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Analysis of charge-carrier injection at molecular orientation-controlled interfaces

Research Project

Project/Area Number 25790040
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Applied materials
Research InstitutionKyushu University

Principal Investigator

MATSUSHIMA Toshinori  九州大学, 最先端有機光エレクトロニクス研究センター, 准教授 (40521985)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords分子配向 / イオン化ポテンシャル / キャリア移動度 / 有機太陽電池 / 表面ダイポール / 開放電圧 / 冷間等方圧加圧 / 熱間等方圧加圧
Outline of Final Research Achievements

Control of molecular orientation led to an enhancement in light absorption, carrier mobilities, exciton diffusion lengths, and HOMO-LUMO differences, resulting in a significant enhancement in organic solar cell efficiencies three times. Cold isostatic pressing of an H2PC film was found to enhance its hole mobility 2000 times as well as performances of organic light-emitting diodes, organic thin film transistors, and organic solar cells. Operation of organic transistors containing organic powder compressed with hot isostatic pressing as a semiconductor was demonstrated to be possible. Hot isostatic pressing of organic-inorganic perovskite layers was very effective for improving perovskite film morphology and enhancing solar cell characteristics.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (32 results)

All 2015 2014 2013

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (23 results) (of which Invited: 5 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Introduction of Oxygen into Organic Thin Films with the Aim of Suppressing Singlet-Triplet Annihilation2015

    • Author(s)
      Munetomo Inoue, Toshinori Matsushima, Hajime Nakanotani, and Chihaya Adachi
    • Journal Title

      Chemical Physics Letters

      Volume: 624 Pages: 43-46

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exciton Quenching Behavior of Thermally Activated Delayed Fluorescence Molecules by Charge Carriers2015

    • Author(s)
      Atula S. D. Sandanayaka, Kou Yoshida, Toshinori Matsushima, and Chihaya Adachi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: in press Issue: 14 Pages: 7631-7636

    • DOI

      10.1021/acs.jpcc.5b01314

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical second harmonic generation phase measurement at interfaces of some organic2014

    • Author(s)
      Siti Zulaikha Ngah Demon, Yoshihiro Miyauchi, Goro Mizutani, Toshinori Matsushima,
    • Journal Title

      Applied Surface Science

      Volume: 311 Pages: 715-720

    • DOI

      10.1016/j.apsusc.2014.05.142

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of the electrical characteristics of metal-free phthalocyanine films using cold isostatic pressing2014

    • Author(s)
      Toshinori Matsushima,* Yu Esaki and Chihaya Adachi*
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 24 Pages: 243301-243301

    • DOI

      10.1063/1.4904463

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Ultraviolet Light Responsivity of a Pentacene Phototransistor by Introducing Photoactive Molecules into a Gate Dielectric2014

    • Author(s)
      Toan Thanh Dao, Toshinori Matsushima, Motonobu Murakami, Kei Ohkubo, Shunichi Fukuzumi, and Hideyuki Murata
    • Journal Title

      Japanese Journal of Applied. Physics

      Volume: 53

    • NAID

      120005652016

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Horizontally oriented molecular thin films for application in organic solar cells2014

    • Author(s)
      Toshinori Matsushima, Hitoshi Matsuo, Tetsuo Yamamoto, Akichika Nakao, Hideyuki Murata
    • Journal Title

      Solar Energy Materials & Solar Cells

      Volume: 123 Pages: 81-91

    • NAID

      120005694518

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controllable threshold voltage of a pentacene field-effect transistor based on a double-dielectric structure2013

    • Author(s)
      Toan Thanh Dao, Toshinori Matsushima, Hideyuki Murata
    • Journal Title

      Organic Electronics

      Volume: 14 Pages: 2007-2013

    • NAID

      120005367936

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge transfer-induced horizontal orientation of organic molecules near transition metal oxide surfaces2013

    • Author(s)
      Toshinori Matsushima and Hideyuki Murata
    • Journal Title

      Organic Electronics

      Volume: 14 Pages: 1149-1156

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 圧縮粉末を用いた有機トランジスタ2015

    • Author(s)
      松島敏則,江崎有,安達千波矢
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Exciton Quenching of Thermally Activated Delayed Fluorescence Molecules2015

    • Author(s)
      Atula S. D. Sandanayaka, T. Matsushima, and C. Adachi
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Efficient and Stable Solution-Processed Planar Perovskite Solar Cells2015

    • Author(s)
      Chuanjiang Qin, T. Matsushima, C. Adachi
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機薄膜への酸素の導入によるSinglet-Triplet Annihilationの抑制2015

    • Author(s)
      井上 棟智、松島 敏則、安達 千波矢
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ微細構造OLEDを用いたSinglet-Polaron Annihilationの抑制2015

    • Author(s)
      新田 篤志、桑江 博之、吉田 功、井上 棟智、松島 敏則、水野 潤、安達 千波矢
    • Organizer
      2015年 第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機ELの基礎と最近の研究動向2014

    • Author(s)
      松島敏則、中野谷一、安達千波矢
    • Organizer
      2014年 応用物理学会九州支部 特別共通セミナー「有機エレクトロニクスの最前線」
    • Place of Presentation
      大分大学
    • Year and Date
      2014-12-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 冷間等方圧加圧による有機薄膜の電気伝導性の向上2014

