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Fundamental study of green EUV lithography using natural polysaccharide for the use of pure water in developable process

Research Project

Project/Area Number 25790036
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nano/Microsystems
Research InstitutionToyama Prefectural University

Principal Investigator

TAKEI SATOSHI  富山県立大学, 工学部, 准教授 (90580069)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords水溶性 / 微細加工 / 極端紫外光 / 電子線 / リソグラフィ / 水現像 / バイオマス / 糖鎖 / レジスト / 感光性 / 植物の高度利用 / デンプン / 植物
Outline of Final Research Achievements

An approach of natural polysaccharide to green resist polymers in extreme-ultraviolet (EUV) and electron beam (EB) lithography has successfully achieved for the use of pure water in the developable process, instead of conventionally used tetramethylammonium hydroxide and organic solvents. The green resist material with adjusted weight-average molecular weight and hydroxyl groups as a water-developable property was found to have the acceptable properties such as spin-coating properties on 200 mm wafer, prediction sensitivities of EUV at the wavelength of 6.7 and 13.5 nm, a high contrast of water dissolution rate before and after EB irradiation, and pillar patterns with 100-400 nm in high EB sensitivity of 7 µC/cm2.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 1 results,  Acknowledgement Compliant: 5 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] テキサス大学/NNIN(米国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] “Inedible cellulose-based biomass resist material amenable to water-based processing for use in electron beam lithography2015

    • Author(s)
      Satoshi Takei, Hirotaka Maki, Kigen Sugahara, Kenta Ito, and Makoto Hanabata
    • Journal Title

      AIP adv.

      Volume: 5

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Ultraviolet nanoimprint lithography using cyclodextrin-based porous template for pattern failure reduction2015

    • Author(s)
      Satoshi Takei and Makoto Hanabata
    • Journal Title

      Appl. Phys. Lett.

      Volume: 107

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanomorphology of polymer blends for a light-scattering thermosetting plate based on self-assembly2015

    • Author(s)
      Satoshi Takei, Yoshiyuki Yokoyama, Makoto Hanabata
    • Journal Title

      Macromolecular Materials and Engineering

      Volume: 300 Pages: 730-736

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Restricted diffusion of guest molecules in polymer thin films on solid substrates as revealed by three-dimensional single-molecule tracking2015

    • Author(s)
      Syoji Ito, Yuhei Taga, Kengo Hiratsuka, Satoshi Takei, Daichi Kitagawa, Seiya Kobatake and
    • Journal Title

      Chem. Commun.

      Volume: 51 Pages: 13756-13759

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Eco-friendly, water-repellent, light-transparent film derived from psicose using nanoimprint lithography2015

    • Author(s)
      Satoshi Takei, Makoto Hanabata
    • Journal Title

      Materials Lett.

      Volume: 143 Pages: 197-200

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Approach of natural polysaccharide to green resist polymers for EUV lithography2014

    • Author(s)
      Satoshi Takei, Akihiro Oshima, Tomoko G. Oyama, Kenta Ito, Kigenn Sugahara, Miki Kashiwakura, Takahiro Kozawa, Seiichi Tagawa, Makoto Hanabata
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Pages: 116505-116505

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Planarizing material for reverse-tne step and flash imprint lithography2014

    • Author(s)
      Tsuyoshi Ogawa, B. Michael Jacobsson, Ryan Deschner, William Bell, Michael W. Lin, Yuji Hagiwara, Satoshi Takei, Makoto Hanabata, and C. Grant Willson
    • Journal Title

      J. Micro/Nanolithogr. MEMS MOEMS

      Volume: 13 Pages: 031302-031302

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Organic solvent-free water-developable sugar resist material derived from biomass in green lithography2014

    • Author(s)
      32. Satoshi Takei, Akihiro Oshima, Takumi Ichikawa, Atsushi Sekiguchi, Miki Kashiwakura, Takahiro Kozawa, Seiichi Tagawa, Tomoko G. Oyama, Syoji Ito and Hiroshi Miyasaka
    • Journal Title

      Microelectron. Eng.

