| Project/Area Number |
25810107
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Gifu University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | メソポーラスシリカ / アミド化反応 / グリーンケミストリー / シリカ / メソ多孔体 |
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| Outline of Final Research Achievements |
For environmental benign amidation reaction, we have developed a core-shell type catalyst as new mesoporous silica catalyst which is mesoporous silica coated silica beads. The optimization of mesoporous silica revealed that both appropriate density of silanol and pore size trigger the highest catalytic activity for direct amidation reaction. Under various modification conditions of silica beads, it can be succeeded the preparation of silica beads covered by mesoporous silica, assigned by nitrogen adsorption-desorption isotherm and FE-SEM. However, it is observed the partial cracks and unmodified moiety.
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