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Deepening in elucidation of adsorption structure of adsorbed water on superhydrophobic/superhydrophilic surfaces and development of control technology for dynamic behavior of water

Research Project

Project/Area Number 25709061
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionShibaura Institute of Technology

Principal Investigator

ISHIZAKI Takahiro  芝浦工業大学, 工学部, 准教授 (50397486)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥25,870,000 (Direct Cost: ¥19,900,000、Indirect Cost: ¥5,970,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2014: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2013: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Keywords超はっ水 / 超親水 / 吸着水 / 水の動的挙動 / ヒステリシス / 水の動的制御
Outline of Final Research Achievements

In this study, some organic thin films were formed on glass and Si substrates by thermal CVD method using methyl-terminated organic silane molecule as raw materials and, the static and dynamic behaviors of water droplet on the film coated hydrophobic surfaces were investigated. The static water contact angles increased with an increase in the treatment temperature in the thermal CVD process. The contact angle hysteresis were tend to become lower as the static contact angle were higher. AFM study revealed that the increase in the contact angle hysteresis could be due to the pinning effect based on the increase in the surface roughness. The adhesion force of the adsorbed water on various film coated hydrophobic surfaces were estimated by a force curve measurement. These results revealed that it was necessary to use silane molecules with constant distance between methyl groups in the molecular framework to form surface having low contact angle hysteresis.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (19 results)

All 2016 2015 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of treatment temperature on surface wettability of methylcyclosiloxane layer formed by chemical vapor deposition2016

    • Author(s)
      T. Ishizaki, K. Sasagawa, T. Furukawa, S. Kumagai, E. Yamamoto, S. Chiba, T. Kiguchi
    • Journal Title

      Appl. Surf. Sci.

      Volume: 382 Pages: 446-451

    • DOI

      10.1016/j.apsusc.2016.03.149

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 2種類の有機シラン分子を化学吸着させたSi表面の濡れ性挙動2016

    • Author(s)
      笹川圭祐、石崎貴裕
    • Organizer
      表面技術協会第133回講演大会
    • Place of Presentation
      早稲田大学西早稲田キャンパス
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effect of Surface Wettability on Adsorption Behavior of Human Plasma Fibrinogen with Heparin2016

    • Author(s)
      T. Ishizaki, T. Furukawa, K. Sasagawa, N. Saito
    • Organizer
      The 2nd Int'l Conference on Surface and Interface of Materials (SIM 2016)
    • Place of Presentation
      Arnoma Grand Bangkok, Thailand
    • Year and Date
      2016-01-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 溶液プロセスによるマグネシウム合金上への超はっ水皮膜の形成とその化学的特性評価2015

    • Author(s)
      熊谷颯,石崎貴裕
    • Organizer
      日本材料科学会第3回 メゾスコピック研究会講演会
    • Place of Presentation
      千葉工業大学 東京スカイツリータウンキャンパス
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Preparation of dewetting surface showing low contact angle hysteresis by thermal CVD using organic silane molecules with different molecular configuration2015

    • Author(s)
      T. Ishizaki, T. Furukawa, K. Teshima
    • Organizer
      16th European Conference on Applications of Surface and Interface Analysis (ECASIA’15)
    • Place of Presentation
      Granada Congress&Exhibition Center, Granada, Spain
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 溶液プロセスによるマグネシウム合金表面の超はっ水化処理技術の開発2015

    • Author(s)
      熊谷颯,石崎貴裕
    • Organizer
      表面技術協会第132回講演大会
    • Place of Presentation
      信州大学長野キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 簡易プロセスによる高機能性材料創製技術の開発2015

    • Author(s)
      石崎貴裕
    • Organizer
      公益財団法人 りそな中小企業振興財団 平成27年度第3回技術懇親会
    • Place of Presentation
      芝浦工業大学
    • Year and Date
      2015-09-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Preparation of dewetting surface showing low contact angle hysteresis using organic silane molecules with different molecular configuration2015

    • Author(s)
      T. Ishizaki, K. Teshima
    • Organizer
      12th International Conference on Nanosciences & Nanotechnologies (NN15)
    • Place of Presentation
      Porto Palace is a Conference Centre & Hotel, Thessaloniki, Greece
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 分子構造の異なる有機シラン分子で被覆した表面の濡れ性評価2015

    • Author(s)
      古川卓弥,石崎貴裕
    • Organizer
      表面技術協会第131回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2015-03-04 – 2015-03-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of dewetting surface showing low contact angle hysteresis toward control of water droplet behavior2014

    • Author(s)
      D. Yashima, T. Ishizaki
    • Organizer
      EMN(Energy Materiao and Nanotechnology)2014
    • Place of Presentation
      Florida, Orland, USA
    • Year and Date
      2014-11-22 – 2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] はっ水表面における水の静的・動的挙動に及ぼす有機シラン分子の構造2014

    • Author(s)
      八島大,石崎貴裕
    • Organizer
      表面技術協会第130回講演大会
    • Place of Presentation
      京都大学
    • Year and Date
      2014-09-22 – 2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of self-repairing hydrophobic surface using Mg-Al layered double hydroxides2014

    • Author(s)
      N. Toyoda, T. Ishizaki
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication of hydrophobic/superhydrophobic silica surface showing low contact angle hysteresis by thermal CVD2014

    • Author(s)
      D. Yashima, T. Ishizaki
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] はっ水・超はっ水表面における水の吸着・動的挙動2013

    • Author(s)
      八島大、石崎貴裕
    • Organizer
      表面技術協会第128回講演大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Facile Preparation preparation of superhydrophobic silica coating system hydrophobic on glass by thermal CVD2013

    • Author(s)
      Dai Yashima, Takahiro Ishizaki
    • Organizer
      International Conference on Surface Engineering (ICSE2013)
    • Place of Presentation
      Haeundae Grand Hotel, Busan, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] 気相プロセスを用いたはっ水・超はっ水処理

    • Author(s)
      石崎貴裕
    • Organizer
      第58回CVD研究会
    • Place of Presentation
      愛知工業大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 濡れ性制御表面の構築とその応用

    • Author(s)
      石崎貴裕
    • Organizer
      FS分子産業講演会:界面の制御,機能,応用
    • Place of Presentation
      産業技術総合研究所つくばセンター
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Handbook of Self-Cleaning Surfaces and Materials: From Fundamentals to Applications Vol. 2: Chapter 22, Superhydrophobic anticorrosion coating2016

    • Author(s)
      T. Ishizaki, T. Furukawa, N. Kamiyama, N. Saito, O. Takai
    • Total Pages
      250
    • Publisher
      Wiley
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 撥水性マグネシウム材の製造方法および撥水性マグネシウム材2016

    • Inventor(s)
      石崎貴裕,熊谷颯
    • Industrial Property Rights Holder
      石崎貴裕,熊谷颯
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-031381
    • Filing Date
      2016-02-22
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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