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The elucidation of the stability and novel physical properties of amino acid and related substances in the extreme environment by an electron microscopy

Research Project

Project/Area Number 25790003
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanostructural chemistry
Research InstitutionOsaka University

Principal Investigator

KEITA Kobayashi  大阪大学, 超高圧電子顕微鏡センター, 助教 (40556908)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsナノマテリアル / カーボンナノチューブ / カルコゲン / 氷 / 構造相転移 / 透過電子顕微鏡 / 電子エネルギー損失分光分析 / ナノ制限空間 / 走査透過電子顕微鏡 / 電子エネルギー損失分光 / カーボンナノホーン / 炭化ニオブ / アラニン
Outline of Final Research Achievements

Unusual structures and properties of materials at two extreme environments, outer space mimicked by inner column of an electron microscope and confined nano spaces in inner of carbon nanotubes, were studied by transmission electron microscopy and electron energy loss spectroscopy. Experimental results suggest that amino acids may be able to be protected from high energy ray irradiation by ionic liquid coating. The results imply that amino acids can survive at outer space when the amino acids are protected by these materials. Also we found that van der Waals interaction between host materials which form the confined nano space and guest materials significantly affects structure and properties of the guest materials in the confined nanospace. The results provide important theoretical suggestions for development of nano devices by applying the confined nano space.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Acknowledgement Compliant: 1 results,  Peer Reviewed: 2 results) Presentation (17 results) (of which Invited: 2 results)

  • [Journal Article] 官能基の極性に依存したC60誘導体の中空状ナノ炭素物質内部空間への内包の傾向2015

    • Author(s)
      小林慶太, 上野裕, 小久保研, 湯田坂雅子, 保田英洋
    • Journal Title

      New Diamond

      Volume: 31(1) Pages: 28-30

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] ナノ制限空間における物質の構造と挙動についての透過電子顕微鏡観察2015

    • Author(s)
      小林慶太
    • Journal Title

      まてりあ

      Volume: 54

    • NAID

      130005071729

    • Related Report
      2014 Annual Research Report
  • [Journal Article] “Syntesis of Refractory Conductive Niobium Carbide Nanowires within the Inner Space of Carbon Nanotube Templates”2014

    • Author(s)
      K.Kobayashi
    • Journal Title

      Appl.Phys.Express

      Volume: 7 Issue: 1 Pages: 15101-15101

    • DOI

      10.7567/apex.7.015101

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of functional group polarity on the encapsulation of C60 derivatives in the inner space of carbon nanohorns2014

    • Author(s)
      Keita Kobayashi, Hiroshi Ueno, Ken Kokubo, Masako Yudasaka, Hidehiro Yasuda
    • Journal Title

      Carbon

      Volume: 68 Pages: 346-351

    • DOI

      10.1016/j.carbon.2013.11.011

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Structural transformation of tellurium encapsulated in the inner space of carbon nanotubes depending on tube diameter2015

    • Author(s)
      Keita Kobayashi, Hidehiro Yasuda
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学 伊藤国際学術研究センター 伊藤謝恩ホール, 東京
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Anomalous structure of tellurium encapsulated within confined nanospaces of carbon nanotubes, and relation between carbon nanotube diameter and the structure2014

    • Author(s)
      Keita Kobayashi, Hidehiro Yasuda
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center, Boston, USA
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ空間における希ガスその場観察の検討2014

    • Author(s)
      小林慶太
    • Organizer
      日本顕微鏡学会その場観察研究部会第二回研究討論会
    • Place of Presentation
      ファインセラミックスセンター, 名古屋
    • Year and Date
      2014-11-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 電子顕微鏡内で極限状態の物質を観察する: 擬宇宙空間とナノ空間2014

    • Author(s)
      小林慶太
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス, 名古屋
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ナノ空間内部におけるテルルの特異な結晶構造2014

    • Author(s)
      小林慶太, 保田英洋
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学東山キャンパス, 名古屋
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Relation between valence of iron ions in maghemite nanoparticles and their saturation magnetization2014

    • Author(s)
      Keita Kobayashi, Kazunari Nojiri, Tomoyuki Terai, Tomoyuki Kakeshita, Hidehiro Yasuda
    • Organizer
      ISSPIC XVII: International Symposium on Small Particles and Inorganic Clusters
    • Place of Presentation
      Kyusyu University, Fukuoka, Japan
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analytical transmission electron microscopy of Xe gas encapsulated within the inner space of fullerene-capped single-wall carbon nanotubes2014

