Construction of supramolecular multi-ferrocenyl assemblies toward molecular devices using intramolecular charge distributions as information
| Project/Area Number |
25790016
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
Tahara Keishiro 奈良先端科学技術大学院大学, 物質創成科学研究科, 助教 (50622297)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | フェロセン / 超分子 / 分子内電荷移動 / ビフェロセニウム / 水素結合 / 原子価互変異性 / ビフェロセン / 組織体 / 原子価間電荷移動 / カテコール / ボレート / 混合原子価 |
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| Outline of Final Research Achievements |
Covalent and non-covalent assemblies were constructed from multi-ferrocenyl complexes as building blocks to obtain insight into utilization of intramolecular charge transfer properties for molecular devices. 1',1’’’-Biferrocenediboronic acid was newly synthesized and chemically oxidized to afford a 1D hydrogen-bonded chain of valence-detrapped biferrocenium species in the solid state. A Biferrocene dimer was also prepared as a covalent assembly, exhibiting inter-biferrocenyl interactions derived from electrostatic repulsions in its solution.
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Report
(4 results)
Research Products
(18 results)
