| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
We synthesized a group of diradical metal complexes and studied their functions, in order to obtain design strategy of novel multi-signaling cation sensors. The diradical metal complex having the ligands linked by a propylene group was synthesized to ensure the high kinetic stability which was required to be used as a sensor in solution. The half-life indicating its kinetic stability was measured for the diradical complexes with and without the linker. The half-life of the diradical complex with the linker is 1000 times longer than that without the linker. Additionally, we found the near-infrared absorption switching of the diradical complex caused by the inclusion to cyclodextrin.
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