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Control of adsorption/desorption dynamics at the liquid/solid interface towards self-repairing molecular devices

Research Project

Project/Area Number 25810048
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionKyoto University

Principal Investigator

Hirose Takashi  京都大学, 工学(系)研究科(研究院), 助教 (30626867)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords協同的組織化 / 光応答性 / 走査型トンネル顕微鏡 / 固液界面 / ジアリールエテン / 走査トンネル顕微鏡
Outline of Final Research Achievements

In this study, we investigated the process of the molecular ordering formation at the liquid/solid interface and its photoresponsivility. Photochromic compounds that alter chemical structure upon photoirradiation were used as adsorbate to impart a photoresponsiveness to molecular orderings. The structure and arrangement of molecular ordering formed on a graphite substrate were observed at the single-molecule resolution using scanning tunneling microscopy.
Photochromic compounds bearing alkyl side chains linked via amide group has a unique ordering formation process and whose molecular ordering steeply grows at a critical concentration. By using such sharp concentration dependence of molecular ordering formation, photoresponsive molecular orderings with high photoresponsivility were successfully observed.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (41 results)

All 2016 2015 2014 2013 Other

All Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 8 results) Presentation (26 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Remarks (3 results)

  • [Journal Article] Fluorescence behavior of 5,10-disubstituted [5]helicene derivatives in solution and the effect of self-assembly on their radiative and non-radiative rate constants2016

    • Author(s)
      Takashi Hirose, Natsuki Ito, Hiromu Kubo, Tohru Sato, Kenji Matsuda
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 14 Pages: 2811-2819

    • DOI

      10.1039/c5tc03675e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rational Design of Highly Photoresponsive Surface-Confined Self-Assembly of Diarylethenes: Reversible Three-State Photoswitching at the Liquid/Solid Interface2016

    • Author(s)
      N. Maeda, T. Hirose, S. Yokoyama, K. Matsuda
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 17 Pages: 9317-9325

    • DOI

      10.1021/acs.jpcc.6b02115

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoinduced Four-State Three-Step Ordering Transformation of Photochromic Terthiophene at a Liquid/Solid Interface Based on Two Principles: Photochromism and Polymorphism2015

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Langmuir

      Volume: 31 Issue: 23 Pages: 6404-6414

    • DOI

      10.1021/acs.langmuir.5b01404

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface2015

    • Author(s)
      D. Frath, T. Sakano, Y. Imaizumi, S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 32 Pages: 11350-11358

    • DOI

      10.1002/chem.201500804

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] "Investigation into Surface-Confined Self-Assembly Stabilized via Hydrogen Bond of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage2015

    • Author(s)
      N. Nishitani, T. Hirose, K. Matsuda
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 9 Pages: 1926-1931

    • DOI

      10.1002/asia.201500453

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of Alkyl Chain Length and Hydrogen Bonds on the Cooperative Self-Assembly of 2-Thienyl-Type Diarylethenes at a Liquid/Highly Oriented Pyrolytic Graphite (HOPG) Interface2015

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 39 Pages: 13569-13576

    • DOI

      10.1002/chem.201500707

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triangulene Leuco Derivatives at the Ethanol/Au(111) Substrate2015

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 11 Pages: 1616-1618

    • DOI

      10.1246/cl.150738

    • NAID

      130005108094

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fluorescence Enhancement of Covalently Linked 1-Cyano-1,2-Diphenylethene Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants2015

    • Author(s)
      T. Hirose, Y. Tsunoi, Y. Fujimori, K. Matsuda
    • Journal Title

      Chemistry A European Journal

      Volume: 21 Issue: 4 Pages: 1637-1644

    • DOI

      10.1002/chem.201404745

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photochemical Cleavage of the Axial Group Attached to the Central Carbon Atom of Triazatriangulene2015

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 1 Pages: 76-78

    • DOI

      10.1246/cl.140897

    • NAID

      130004701544

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Facile Photochemical Synthesis of 5,10-Disubstituted [5]Helicenes by Removing Molecular Orbital Degeneracy2014

    • Author(s)
      N. Ito, T. Hirose, K. Matsuda
    • Journal Title

      Organic Letters

      Volume: 16 Issue: 9 Pages: 2502-2505

    • DOI

      10.1021/ol5008718

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phototriggered Formation and Disappearance of Surface-Confined Self-Assembly Composed of Photochromic 2-Thienyl-Type Diarylethene: A Cooperative Model at the Liquid/Solid Interface2014

