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Development of novel metallocene-containing fire suppressants

Research Project

Project/Area Number 25750135
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Social systems engineering/Safety system
Research InstitutionYokohama National University

Principal Investigator

Koshiba Yusuke  横浜国立大学, 工学(系)研究科(研究院), 技術専門職員 (60419273)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords消火 / 消火剤 / フェロセン / メタロセン / 分散 / 火災 / 分散系 / 遷移金属 / 燃焼抑制
Outline of Final Research Achievements

The objectives of this study were to directly compare the flame inhibition efficiency of transition metals using metallocenes and to develop a novel ferrocene-containing fire suppressant: an aqueous ferrocene dispersion. In this study, the downward flame spread rates over filter paper samples on which each metallocene was adsorbed were determined; besides, TG measurements were conducted to finally determine the phase in which each metallocene produced its flame inhibition effect. Aside from the experiments, for aqueous ferrocene dispersions, the dispersibilities and suppression capabilities to suppress pool fires were investigated. The former experiment indicated that the metallocenes tested in this study exhibit a flame inhibition effect solely in the gas phase. The latter experiment demonstrated that there is a positive relationship between their suppression capabilities and the dispersions and that aqueous ferrocene dispersions have shorter extinguishing times than a wet chemical.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (19 results)

All 2016 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (13 results) (of which Int'l Joint Research: 2 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] Extinguishing pool fires with aqueous ferrocene dispersions containing gemini surfactants2016

    • Author(s)
      Koshiba Y., Ohtani H.
    • Journal Title

      Journal of Loss Prevention in the Process Industries

      Volume: 40 Pages: 10-16

    • DOI

      10.1016/j.jlp.2015.11.029

    • NAID

      120006534531

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Direct comparison of the flame inhibition efficiency of transition metals using metallocenes2015

    • Author(s)
      Koshiba Y., Agata S., Takahashi T., Ohtani H.
    • Journal Title

      Fire Safety Journal

      Volume: 73 Pages: 48-54

    • DOI

      10.1016/j.firesaf.2015.03.003

    • NAID

      120006534535

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fire extinguishing properties of novel ferrocene/surfynol 465 dispersions2015

    • Author(s)
      Koshiba Y., Iida K., Ohtani H.
    • Journal Title

      Fire Safety Journal

      Volume: 72 Pages: 1-6

    • DOI

      10.1016/j.firesaf.2015.02.011

    • NAID

      120006534536

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Flame inhibition mechanisms of vanadocene2015

    • Author(s)
      Koshiba Y., Takahashi T., Ohtani H.
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawaii Convention Center (Honolulu, the United States)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バナドセンの燃焼抑制メカニズムの解明2015

    • Author(s)
      髙橋,小柴佑介,大谷英雄
    • Organizer
      第48回安全工学研究発表会
    • Place of Presentation
      朱鷺メッセ (新潟県新潟市)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fire suppression efficiency of aqueous dispersions of ferrocene: Effects of ferrocene particle size and surfactant2015

    • Author(s)
      Koshiba Y., Iida K., Ohtani H.
    • Organizer
      10th Asia-Oceania Symposium on Fire Science and Technology
    • Place of Presentation
      Tsukuba International Congress Center (Tsukuba, Japan)
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] XRDおよびXPSを用いた燃焼抑制に寄与するバナジウム化合物の同定2015

    • Author(s)
      小柴佑介
    • Organizer
      平成27年度機器分析技術研究会
    • Place of Presentation
      山形大学(山形県米沢市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] フェロセン/水分散系の消火性能に及ぼすフェロセン粒径および分散剤の影響2015

    • Author(s)
      小柴佑介,大谷英雄 ら
    • Organizer
      平成27年度日本火災学会研究発表会
    • Place of Presentation
      山形大学(山形県米沢市)
    • Year and Date
      2015-05-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 固相において燃焼抑制効果を示すバナジウム化合物の同定2014

    • Author(s)
      髙橋知秀,小柴佑介,大谷英雄
    • Organizer
      日本機械学会産業・化学機械と安全部門研究発表講演会2014冬
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] フェロセン/水分散系の分散性が消火能力に与える影響2014

    • Author(s)
      飯田慶大,小柴佑介,大谷英雄
    • Organizer
      第47回安全工学研究発表会
    • Place of Presentation
      産業技術総合研究所(茨城県つくば市)
    • Year and Date
      2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Flame inhibition effect of metallocenes2014

    • Author(s)
      Koshiba Y., Takahashi T., Agata S., Ohtani H.
    • Organizer
      5th World Conference on the Safety of Oil and Gas Industry
    • Place of Presentation
      Okayama Convention Center (Okayama, Japan)
    • Year and Date
      2014-06-10
    • Related Report
      2014 Research-status Report
  • [Presentation] フェロセン/水分散消火剤の開発2014

    • Author(s)
      飯田慶大,小柴佑介,大谷英雄
    • Organizer
      平成26年度日本火災学会研究発表会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2014-05-27
    • Related Report
      2014 Research-status Report
  • [Presentation] フェロセン/水分散系の消火能力に関する研究

    • Author(s)
      飯田慶大,武田透摩,小柴佑介,大谷英雄
    • Organizer
      日本機械学会 産業・化学機械と安全部門講演会2013
    • Place of Presentation
      横浜国立大学 (神奈川県横浜市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Experimental study of fire suppression by aqueous dispersions of ferrocene

    • Author(s)
      Koshiba Y., Iida K., Takeda T., Ohtani H.
    • Organizer
      Asia Pacific Symposium on Safety 2013
    • Place of Presentation
      Orchard Hotel Singapore (Singapore)
    • Related Report
      2013 Research-status Report
  • [Presentation] メタロセンの燃焼抑制効果に関する実験的研究

    • Author(s)
      小柴佑介,阿形早織,髙橋知秀,大谷英雄
    • Organizer
      日本機械学会 産業・化学機械と安全部門講演会 2013 秋
    • Place of Presentation
      東京工業大学 (東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 熱重量分析による遷移金属化合物の燃焼抑制効果が発現する相の解明

    • Author(s)
      小柴佑介
    • Organizer
      実験・実習技術研究会
    • Place of Presentation
      岩手大学 (岩手県盛岡市)
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 消火剤および消火方法2016

    • Inventor(s)
      大谷英雄,小柴佑介
    • Industrial Property Rights Holder
      国立大学法人横浜国立大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-23
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 消火剤および消火方法2014

    • Inventor(s)
      小柴佑介,大谷英雄
    • Industrial Property Rights Holder
      横浜国立大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-12-24
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 消火剤2013

    • Inventor(s)
      大谷英雄,小柴佑介
    • Industrial Property Rights Holder
      横浜国立大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-127569
    • Filing Date
      2013-06-18
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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