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Development of metal oxide mesocrystals for solar active photocatalysis

Research Project

Project/Area Number 25810114
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Research InstitutionKobe University (2014)
Osaka University (2013)

Principal Investigator

TACHIKAWA Takashi  神戸大学, 理学(系)研究科(研究院), 准教授 (20432437)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords光触媒 / 電子移動反応 / ナノ粒子 / メソ結晶 / エネルギー変換 / 高機能触媒
Outline of Final Research Achievements

It is important to fabricate innovative photofunctional materials and understand the fundamental reaction mechanisms for developing an efficient light energy conversion system. In this project, we have synthesized porous metal oxide mesocrystals and modified them with various nanomaterials to improve the photocatalytic activity. For example, plasmonic Au nanoparticle-modified titanium dioxide mesocrystals were found to have greatly improved visible light photocatalytic activity owing to an efficient interparticle electron migration in the mesocrystal structure. Furthermore, we have developed a facile method for synthesizing different kind of mesocrystals and their composites.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (7 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results) Presentation (3 results)

  • [Journal Article] Efficient charge separation on 3D architectures of TiO2 mesocrystals packed with a chemically2015

    • Author(s)
      Peng Zhang, Takashi Tachikawa, Mamoru Fujitsuka, Tetsuro Majima
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 33 Pages: 7187-7190

    • DOI

      10.1039/c5cc01753j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Au/TiO2 Superstructure-Based Plasmonic Photocatalysts Exhibiting Efficient Charge Separation and Unprecedented Activity2014

    • Author(s)
      Z. Bian, T. Tachikawa, P. Zhang, M. Fujitsuka, and T. Majima
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 1 Pages: 458-465

    • DOI

      10.1021/ja410994f

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] A nanocomposite superstructure of metal oxides with effective charge transfer interfaces2014

    • Author(s)
      Z. Bian, T. Tachikawa, P. Zhang, M. Fujitsuka, and T. Majima
    • Journal Title

      Nature Commun.

      Volume: 5 Issue: 1

    • DOI

      10.1038/ncomms4038

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Efficient charge separation and photooxidation on cobalt phosphate-loaded TiO2 mesocrystal superstructures2014

    • Author(s)
      Takashi Tachikawa, Peng Zhang, Zhenfeng Bian, Tetsuro Majima
    • Journal Title

      Journal of Material Chemistry A

      Volume: 2 Issue: 10 Pages: 3381-3388

    • DOI

      10.1039/c3ta14319h

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Auナノ粒子修飾TiO2メソ結晶中における長寿命電荷分離の観測2014

    • Author(s)
      立川貴士
    • Organizer
      2014光化学討論会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二酸化チタン光触媒反応機構に関する研究2013

    • Author(s)
      立川貴士
    • Organizer
      光化学討論会2013
    • Place of Presentation
      愛媛大学・城北地区
    • Related Report
      2013 Research-status Report
  • [Presentation] 二酸化チタンメソ結晶の合成と光触媒への応用2013

    • Author(s)
      立川貴士
    • Organizer
      第32回 固体・表面光化学討論会
    • Place of Presentation
      早稲田大学・国際会議場
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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