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Fabrication of ferroelectric tunnelling junction memory using ferroelectric polymer ultrathin film

Research Project

Project/Area Number 25790053
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo University of Science (2014)
Tohoku University (2013)

Principal Investigator

NAKAJIMA Takashi  東京理科大学, 理学部, 講師 (60516483)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords強誘電体薄膜 / 高分子 / 抵抗変化 / 不揮発性メモリ / 高分子強誘電体 / 超薄膜 / トンネル伝導
Outline of Final Research Achievements

In this project, the research has been done for understanding a polarization-induced resistive switching phenomenon in ferroelectrics and establishing a nonvolatile memory. We observed a clear polarization reversal-induced resistance switching effect in ferroelectric Vinylidene-fluoride (VDF)/Trifluoroethylene (TrFE) copolymer thin films. Pt and Au were used as the bottom and top electrodes, respectively, and the thickness of the VDF/TrFE copolymer film was adjusted to be 10 nm. The conduction current was 100 times higher in the case of the spontaneous polarization of the VDF/TrFE film towards the Au electrode than that in the case of the opposite direction. This resistance switching was confirmed to be reproducible after 10 successive polarization reversals. Thus, we concluded that the film based on the structure can work as a novel resistive switching memory.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (19 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (15 results) (of which Invited: 3 results) Remarks (1 results)

  • [Journal Article] High-Symmetry Polarization Domains in Low-Symmetry Ferroelectrics2014

    • Author(s)
      I. Lukyanchuk, P. Sharma, T. Nakajima, S. Okamura, J. F. Scott, and A. Gruverman
    • Journal Title

      Nano Lett.

      Volume: 14 Issue: 12 Pages: 6931-6935

    • DOI

      10.1021/nl503070f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polarization induced resistance switching effect in ferroelectric vinylidenefluoride/trifluoroethylene copolymer ultrathin films2014

    • Author(s)
      S. Usui, T. Nakajima, Y. Hashizume, and S. Okamura
    • Journal Title

      Appl. Phys. Lett.

      Volume: 105 Issue: 16

    • DOI

      10.1063/1.4900490

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferroelectric Properties of Vinylidene Fluoride-Trifluoroethylene Copolymer Thin Films Fabricated on Amorphous Alloy Electrode2014

    • Author(s)
      T. Nakajima, S. Yamaura, T Furukawa, and S. Okamura
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 9S Pages: 09PC05-09PC05

    • DOI

      10.7567/jjap.53.09pc05

    • NAID

      210000144500

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高分子強誘電体VDF/TeFE共重合体薄膜の分極反転特性2015

    • Author(s)
      中川佑太,橋爪洋一郎,中嶋宇史,岡村総一郎
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川・東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structures and Ferroelectric Properties of VDF/TeFE Copolymer Thin Films Crystallized from Molten Phase2014

    • Author(s)
      Y. Nakagawa, Y. Hashizume, T. Nakajima, and S. Okamura
    • Organizer
      The 6th China-Japan Symposium on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Yamanashi/Hotel Kofukaku Kuwarubi
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] VDF/TrFE共重合体超薄膜における分極誘起抵抗変化効果に対する電極の影響2014

    • Author(s)
      臼井翔吾、中嶋宇史、橋爪洋一郎、岡村総一郎
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道・北海道大
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 低Tcフッ化ビニリデン/三フッ化エチレン共重合体薄膜の結晶化挙動と強誘電特性2014

    • Author(s)
      中嶋宇史、山浦真一、古川猛夫、岡村総一郎
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道・北海道大
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高分子強誘電体材料の機能物性とデバイス展開2014

    • Author(s)
      中嶋宇史
    • Organizer
      第277回応用セラミックス研究所講演会(第一回材料構造講演会)
    • Place of Presentation
      東京・東京工業大
    • Year and Date
      2014-08-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 強誘電性ポリマー薄膜の極限物性とメモリデバイスへの応用展開2014

    • Author(s)
      中嶋宇史
    • Organizer
      日本半導体技術ロードマップ専門委員会(STRJ)講演会
    • Place of Presentation
      東京・東京大
    • Year and Date
      2014-07-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] フッ素系高分子強誘電体材料・デバイスの新たな展開2014

    • Author(s)
      中嶋宇史
    • Organizer
      電気学会電子回路技術委員会主催第43回EMシンポジウム
    • Place of Presentation
      東京・東京理科大
    • Year and Date
      2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] アモルファス合金電極上に形成されたVDF/TrFE共重合体極薄膜の強誘電性2014

    • Author(s)
      中嶋宇史、阿部克博、山浦真一、岡村総一郎
    • Organizer
      第31回強誘電体応用会議
    • Place of Presentation
      京都・コープイン京都
    • Year and Date
      2014-05-28 – 2014-05-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶融状態から形成されたVDF/TeFE共重合体薄膜の微構造と強誘電特性2014

    • Author(s)
      中川佑太、橋爪洋一郎、中嶋宇史、古川猛夫、岡村総一郎
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学、神奈川
    • Related Report
      2013 Research-status Report
  • [Presentation] 強誘電性ポリマー材料・デバイスの新展開2014

    • Author(s)
      中嶋宇史
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学、神奈川
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Ferroelectric Properties of Ultrathin VDF/TrFE Copolymer Films Fabricated on Amorphous PdCuSi Electrode2013

    • Author(s)
      T. Nakajima, K. Abe, S. Okamura, S. Yamaura
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      石川県立音楽堂、石川
    • Related Report
      2013 Research-status Report
  • [Presentation] Polarization Switching Characteristics of Ferroelectric VDF/TrFE Copolymer Fabricated on Metallic Glass Thin Film2013

    • Author(s)
      T. Nakajima, K. Abe, S. Okamura and S. Yamaura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学、京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Control of Higher Order Structures of VDF/TeFE Copolymer Thin Films and Their Ferroelectric Properties2013

    • Author(s)
      Y. Nakagawa, H. Ishii, Y. Hashizume, T. Nakajima, T. Furukawa and S.Okamura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学、京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of FTJ devices using ultrathin VDF/TrFE copolymer2013

    • Author(s)
      S. Usui, T. Nakajima, Y. Hashizume, T. Furukawa and S.Okamura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学、京都
    • Related Report
      2013 Research-status Report
  • [Presentation] 強誘電体障壁をもちいた全非磁性トンネル接合のスイッチング特性

    • Author(s)
      中嶋宇史、臼井翔吾、古川猛夫、岡村総一郎
    • Organizer
      2014年Bi系マルチフェロイクス研究会
    • Place of Presentation
      東北大学、仙台
    • Related Report
      2013 Research-status Report
  • [Remarks] 東京理科大学岡村・中嶋研究室

    • URL

      http://www.rs.kagu.tus.ac.jp/sokamura/index.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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