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Journal Title

      Chemical Communications

      Volume: Advance Article Issue: 45 Pages: 5964-5966

    • DOI

      10.1039/c3cc48895k

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of Two-Dimensional Ordering of Diarylethene Annulated Isomer upon In Situ UV Irradiation at the Liquid/HOPG Interface2013

    • Author(s)
      T. Sakano, Y. Imaizumi, T. Hirose, K. Matsuda
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 12 Pages: 1537-1539

    • DOI

      10.1246/cl.130705

    • NAID

      130004867824

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] STM Investigation on Highly Photoresponsive Surface-Confined Self-Assembly of Photochromic Diarylethenes2016

    • Author(s)
      T. Hirose, S. Yokoyama, N. Maeda, N. Nishitani, D. Frath, K. Matsuda
    • Organizer
      Multi-Responsive Photochromes (MRP) Conference in Nantes
    • Place of Presentation
      Nantes (France)
    • Year and Date
      2016-04-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 溶液中における 5,10-二置換[5]ヘリセン誘導体の超分子組織化と発光増強特性の解析2016

    • Author(s)
      廣瀬崇至、伊藤夏輝、久保拓夢、佐藤徹、松田建児
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cooperative Self-Assemblies at the Liquid/solid Interface Controlled by Multidirectional Hydrogen Bond: STM Observation of Anisotropic Domai2016

    • Author(s)
      N. Nishitani, T. Hirose, K. Matsuda
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジアリールエテンが形成する分子配列の光応答性:高い協同性に基づく高感度な分子配列転移2016

    • Author(s)
      前田尚生、廣瀬崇至、松田建児
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測:協同的組織化モデルを用いた配列形成プロセスの解析2016

    • Author(s)
      廣瀬 崇至
    • Organizer
      第61回超分子創製化学セミナー
    • Place of Presentation
      立命館大学 薬学部(滋賀県・草津市)
    • Year and Date
      2016-01-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Photoresponsive Supramolecular Assemblies Composed of Photochromic Diarylethenes: Investigation of Concentration Dependence of Surface Coverage at a Liquid/Solid Interface Using a Nucleation–Growth Model2015

    • Author(s)
      T. Hirose, S. Yokoyama, D. Frath, T. Sakano, K. Matsuda
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Elongation-Type Self-Assembly at a Liquid/Solid Interface: Effect of Hydrogen Bond of Urea and Amide Groups2015

    • Author(s)
      N. Nishitani, T. Hirose, K. Matsuda
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      Rihga Royal Hotel KYOTO (京都府・京都市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ターアリーレン分子の熱および光異性化を利用した多刺激応答性二次元分子配列のSTM観察2015

    • Author(s)
      横山創一、廣瀬崇至、松田建児
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学(愛媛県・松山市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジアリールエテンが形成する光応答性二次元分子配列のSTM観察とチエニル基の置換位置依存性2015

    • Author(s)
      廣瀬崇至、前田尚生、横山創一、松田建児
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学(愛媛県・松山市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 第26回基礎有機化学討論会2015

    • Author(s)
      西谷暢彦、廣瀬崇至、松田建児
    • Organizer
      水素結合によって安定化された2次元分子配列のSTM観察:濃度に依存した表面被覆率の定量的評価
    • Place of Presentation
      愛媛大学・松山大学(愛媛県・松山市)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジアリールエテンが形成する分子配列のSTM観察とチエニル基の置換位置効果2015

    • Author(s)
      前田尚生、廣瀬崇至、松田建児
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学 杉本キャンパス(大阪府・大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水中および有機溶媒中における5,10-二置換[5]ヘリセン誘導体の自己集合と発光特性2015

    • Author(s)
      廣瀬崇至、伊藤夏輝、佐藤徹、松田建児
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学 杉本キャンパス(大阪府・大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] STM Observation of Surface-Confined Self-Assembly Stabilized via Hydrogen Bond of Urea and Amide Groups: Nucleation–Elongation Mechanism at a Liquid/Solid Interface2015

    • Author(s)
      N. Nishitani, T. Hirose, K. Matsuda
    • Organizer
      7th East Asia Symposium on Functional Dyes and Advanced Materials (EAS7)
    • Place of Presentation
      Osaka Prefecture University (大阪府・堺市)
    • Year and Date
      2015-09-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocontrol over Surface-Confined Self-Assembly Composed of Photochromic Diarylethenes: Cooperative Model at the Liquid/Solid Interface2015

