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Photochemical synthesis of composites consisting of multi-component mixed oxides and semiconductors and their application in photocatalysis

Research Project

Project/Area Number 25709078
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionTokyo Institute of Technology

Principal Investigator

Maeda Kazuhiko  東京工業大学, 理工学研究科, 准教授 (40549234)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥25,350,000 (Direct Cost: ¥19,500,000、Indirect Cost: ¥5,850,000)
Fiscal Year 2015: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Keywords光触媒 / 助触媒 / 水の分解 / 水素製造 / 人工光合成 / ナノ粒子
Outline of Final Research Achievements

Metal species that can be photodeposited with Cr on the surface of strontium titanate powder were explored. As a result, it was found that Au and Pd fit the bill, and worked as cocatalysts for hydrogen evolution in photocatalytic overall water splitting when mixed with Cr species. Detailed investigations on the Pd/Cr system indicated that the photocatalytic activity for overall water splitting depended strongly on the structure and electronic state of the Pd/Cr multicomponent cocatalyst. The mechanism by which the Pd/Cr nanoparticles were formed was also discussed on the basis of experimental results.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (37 results)

All 2016 2015 2014 2013 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (27 results) (of which Int'l Joint Research: 5 results,  Invited: 20 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Development of Novel Photocatalyst and Cocatalyst Materials for Water Splitting under Visible Light2016

    • Author(s)
      Kazuhiko Maeda, Kazunari Domen
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 89 Issue: 6 Pages: 627-648

    • DOI

      10.1246/bcsj.20150441

    • NAID

      130005157271

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Light-Induced Synthesis of Heterojunctioned Nanoparticles on a Semiconductor as Durable Cocatalysts for Hydrogen Evolution2016

    • Author(s)
      Tomoki Kanazawa, Kazuhiko Maeda
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 8 Issue: 11 Pages: 7165-7172

    • DOI

      10.1021/acsami.6b00907

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrothermal synthesis of rhodium-doped barium titanate nanocrystals for enhanced photocatalytic hydrogen evolution under visible light2015

    • Author(s)
      Shunta Nishioka, Kazuhiko Maeda
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 121 Pages: 100123-100128

    • DOI

      10.1039/c5ra20044j

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dependence of Activity of Rutile Titanium(IV) Oxide Powder for Photocatalytic Overall Water Splitting on Structural Properties2014

    • Author(s)
      Kazuhiko Maeda, Naoya Murakami, Teruhisa Ohno
    • Journal Title

      Journal of Physical Chemistry C

      Volume: Vol. 118 Issue: 17 Pages: 9093-9100

    • DOI

      10.1021/jp502949q

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Doped Barium Titanate Perovskite as a Stable p-type Semiconductor Photocatalyst for Hydrogen Evolution under Visible Light2014

    • Author(s)
      Kazuhiko Maeda
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 6 Issue: 3 Pages: 2167-2173

    • DOI

      10.1021/am405293e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic properties of rutile TiO2 powder for overall water splitting2014

    • Author(s)
      Kazuhiko Maeda
    • Journal Title

      Catalysis Science & Technology

      Volume: 印刷中 Issue: 7 Pages: 1949-1953

    • DOI

      10.1039/c4cy00251b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 同時光析出法を用いた水の酸化助触媒の開発2016

    • Author(s)
      金澤 知器, 石谷 治, 前田 和彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Visible-Light-Driven Water Splitting and Carbon Dioxide Fixation by Surface Modified Semiconductor Photocatalysts2016

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      Prof. Hua Zhang’s group special seminar
    • Place of Presentation
      Nanyang Technological University, Singapore
    • Year and Date
      2016-02-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光析出法によるFe-Cr複合酸化物ナノ粒子の調製と水分解助触媒への応用2016

    • Author(s)
      金澤知器, 石谷治, 前田和彦
    • Organizer
      新学術域領域「人工光合成」 第4回公開シンポジウム
    • Place of Presentation
      東京理科大学葛飾キャンパス
    • Year and Date
      2016-01-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] Heterogeneous photocatalysis: New ideas and methodologies toward efficient water splitting2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Hyatt Regency Waikiki, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Photocatalysts for Solar-to-Fuel Conversion2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      228th Electrochemical Society (ECS) Meeting
    • Place of Presentation
      Phoenix Convention Center, USA
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 同時光析出法で調製したPd-Cr系ナノ粒子の水分解反応に対する助触媒効果2015

    • Author(s)
      金澤 知器, 石谷 治, 前田 和彦
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 太陽光エネルギー変換を指向した非酸化物系光触媒の開発2015

    • Author(s)
      前田和彦
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 同時光析出法で調製した複合系ナノ粒子の水分解反応に対する助触媒効果2015