      Volume: 印刷中

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] EB and EUV lithography using inedible cellulose-based biomass resist material2016

    • Author(s)
      Satoshi Takei, Makoto Hanabata, Akihiro Oshima, Miki Kashiwakura, Takahiro Kozawa, and Seiichi Tagawa
    • Organizer
      SPIE
    • Place of Presentation
      サンノゼ、アメリカ
    • Year and Date
      2016-02-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoimprint lithography using disposable biomass template2016

    • Author(s)
      Makoto Hanabata, Satoshi Takei, Kigen Sugahara, Shinya Nakajima, Naoto Sugino, Takao Kameda, Jiro Fukushima, Yoko Matsumoto, Atsushi Sekiguchi
    • Organizer
      SPIE
    • Place of Presentation
      サンノゼ、アメリカ
    • Year and Date
      2016-02-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Green lithography using water-developable sugar-based negative resist materials2015

    • Author(s)
      Satoshi Takei, Makoto Hanabata, Kigen Sugahara, Naoto Sugino, Takao Kameda, Jiro Fukushima
    • Organizer
      MRS
    • Place of Presentation
      ボストン、アメリカ
    • Year and Date
      2015-11-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoimprint lithography using TiO2-SiO2 ultraviolet curable materials2015

    • Author(s)
      Satoshi Takei
    • Organizer
      SPIE
    • Place of Presentation
      プラハ、チョコ
    • Year and Date
      2015-04-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoimprint lithography for green water-repellent film derived from biomass with high-light transparency2015

    • Author(s)
      Satoshi Takei
    • Organizer
      Proc. SPIE
    • Place of Presentation
      San Jose USA
    • Year and Date
      2015-02-22 – 2015-02-26
    • Related Report
      2014 Research-status Report
  • [Presentation] High-sensitivity green resist material with organic solvent-free spin-coating and tetramethylammonium hydroxide-free water-developable processes for EB and EUV lithography2015

    • Author(s)
      Satoshi Takei
    • Organizer
      Proc. SPIE
    • Place of Presentation
      San Jose USA
    • Year and Date
      2015-02-22 – 2015-02-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 光・電子機能性材料の開発2015

    • Author(s)
      竹井 敏
    • Organizer
      高分子学会北陸支部
    • Place of Presentation
      富山
    • Year and Date
      2015-02-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] グリーンリソグラフィを用いた植物系機能性材料の開発2015

    • Author(s)
      竹井 敏
    • Organizer
      Nano tech 2015 第14回 国際ナノテクノロジー総合展・技術会議
    • Place of Presentation
      東京
    • Year and Date
      2015-01-28 – 2015-01-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 水溶性微細加工用レジスト材料の極端紫外光EUV応答システムの開発2015

    • Author(s)
      竹井 敏
    • Organizer
      新学術領域研究「高次複合光応答分子システムの開拓と学理の構築 第二回シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2015-01-24
    • Related Report
      2014 Research-status Report
  • [Presentation] バイオマス原料を用いた微細加工用レジスト材料の開発2014

    • Author(s)
      竹井 敏
    • Organizer
      富山県新世紀産業機構 とやまナノテク国際シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2014-12-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 高植物由来率のナノ微細加工用フィルム材料2014

    • Author(s)
      竹井 敏
    • Organizer
      第37回UV/EB研究会、大阪ニュークリアサイエンス協会
    • Place of Presentation
      大阪
    • Year and Date
      2014-09-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Organic solvent-free sugar-based nanopatterning transparency material derived from biomass for eco-friendly optical biochips using green lithography2014

    • Author(s)
      Satoshi Takei
    • Organizer
      Proc. SPIE
    • Place of Presentation
      brussels belgium
    • Year and Date
      2014-04-13 – 2014-04-17
    • Related Report
      2014 Research-status Report
  • [Presentation] Approach of pullulan derivatives to resist polymers for green lithography in eco-friendly optical NEMS and MEMS2014

    • Author(s)
      Satoshi Takei
    • Organizer
      Proc. SPIE
    • Place of Presentation
      brussels belgium
    • Year and Date
      2014-04-13 – 2014-04-17
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of green resist material derived from biomass for EUV lithography2013

    • Author(s)
      43. Satoshi Takei, Akihiro Oshima, Tomoko G. Oyama, Takumi Ichikawa, Miki Kashiwakura, Takahiro Kozawa, and Seiichi Tagawa
    • Organizer
      The 4th Organic and Inorganic Electronic Materials and Related Nanotechnologies EM-NANO
    • Place of Presentation
      Kanazawa
    • Related Report
      2013 Research-status Report
  • [Presentation] Fundamental study on green resist materials of extreme ultraviolet

    • Author(s)
      Satoshi Takei
    • Organizer
      ASME
    • Place of Presentation
      Toyama
    • Related Report
      2013 Research-status Report
  • [Book] 水溶性高分子の最新動向2015

    • Author(s)
      竹井 敏(分担執筆)
    • Total Pages
      11
    • Publisher
      ㈱シーエムシー出版
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] テンプレート形成用重合性化合物及びその硬化性組成物並びにその硬化物2016

    • Inventor(s)
      40 竹井 敏、花畑 誠
    • Industrial Property Rights Holder
      40 竹井 敏、花畑 誠
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-028091
    • Filing Date
      2016-02-17
    • Related Report
      2015 Annual Research Report

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Published: 2014-07-25   Modified: 2022-01-27  

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