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The molecular visualization of an isolated polymer chain under flow by AFM

Research Project

Project/Area Number 25810069
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionYamagata University

Principal Investigator

NISHITSUJI SHOTARO  山形大学, 理工学研究科, 助教 (00564858)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords高分子単分子膜 / 原子間力顕微鏡 / 単分子膜 / 高分子鎖
Outline of Final Research Achievements

Up to now, the spreading process of polymer melt on a solid substrate is one of the unsolved problem. In order to understand this mechanism, the molecular visualization of isolated polymer chain under flow is needed. In this study, spreading of a poly(methyl methacrylate)(PMMA)/PMMA oligomer blend, which was a miscible system, on a mica substrate is observed by using in-situ atomic force microscopy(AFM) under constant temperature and humidity to investigate the mobility of an isolated polymer chain under flow. The results showed that the isolated PMMA chain in PMMA/PMMA oligomer blend under flow were successfully visualized with molecular resolution by AFM. This study is very important to understand the surface phenomenon, such as adhesion, wetting and friction.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (3 results)

All 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (1 results) Remarks (1 results)

  • [Journal Article] Two-Dimensional Phase Separation of a Poly(methyl methacrylate) / Poly(L-lactide) Mixed Langmuir Monolayer via Spinodal Decomposition Mechanism2013

    • Author(s)
      Go Sato, Shotaro Nishitsuji, Jiro Kumaki
    • Journal Title

      J. Phys. Chem. B

      Volume: 117 Issue: 30 Pages: 9067-9072

    • DOI

      10.1021/jp403195g

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 高分子ブレンド融液の展開挙動AFM観察2014

    • Author(s)
      一戸捷人、西辻祥太郎、熊木治郎
    • Organizer
      第19回高分子分析討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-10-16 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://nishitsuji-lab.yz.yamagata-u.ac.jp/

    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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