    • Author(s)
      T. Hirose, S. Yokoyama, D. Frath, T. Sakano, K. Matsuda
    • Organizer
      16th International Symposium on Novel Aromatic Compounds (ISNA-16)
    • Place of Presentation
      Universidad Complutense de Madrid
    • Year and Date
      2015-07-05 – 2015-07-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Photocontrol over Surface-Confined Self-Assembly Composed of Photochromic Diarylethenes: Cooperative Model at the Liquid/Solid Interface2015

    • Author(s)
      T. Hirose, S. Yokoyama, D. Frath, T. Sakano, K. Matsuda
    • Organizer
      16th International Symposium on Novel Aromatic Compounds (ISNA-16)
    • Place of Presentation
      Madrid (Spain)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ウレア基とアミド基の水素結合に由来する協同的組織化挙動の固液界面におけるSTM 観察2015

    • Author(s)
      西谷暢彦、廣瀬崇至、松田建児
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス
    • Year and Date
      2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ジアリールエテンが形成する光応答性分子配列の STM 観察とチエニル基の置換位置依存性2015

    • Author(s)
      前田尚生、廣瀬崇至、松田建児
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス
    • Year and Date
      2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Mixing-Induced Cooperativity" Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface2015

    • Author(s)
      F. Denis, T. Sakano, Y. Imaizumi, S. Yokoyama, T. Hirose, K. Matsuda
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Photoresponsive 2-D Orderings of Diarylethenes at the Liquid/HOPG Interface: Correlation between Molecular Structure and Cooperative Parameter2015

    • Author(s)
      S. Yokoyama, T. Hirose, K. Matsuda
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] STM Observation of Phototriggered Formation and Disappearance of Molecular Orderings: A Cooperative Model on 2-D Surface2014

    • Author(s)
      T. Hirose
    • Organizer
      The 4th International Kyoto Symposium on Organic Nanostructures
    • Place of Presentation
      京都大学 桂キャンパス
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 固液界面におけるジアリールエテンの協同的分子配列形成の評価と配列形成・崩壊挙動の光制御2014

    • Author(s)
      横山創一、廣瀬崇至、松田建児
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-10-11
    • Related Report
      2014 Research-status Report
  • [Presentation] ウレア基を介した水素結合ネットワークを有する2次元配列のSTM観察と協同的組織化挙動2014

    • Author(s)
      西谷暢彦、廣瀬崇至、松田建児
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学 川内北キャンパス
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 固液界面におけるジアリールエテンの協同的組織化と配列形成・消失の光制御2014

    • Author(s)
      横山創一、廣瀬崇至、松田建児
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学 川内北キャンパス
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Phototriggered formation and disappearance of surface confined self-assembly of photochromic diarylethene: a cooperative model at the liquid/solid interface2014

    • Author(s)
      S. Yokoyama, T. Sakano, Y. Imaizumi, T. Hirose, K. Matsuda
    • Organizer
      9th Phenics International Network Symposium
    • Place of Presentation
      Bordeaux, France
    • Year and Date
      2014-07-18 – 2014-07-19
    • Related Report
      2014 Research-status Report
  • [Presentation] アミド基を介して二次元配列した2-チエニル型ジアリールエテンのSTM観察

    • Author(s)
      横山創一、廣瀬崇至、松田建児
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学 目白キャンパス(東京都豊島区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 固液界面におけるジアリールエテンの光応答性二次元配列形成と協同性モデルによる解析

    • Author(s)
      横山創一、廣瀬崇至、松田建児
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス(名古屋市千種区)
    • Related Report
      2013 Research-status Report
  • [Remarks] 京都大学工学研究科 松田研究室ホームページ

    • URL

      http://www.sbchem.kyoto-u.ac.jp/matsuda-lab/prof_hirose.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 京都大学工学研究科松田研究室ホームページ

    • URL

      http://www.sbchem.kyoto-u.ac.jp/matsuda-lab/prof_hirose.html

    • Related Report
      2014 Research-status Report
  • [Remarks] 京都大学工学研究科松田研究室ホームページ

    • URL

      http://www.sbchem.kyoto-u.ac.jp/matsuda-lab/prof_hirose.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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