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In situ chemical analysis of natural water composition using laser ablated plasmas

Research Project

Project/Area Number 25709084
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Naval and maritime engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Thornton Blair  東京大学, 生産技術研究所, 特任准教授 (60526789)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2014: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2013: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywordsレーザー誘起破壊分光 / 自然水 / 化学分析 / 分光分析 / LIBS / 海 / 海水 / 熱水 / 海水他元素分析 / プラズマ発光 / レーザ / レーザ誘起破壊分光法 / 液体の化学分析 / 元素分析 / プラズマ / 海洋調査 / 資源調査 / 環境調査
Outline of Final Research Achievements

The aim of this research is to develop a technique for in situ, multi-element analysis of natural river, lake and oceanic fluids. The method developed is based on laser-induced breakdown spectroscopy. In this technique, a high power laser pulse of focused into a bulk fluid to generate a plasma. By observing the spectrum of light emitted from the plasma, it is possible to perform realtime element analysis of ionic species dissolved in seawater. In this research, we demonstrated that the technique can be applied to the high-pressure high-temperature environments that exist on the seafloor. Furthermore, we demonstrated that by measuring the shot-to-shot energy of the laser pulse used and monitoring the temporal evolution of each plasma that is generated, it is possible to significantly improve the quantitative performance of the developed method.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (12 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (4 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] A calibration-free approach for on-site multi-element analysis of metal ions in aqueous solutions by electrodeposition-assisted underwater laser-induced breakdown spectroscopy2016

    • Author(s)
      Ayumu Matsumoto, Ayaka Tamura, Ryo Koda, Kazuhiro Fukami, Yukio H. Ogata, Naoya Nishi, Blair Thornton, Tetsuo Sakka
    • Journal Title

      Spectrochimica Acta Part B: Atomic Spectroscopy

      Volume: 118 Pages: 45-55

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] On site Quantitative Elemental Analysis of Metal Ions in Aqueous Solutions by Laser-Induced Breakdown Spectroscopy Combined with Electrodeposition under Controlled Potential2015

    • Author(s)
      Ayumu Matsumoto, Ayaka Tamura, Ryo Koda, Kazuhiro Fukami, Yukio Ogata, Naoya Nishi, Blair Thornton, Tetsuo Sakka
    • Journal Title

      Analytical Chemistry

      Volume: 87 Pages: 1655-1661

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Development of a deep-sea Laser-induced breakdown spectrometer for in situ multi-element chemical analysis2015

    • Author(s)
      Thornton, B., Takahashi, T., Sato, T., Sakka, T., Tamura, A., Matsumoto, A., Nozaki, T., Ohki, T. and Ohki, K.
    • Journal Title

      Deep-Sea Research Part I

      Volume: 95 Pages: 20-36

    • DOI

      10.1016/j.dsr.2014.10.006

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Long-Duration Nanosecond Single Pulse Lasers for Observation of Spectra from Bulk Liquids at High Hydrostatic Pressures2014

    • Author(s)
      Blair Thornton, Tetsuo Sakka, Tatsuya Masamura, Ayaka Tamura, Tomoko Takahashi, Ayumu Matsumoto
    • Journal Title

      Spectrochimica Acta Part B

      Volume: TBD

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Deep-Sea Laser-Induced Breakdown Spectroscopy and its Application to Hydrothermal Mineral Surveys in the Okinawa Trough2016

    • Author(s)
      Blair Thornton, Tomoko Takahashi, Takumi Sato, Tetsuo Sakka, Toshihiko Ohki, Koichi Ohki
    • Organizer
      In Proc. Ocean Sciences Meeting 2016
    • Place of Presentation
      New Orleans, US
    • Year and Date
      2016-02-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Application of Laser-Induced Breakdown Spectroscopy for In-situ Measurement of Metal Grade for Seafloor Mineral Processing2015

    • Author(s)
      Yasuharu Nakajima, Blair Thornton, Takumi Sato
    • Organizer
      In Proc. Oceans 2015
    • Place of Presentation
      Washington, US
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Quantitative Elemental Analysis of Trace Metal Ions in Aqueous Solutions by Underwater LIBS Combined with Pre-concentration by Electrodeposition2015

    • Author(s)
      Tetsuo Sakka, Ayumu Matsumoto, Ayaka Tamura, Ryo Koda, Kazuhiro Fukami, Yukio H. Ogata, Naoya Nishi, Blair Thornton
    • Organizer
      ASLIBS 2015, China
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2015-06-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Towards real-time quantification of seawater composition using laser-induced breakdown spectroscopy’2015

    • Author(s)
      Takumi Sato, Blair Thornton, Tomoko Takahashi, Tetsuo Sakka, Toshihiko Ohki, Koichi Ohki
    • Organizer
      In Proc. Oceans 2015
    • Place of Presentation
      Genoa, Italy
    • Year and Date
      2015-05-18
    • Related Report
      2015 Annual Research Report
  • [Remarks] Ocean Perception Laboratory

    • Related Report
      2015 Annual Research Report
  • [Remarks] 研究室ホームページ

    • Related Report
      2014 Annual Research Report
  • [Remarks] 深海底レーザ誘起破壊分光法に関する研究

    • URL

      http://ocean.iis.u-tokyo.ac.jp/ja/research/laser_induced.html

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] Chemical analysis device2016

    • Inventor(s)
      Thornton, Sakka, Ohki
    • Industrial Property Rights Holder
      Thornton, Sakka, Ohki
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-23
    • Acquisition Date
      2016-04-18
    • Related Report
      2015 Annual Research Report
    • Overseas

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Published: 2013-05-21   Modified: 2019-07-29  

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