Development of catalytic carbon-carbon bond forming reaction for making quaternary carbon with using organoborate salt
| Project/Area Number |
25810024
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
UEDA Mitsuhiro 大阪府立大学, 理学(系)研究科(研究院), 助教 (60566298)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 鈴木ー宮浦クロスカップリング反応 / 有機ボロン酸 / プロパルギルアセテート / 遷移金属非存在下 / カルボカチオン / 鈴木－宮浦クロスカップリング反応 / 酸触媒 / クロスカップリング反応 / 第二級プロパルギルアセテート |
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| Outline of Final Research Achievements |
The transition-metal catalyzed cross-coupling reaction with using organoboronic acids provides a magnificent tool for organic synthesis. With this method, we generally rely on the use of precious transition metals, such as palladium complexes, as the catalyst. In this time, we found that cross-coupling reaction of propargylic acetates with organoboronic acids proceeded to give the corresponding acetylenic products under metal-free conditions.
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Report
(3 results)
Research Products
(3 results)
