| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
Phenylacetylene having two vinyl ethers and two hydroxyl groups were synthesized. In addition, a one-handed helical polymer was synthesized by the helix-sense-selective polymerization (HSSP) using the Rh catalyst and chiral amine. Furthermore, preparation of supramolecular self-supporting membrane by the highly selective cycloaromatization (SCAT) of the resulting helical polyphenylacetylene was carried out. On the other hand, synthesis of phenylacetylene macromonomer having a poly(vinyl ether)s were synthesized by addition of a large excess amount of the alcohol having an acetylene to the living poly(vinyl ether)s. Gas permeable of precursor polymer is PO2/ PN2 = 3.17, higher than previously.
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