    • Author(s)
      金澤知器, 石谷治, 前田和彦
    • Organizer
      第34回光が関わるシンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2015-06-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Water splitting and CO2 reduction using modified semiconductor photocatalysts2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Hyatt Regency Vancouver, Canada
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of new heterogeneous photocatalysts for solar-to-fuel conversion2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      Prof. Pingwu Du’s group special seminar
    • Place of Presentation
      University of Science and Technology, China
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光触媒による水分解を目指した同時光析出法を基盤とする複合助触媒の開発2015

    • Author(s)
      金澤知器・石谷治・前田和彦
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 表面修飾型光触媒による可視光水分解と二酸化炭素固定化反応2015

    • Author(s)
      前田和彦
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Photocatalytic Water Splitting and CO2 Fixation over Surface-Modified Semiconductors under Visible Light2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      249th ACS National Meeting
    • Place of Presentation
      Colorado Convention Center, USA
    • Year and Date
      2015-03-22 – 2015-03-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Evolution and CO2 Reduction by Metal-Complex/Nanostructured-Semiconductor Hybrids under Visible Light2015

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      3rd International Symposium on Chemistry for Energy Conversion and Storage
    • Place of Presentation
      The Harnack House, Berlin, Germany
    • Year and Date
      2015-01-18 – 2015-01-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Semiconductor Photocatalysts for Water Splitting and CO2 Fixation2014

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      The International Conference on Electronic Materials and Nanotechnology for Green Environment 2014
    • Place of Presentation
      Ramada Plaza, Jeju, Korea
    • Year and Date
      2014-11-16 – 2014-11-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Water Splitting and CO2 Fixation over Modified Semiconductor Photocatalysts under Visible Light2014

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      The 4th International Symposium on Solar Fuels and Solar Cells
    • Place of Presentation
      Dalian Institute of Chemical Physics, China
    • Year and Date
      2014-10-20 – 2014-10-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Visible-light water splitting and CO2 reduction by modified semiconductor photocatalysts2014

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      TOCAT7 KYOTO2014
    • Place of Presentation
      京都テルサ
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光触媒が教えてくれた研究の楽しさと難しさ2014

    • Author(s)
      前田和彦
    • Organizer
      触媒学会若手会 第25回フレッシュマンゼミナール
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-05-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ルチル型酸化チタン粉末上での純水の光分解反応2014

    • Author(s)
      前田和彦
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      ロワジールホテル豊橋
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面ナノ構造を制御した半導体光触媒による水の可視光完全分解2014

    • Author(s)
      前田和彦
    • Organizer
      第31回無機材料に関する最近の研究成果発表会
    • Place of Presentation
      東海大学校友会館
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Solar-driven water splitting by modified semiconductor photocatalysts2014

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      EMN Spring Meeting 2014
    • Place of Presentation
      Redrock Hotel, Las Vegas
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 水の可視光分解のための新規光触媒及び助触媒材料の開発2014

    • Author(s)
      前田和彦
    • Organizer
      近畿大学理工学部古南研究室 表面設計化学セミナー
    • Place of Presentation
      近畿大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 水の可視光分解のための新規光触媒及び助触媒材料の開発2014

    • Author(s)
      前田和彦
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ルチル型酸化チタン粉末を光触媒とした水の完全分解反応2013

    • Author(s)
      前田和彦
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Surface Modified Oxynitrides as Photocatalysts for Water Splitting under Visible Light2013

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      The fifth World Hydrogen Technologies Convention (WHTC2013)
    • Place of Presentation
      Shanghai
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Semiconductor photocatalysts for visible-light water splitting: Structure and reaction mechanism2013

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      平成25年度 日本分光学会年次講演会 国際シンポジウム「分光学の太陽電池・天然/人工光合成への応用」
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Visible-Light water splitting using modified oxynitride photocatalysts2013

    • Author(s)
      Kazuhiko Maeda
    • Organizer
      The 8th international conference on processing & manufacturing of advanced materials
    • Place of Presentation
      Rio Hotel, Las Vegas
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Solar to Chemical Energy Conversion; Theory and Application2016

    • Author(s)
      Kazuhiko Maeda(執筆分担)
    • Total Pages
      489
    • Publisher
      SPringer
    • Related Report
      2015 Annual Research Report
  • [Book] Photocatalysis : Fundamentals and Perspectives2016

    • Author(s)
      Kazuhiko Maeda(執筆分担)
    • Total Pages
      436
    • Publisher
      RSC Publishing
    • Related Report
      2015 Annual Research Report
  • [Book] 人工光合成; 光エネルギーによる物質変換の化学2015

    • Author(s)
      前田和彦(執筆分担)
    • Total Pages
      341
    • Publisher
      三共出版
    • Related Report
      2015 Annual Research Report
  • [Remarks]

    • URL

      http://www.chemistry.titech.ac.jp/~ishitani/member/kmaeda/

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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