    • Author(s)
      江崎有, 松島敏則,安達千波矢
    • Organizer
      「有機EL討論会」第19回例会
    • Place of Presentation
      沖縄県市町村自治会館
    • Year and Date
      2014-11-27 – 2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Cold isostatic pressing as an effective method to enhance electrical properties of organic films2014

    • Author(s)
      Toshinori Matsushima, Yuu Esaki, and Chihaya Adachi
    • Organizer
      The 6th Asian Conference on Organic Electronics 2014 (A-COE 2014)
    • Place of Presentation
      台湾
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Introduction of oxygen into solid-state organic films to suppress singlet-triplet annihilation2014

    • Author(s)
      Munetomo Inoue, Toshinori Matsushima, Hajime Nakanotani, and Chihaya Adachi
    • Organizer
      The 6th Asian Conference on Organic Electronics 2014 (A-COE 2014)
    • Place of Presentation
      台湾
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Near Ultraviolet Organic Light-emitting Diodes with a Wide Bandgap Semiconductor of carbazole derivative for Optoelectronics2014

    • Author(s)
      Toan Thanh Dao, Toshinori Matsushima, and Hideyuki Murata
    • Organizer
      International Symposium on Nano - materials, Technology and Applications
    • Place of Presentation
      ベトナム
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 冷間等方圧加圧による有機薄膜の電気伝導性の向上2014

    • Author(s)
      松島敏則,江崎有, 安達千波矢
    • Organizer
      2014年 第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分子配向によるキャリア注入・輸送制御2014

    • Author(s)
      松島敏則
    • Organizer
      第9回有機デバイス院生研究会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-06-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] SHG分光法による劣化有機EL素子の評価に関する研究2014

    • Author(s)
      伊原知幸, Siti Zulaikha NGAHDEMON, 松本一樹, Muhammad Samir Ullah, 水谷五郎, 松島敏則, 村田英幸
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Influence of charge transfer-induced molecular orientation on charge injection and transport of organic devices2013

    • Author(s)
      Toshinori Matsushima and Hideyuki Murata
    • Organizer
      International Symposium on Optics & Photonics 2013, co-located with SPIE’s Annual Meeting
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 分子配向によるキャリア注入制御2013

    • Author(s)
      松島 敏則,村田 英幸
    • Organizer
      有機EL討論会第17回例会
    • Place of Presentation
      朱鷺メッセ, 新潟県
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Study of ITO/Organic Interfaces by Optical Second Harmonic Generation (SHG) Phase Measurement2013

    • Author(s)
      S.Z.N. Demon, Y. Miyauchi, G. Mizutani, T. Matsushima and H. Murata
    • Organizer
      The 9th International Symposium on Atomic Level Characterizations for New Materials and Devices 2013
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Study of ITO/organic Interfaces by Optical Second Harmonic Generation Phase Measurement2013

    • Author(s)
      Siti Zulaikha Ngah Demon, Yoshihiro Miyauchi, Goro Mizutani, Toshinori Matsushima, and Hideyuki Murata
    • Organizer
      the JAIST International Symposium
    • Place of Presentation
      JAIST, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Enhancement of UV light responsivity of a pentacene phototransistor by introducing photoactive molecules into gate dielectric2013

    • Author(s)
      Toan Thanh Dao, Toshinori Matsushima, Motonobu Murakami, Kei Ohkubo, Shunichi Fukuzumi, and Hideyuki Murata
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      Kanazawa, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Study of the ITO/Organic Interfacesby Optical Second Harmonic Generation (SHG)2013

    • Author(s)
      Siti Zulaikha NGAH DEMON, Yoshihiro MIYAUCHI, Goro MIZUTANI, Toshinori MATSUSHIMA and Hideyuki MURATA
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      Kanazawa, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Charge transfer-induced horizontal orientation of organic molecules near transition metal oxide surfaces2013

    • Author(s)
      Toshinori Matsushima and Hideyuki Murata
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      Kanazawa, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Interface of indium tin oxide with organic semiconductor by optical second harmonic generation phase measurement2013

    • Author(s)
      Siti Zulaikha Ngah Demon, Yoshihiro Miyauchi, Goro Mizutani, Toshinori Matsushima, and Hideyuki Murata
    • Organizer
      平成25年度 応用物理学会 北陸・信越支部 学術講演会
    • Place of Presentation
      金沢工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機薄膜の密度分布解析2013

    • Author(s)
      松島 敏則,村田 英幸
    • Organizer
      有機EL討論会第17回例会
    • Place of Presentation
      朱鷺メッセ, 新潟県
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機薄膜の密度とキャリア移動度の相関2013

    • Author(s)
      松島 敏則、Atula S. D. Sandanayaka、村田 英幸
    • Organizer
      有機EL討論会第16回例会
    • Place of Presentation
      日本科学未来館
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 有機半導体素子の製造方法および有機半導体素子2014

    • Inventor(s)
      松島敏則, 江崎有, 安達千波矢
    • Industrial Property Rights Holder
      松島敏則, 江崎有, 安達千波矢
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-175177
    • Filing Date
      2014-08-29
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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