,佐藤 光,片瀬 貴義,神谷 利夫,細野 秀雄
    • Organizer
      日本金属学会 2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス (愛知県名古屋市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Excitation laser dependence and control factor for crystallinity of cobalt-doped BaFe2As2 epitaxial films by pulsed laser deposition2014

    • Author(s)
      Hidenori Hiramatsu, Hikaru Sato, Takayoshi Katase, Toshio Kamiya, and Hideo Hosono
    • Organizer
      Applied Superconductivity Conference 2014
    • Place of Presentation
      Charlotte, North Carolina (USA)
    • Year and Date
      2014-08-10 – 2014-08-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Strong vortex pinning and isotropic critical current density in BaFe2(As,P)2 epitaxial films grown by pulsed laser deposition2014

    • Author(s)
      Hikaru Sato, Hidenori Hiramatsu, , Takayoshi Katase, Toshio Kamiya, and Hideo Hosono
    • Organizer
      Applied Superconductivity Conference 2014
    • Place of Presentation
      Charlotte, North Carolina (USA)
    • Year and Date
      2014-08-10 – 2014-08-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Progress in Epitaxial Thin Films of 122-type Iron-pnictide Superconductors: Non-equilibrium Impurity Doping and Critical Current Density2014

    • Author(s)
      H. Hiramatsu and H. Hosono
    • Organizer
      13th International Conference on Modern Materials and Technologies (CIMTEC2014): the 6th Forum on New Materials
    • Place of Presentation
      Tuscany (Italy)
    • Year and Date
      2014-06-15 – 2014-06-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Superconductivity of indirectly electron-doped and isovalent-doped 122-type epitaxial films2014

    • Author(s)
      H. Hiramatsu, H. Sato, T. Katase, T. Kamiya, and H. Hosono
    • Organizer
      Energy Materials Nanotechnology Summer Meeting 2014 (EMN 2014): Iron and Iridium based Superconductivity
    • Place of Presentation
      Cancun (Mexico)
    • Year and Date
      2014-06-09 – 2014-06-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] PLD法によるCo添加BaFe2As2エピタキシャル薄膜成長と励起レーザー波長との関係2014

    • Author(s)
      平松秀典
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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