| Project/Area Number |
25810064
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
NAGANO TAKASHI 高知大学, 教育研究部自然科学系, 助教 (80500587)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 鉄触媒 / クロスカップリング / アリル位置換反応 / グリーンケミストリー / アレン |
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| Outline of Final Research Achievements |
As a part of our continuing studies on environmentally benign organic transformations, we have focused on inexpensive and abundant iron salt-catalyzed carbon-carbon bond forming reactions. In the course of this study, we have developed (i) iron-catalyzed Grignard cross-coupling via intramolecular cyclization, (ii) iron-catalyzed Grignard cross-coupling with allylic ethers (allylic substitution), and (iii) unprecedented cross-coupling of hard nucleophiles with 2-bromo-1,3-dienes giving corresponding substituted allenes.
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