| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Outline of Final Research Achievements |
Covalent and non-covalent assemblies were constructed from multi-ferrocenyl complexes as building blocks to obtain insight into utilization of intramolecular charge transfer properties for molecular devices. 1',1’’’-Biferrocenediboronic acid was newly synthesized and chemically oxidized to afford a 1D hydrogen-bonded chain of valence-detrapped biferrocenium species in the solid state. A Biferrocene dimer was also prepared as a covalent assembly, exhibiting inter-biferrocenyl interactions derived from electrostatic repulsions in its solution.
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