    • Author(s)
      Keita Kobayashi, Hidehiro Yasuda
    • Organizer
      第47回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      名古屋大学 IB電子情報館, 名古屋
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 共沈法により合成した糖被膜酸化鉄超微粒子に含まれる鉄イオンの価数の粒径依存性とそれに伴う飽和磁化の変化2014

    • Author(s)
      小林慶太, 野尻和成,寺井智之,掛下知行,保田英洋
    • Organizer
      ナノ学会第12回大会
    • Place of Presentation
      京都大学おうばくプラザ, 宇治
    • Year and Date
      2014-05-22 – 2014-05-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] カーボンナノチューブアンプルを利用した希ガス原子の透過電子顕微鏡分析2014

    • Author(s)
      小林慶太, 斎藤毅, 清宮維春, 保田英洋
    • Organizer
      日本顕微鏡学会第70回記念学術講演会
    • Place of Presentation
      幕張メッセ 国際会議場, 千葉
    • Year and Date
      2014-05-11 – 2014-05-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of functional groups on encapsulation of C60 derivatives inside carbon nanohorns2014

    • Author(s)
      Keita Kobayashi, Hiroshi Ueno, Ken Kokubo, Masako Yudasaka, Hidehiro Yasuda
    • Organizer
      1st KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Senri Life Science Center, Osaka, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Containment method for transmission electron microscopy of gas molecules within the inner space of carbon nanotubes under high vacuum2014

    • Author(s)
      Keita Kobayashi, Takeshi Saito, Masaharu Kiyomiya, Hidehiro Yasuda
    • Organizer
      第46回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学 伊藤国際学術研究センター 伊藤謝恩ホール, 東京
    • Related Report
      2013 Research-status Report
  • [Presentation] One-step synthesis of NbC nanowire within inner space of carbon nanotubes by template method2013

    • Author(s)
      Keita Kobayashi, Satoshi Anada, Takeshi Nagase, Takeshi Saito, Masaharu Kiyomiya, Ikuya Wakamori, Ryo Kitaura, Hisanori Shinohara, Hidehiro Yasuda
    • Organizer
      NT’13: 14th International Conference on the Science and Application of Nanotube
    • Place of Presentation
      Aalto University, Espoo, Finland
    • Related Report
      2013 Research-status Report
  • [Presentation] Phase transition of crystalline ice thin film from Ic phase to XI phase under high energy electron beam irradiation2013

    • Author(s)
      Keita Kobayashi, Hidehiro Yasuda
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center, Boston, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] カーボンナノチューブ内部に調製した炭化ニオブの結晶構造2013

    • Author(s)
      小林慶太, 穴田智史, 永瀬丈嗣, 斎藤毅, 清宮維春, 保田英洋
    • Organizer
      日本顕微鏡学会第69回学術講演会
    • Place of Presentation
      ホテル阪急エキスポパーク, 吹田
    • Related Report
      2013 Research-status Report
  • [Presentation] 改良鋳型法によるカーボンナノチューブ内部空間への金属炭化物の導入2013

    • Author(s)
      小林慶太, 穴田智史, 永瀬丈嗣, 斎藤毅, 清宮維春, 保田英洋
    • Organizer
      ナノ学会第11回大会
    • Place of Presentation
      東京工業大学百年記念館, 東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Interaction between the inner space of carbon nanohorns and functionalized C60 molecules depending on their functional group2013

    • Author(s)
      Keita Kobayashi, Hiroshi Ueno, Ken Kokubo, Hidehiro Yasuda
    • Organizer
      第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      大阪大学大阪大学会館, 大阪
    • Related Report
      2013 Research-status Report
  • [Presentation] 改良鋳型法によるカーボンナノチューブ内部への炭化ニオブナノワイヤーの形成2013

    • Author(s)
      小林慶太, 永瀬丈嗣, 保田英洋, 穴田智史, 斎藤毅, 清宮維春, 北浦良, 王青, 若森育也, 篠原久典
    • Organizer
      日本金属学会2013年秋期(第153回)講演大会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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