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Isotopic fractionation of alkaline earth metals in carbonate samples

Research Project

Project/Area Number 25800301
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Geochemistry/Cosmochemistry
Research InstitutionGakushuin University

Principal Investigator

Ohno Takeshi  学習院大学, 理学部, 助教 (40452007)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords同位体分別 / 金属元素 / 炭酸塩鉱物 / MC-ICP-MS / 炭酸塩 / マグネシウム / カルシウム / ストロンチウム
Outline of Final Research Achievements

Carbonate precipitation experiments indicate the degree of isotopic fractionation of metal elements during the precipitation can be used as a new paleoenvironmental proxy. To investigate the relationship between the crystal structure and the degree of isotopic fractionation of alkaline earth metals, Mg K-edge XANES measurements were performed. As a result, it is revealed that the local structure around Mg atoms in calcite is different from that of aragonite, suggesting that the crystal structure of calcium carbonate can affect the degree of Mg isotopic fractionation.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (11 results)

All 2015 2014 2013

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (5 results) (of which Invited: 1 results)

  • [Journal Article] Accumulation of 137Cs by rice grown in four types of soil contaminated by Fukushima Dai-ichi Nuclear Power Plant accident in 2011 and 20122015

    • Author(s)
      Shigeto Fujimura, Yasuyuki Muratastu, Takeshi Ohno, Masaaki Saitou, Yasukazu Suzuki, Tmoyuki Kobayashi, Yoshikatsu Ueda, Kunio Yoshioka
    • Journal Title

      Journal of Environmental Radioactivity

      Volume: 140 Pages: 59-64

    • DOI

      10.1016/j.jenvrad.2014.10.018

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Analysis of 129I in the soils of Fukushima Prefecture: Preliminary reconstruction of 131I deposition related to the accident at Fukushima Daiichi nuclear power plant2015

    • Author(s)
      Yasuyuki Muramatsu, Hiroyuki Matsuzaki, Chiaki Toyama, Takeshi Ohno
    • Journal Title

      Journal of Environmental Radioactivity

      Volume: 139 Pages: 347-351

    • DOI

      10.1016/j.jenvrad.2014.05.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The anomalous Ca cycle in the Ediacaran ocean: evidence from Ca isotopes preserved in carbonates in the Three Gorges area, South China2014

    • Author(s)
      Y. Sawaki, M. Tahata, T. Ohno, T. Komiya, T. Hirata, S. Maruyama, J. Han, D. Shu
    • Journal Title

      Gondwana Research

      Volume: 25 Issue: 3 Pages: 1070-1089

    • DOI

      10.1016/j.gr.2013.03.008

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 誘導結合プラズマ質量分析法における同位体分析技術の進歩と環境地球化学への応用2014

    • Author(s)
      大野 剛
    • Journal Title

      質量分析学会誌

      Volume: 62 Pages: 103-113

    • NAID

      130004705245

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Determination of radioactive cesium isotope ratios by Triple Quadrupole ICP-MS and its application to rainwater following the Fukushima Daiichi Nuclear Power Plant accident2014

    • Author(s)
      Takeshi Ohno, Yasuyuki Muramatsu
    • Journal Title

      Journal of Analytical Atomic Spectrometry

      Volume: 29 Issue: 2 Pages: 347-351

    • DOI

      10.1039/c3ja50291k

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Determination of ultratrace 129I in soil samples by Triple Quadrupole ICP-MS and its application to Fukushima soil samples2013

    • Author(s)
      Takeshi Ohno, Yasuyuki Muramatsu, Yasuyuki Shikamori, Chiaki Toyama, Nobuaki Okabe, Hiroyuki Matsuzaki
    • Journal Title

      Journal of Analytical Atomic Spectrometry

      Volume: 28 Issue: 8 Pages: 1283-1287

    • DOI

      10.1039/c3ja50121c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 炭酸塩鉱物沈澱反応におけるマグネシウム同位体分別とXAFS法による局所構造解析2015

    • Author(s)
      柵木彩花、肆矢俊浩、大野剛、小川雅裕、山川庸芝明、高橋嘉夫
    • Organizer
      2015年日本地球化学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Isotopic fractionation of alkali earth metals during carbonate precipitation2014

    • Author(s)
      Toshihiro Yotsuya, Takeshi Ohno, Gen Shimoda, Kosuke Goto, Yasuyuki Muramatsu
    • Organizer
      AGU Fall Meeting
    • Place of Presentation
      San Francisco
    • Year and Date
      2014-12-15 – 2014-12-19
    • Related Report
      2014 Research-status Report
  • [Presentation] 炭酸塩鉱物沈殿反応におけるアルカリ土類金属元素同位体分別2014

    • Author(s)
      肆矢俊浩、大野剛、下田玄、後藤孝介、村松康行
    • Organizer
      日本地球化学会
    • Place of Presentation
      富山大学
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] セリウム・ネオジムの同位体分別と地球化学への応用2013

    • Author(s)
      大野 剛
    • Organizer
      2013年地球惑星科学連合大会
    • Place of Presentation
      千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] 無機質量分析計における質量差別効果とその補正法について2013

    • Author(s)
      大野 剛
    • Organizer
      第61回質量分析総合討論会
    • Place of Presentation
      茨城
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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