| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
We present a series of cyclic structures constructed from obliquely crossing rod segments, which have chirality based on the direction of the rods with respect to the molecular plane. This structure is called ‘Kumiigeta’. The chiral compounds of this type are expected to have novel and useful functions. Kumiigeta-compounds were synthesized using axially chiral binaphthyls and rod type compounds. Conformation and optical properties of them were analyzed by UV-Vis, CD spectra and quantum chemical calculations.
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