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Synthesis and characterization of half-metallic antiferromagnetic materials by atomic-layer control

Research Project

Project/Area Number 25790054
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionThe University of Tokyo

Principal Investigator

CHIKAMATSU Akira  東京大学, 理学(系)研究科(研究院), 助教 (40528048)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords薄膜・表面界面物性 / 酸化物エレクトロニクス / 薄膜新材料 / スピンエレクトロニクス / 表面界面物性 / 結晶成長 / エピタキシャル / 物性実験
Outline of Final Research Achievements

Half-metallic antiferromagnet (HMAF) compounds have been theoretically predicted in many structural systems by first-principles calculations, but none of them could be experimentally synthesized thus far. In this study, epitaxial thin films of LaSrVMoO6 and Cr-doped SrRuO3, which are predicted to be possible HMAF candidates, were fabricated by pulsed-laser deposition method, and investigated their physical properties and electronic states. It was found that the resistivity of the fabricated LaSrVMoO6 thin films was lower than that of the polycrystalline samples. In particular, the resistivity at 5 K of the LaSrVMoO6 thin films showed 2×10-4 Ω cm, being due to the improvement in the crystallinity and the ordering of V and Mo ions. It was also found that in the SrRu0.9Cr0.1O3 films, the Cr 3dt2g orbital is strongly hybridized with the Ru 4dt2g one. Furthermore, the perfect B-site ordered Sr2MgMoO6 epitaxial thin films, which can be used as a seed layer, were successfully fabricated.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (11 results)

All 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (6 results) (of which Invited: 2 results)

  • [Journal Article] Topotactic reductive fluorination of strontium cobalt oxide epitaxial thin films2015

    • Author(s)
      片山司、近松彰、広瀬靖、福村知昭、長谷川哲也
    • Journal Title

      Journal of Sol-Gel Science and Technology

      Volume: 73 Issue: 3 Pages: 527-530

    • DOI

      10.1007/s10971-014-3499-x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metallic transport and large anomalous Hall effect at room temperature in ferrimagnetic Mn4N epitaxial thin film2014

    • Author(s)
      X. Shen, A. Chikamatsu, K. Shigematsu, Y. Hirose, T. Fukumura and T. Hasegawa
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 7

    • DOI

      10.1063/1.4893732

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Sr2MgMoO6-δ thin films fabricated using pulsed-laser deposition with high concentrations of oxygen vacancies2014

    • Author(s)
      K. Shigematsu, A. Chikamatsu, T. Fukumura, S. Toyoda, E. Ikenaga and T. Hasegawa
    • Journal Title

      Applied Physics Letters

      Volume: 104 Issue: 26

    • DOI

      10.1063/1.4886136

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Topotactic fluorination of strontium iron oxide thin films using polyvinylidene fluoride2014

    • Author(s)
      片山司、近松彰、広瀬靖、高木亮介、神坂英幸、福村知昭、長谷川哲也
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 2 Issue: 27 Pages: 5350-5356

    • DOI

      10.1039/c4tc00558a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metallic conductivity in infinite-layer strontium iron oxide thin films reduced by calcium hydride2014

    • Author(s)
      T. Katayama, A. Chikamatsu, Y. Hirose, H. Kumigashira, T. Fukumura, and T. Hasegawa
    • Journal Title

      Journal of Physics D: Appllied Physics

      Volume: 47 Issue: 13 Pages: 135304-135304

    • DOI

      10.1088/0022-3727/47/13/135304

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] SrRu0.5Cr0.5O3エピタキシャル薄膜の作製及び物性評価2015

    • Author(s)
      山田 佳補,近松 彰,重松 圭,福村 知昭,長谷川 哲也
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] トポタクティック合成法による酸化物薄膜へのアニオンドープ2015

    • Author(s)
      近松 彰
    • Organizer
      放射光セミナー
    • Place of Presentation
      東京大学物性研究所
    • Year and Date
      2015-01-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Srn+1RunO3n+1 薄膜へのポリフッ化ビニリデンによるトポタクティックフッ素ドープ2014

    • Author(s)
      河原 佳祐,近松 彰,片山 司,小野塚 智也,福村 知昭,長谷川 哲也
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素ドープに伴うNdNiO3薄膜の構造変化2014

    • Author(s)
      小野塚 智也,近松 彰,片山 司,福村 知昭,長谷川 哲也
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペロブスカイト構造を有するコバルト系ヒドリド酸化物薄膜の作製2014

    • Author(s)
      片山 司,近松 彰,神坂 英幸,廣瀬 靖,福村 知昭,長谷川 哲也
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Topotactic reaction of iron oxide thin films2014

    • Author(s)
      A. Chikamatsu, T. Katayama, Y. Hirose, H. Kamisaka, T. Fukumura, and T. Hasegawa
    • Organizer
      2014 Collaborative Conference on Materials Research
    • Place of Presentation
      Incheon/Seoul, South Korea
    • Year and Date
      2014-06-25
    • Related Report
      2014 Annual Research Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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