Project/Area Number |
25810069
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Yamagata University |
Principal Investigator |
|
Project Period (FY) |
2013-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
|
Keywords | 高分子単分子膜 / 原子間力顕微鏡 / 単分子膜 / 高分子鎖 |
Outline of Final Research Achievements |
Up to now, the spreading process of polymer melt on a solid substrate is one of the unsolved problem. In order to understand this mechanism, the molecular visualization of isolated polymer chain under flow is needed. In this study, spreading of a poly(methyl methacrylate)(PMMA)/PMMA oligomer blend, which was a miscible system, on a mica substrate is observed by using in-situ atomic force microscopy(AFM) under constant temperature and humidity to investigate the mobility of an isolated polymer chain under flow. The results showed that the isolated PMMA chain in PMMA/PMMA oligomer blend under flow were successfully visualized with molecular resolution by AFM. This study is very important to understand the surface phenomenon, such as adhesion, wetting and friction.
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