Construction of Long-Lived Luminescent Iridium(III) Complexes Inducing by Hydrogen Bonding
| Project/Area Number |
25810052
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Waseda University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 金属錯体 / イリジウム / 発光 / 水素結合 / 発光性イリジウム錯体 |
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| Outline of Final Research Achievements |
Hydrogen bonding which is one of the intermolecular interaction has been considered hardly inducing the luminescent behavior of the compounds. In this project, I attempt the construction of the luminescent iridium(III) complexes having strong complementary dual hydrogen bonding. As the result of the measurement of the luminescent behavior of the obtained complexes, the quantum yield value of dimer complexes are twice as large as those of monomer complexes because of suppression of non-radiative process.
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Report
(4 results)
Research Products
(68 results)
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[Journal Article] Relative kinetic reactivities of boronic acids and boronate ions toward 1,2-diols.2014
Author(s)
Okamoto T, Tanaka A, Watanabe E, Miyazaki T, Sugaya T, Iwatsuki S, Inamo M, Takagi H D, Odani A, Ishihara K.
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Journal Title
Eur J Inorg Chem
Volume: 2014(14)
Issue: 14
Pages: 2389-2395
DOI
Related Report
Peer Reviewed
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[Journal Article] Universal Reaction Mechanism of Boronic Acid with Diol in Aqueous Solution, Based on Kinetics, and Basic Concept of Conditional Formation Constant2014
Author(s)
Furikado Y, Nagahata T, Okamoto T, Sugaya T, Iwatsuki S, Inamo M, Takagi H D, Odani A, Ishihara K
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Journal Title
Chem. Eur. J.
Volume: 20(41)
Issue: 41
Pages: 13194-13202
DOI
Related Report
Peer Reviewed
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