Study on the photochemical reacitivity of oraganotellurium, and its application for living radical polymerization
| Project/Area Number |
25810021
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | ラジカル反応 / ラジカル重合 / 光反応 / リビングラジカル重合 / テルル / 高分子反応 / 量子収率 / 高分子 / 制御重合 |
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| Outline of Final Research Achievements |
The reactivity of C-Te bond photolysis of variuos organotellurium compounds was studied, and the living radical polymerization employing these comounds was examined. The efficient radical generation from living polymer bearing organotellurium group at chain end under photoirradiation was utilized for the radical coupling reaction of polymers, and also the clarification of the mechanism of radical polymerization. Althoguh the living radical polymerization of vinyl acetate using organotellurium compounds was studied detaily, a higly controlled polymerization was not achieved as targeted.
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Report
(3 results)
Research Products
(11 results)
